Synthesis and characterization of layered sodium cobaltates

研究成果: Chapter

摘要

The layered sodium cobaltates γ-NaxCoO2 show low electrical conductivity andlarge thermopower. These features are required for candidate materials in thermoelectricapplications. Superconductive sodium cobalt oxyhydrates can be obtained by topotactictransformation of γ-NaxCoO2 via oxidative de-intercalation and hydration. This chapterpresents the synthesis of γ-Na0.7CoO2 in the form of sol-gel bulk, films, nanotubules andsubmicron tubules. Materials characterization of γ-NaxCoO2 and cobalt oxyhydrates willbe also presented. According to thermopower analysis, band narrowing is observed when γ-Na0.7CoO2 is transformed to potassium sodium cobaltoxyhydrates. According to theCo K-edge x-ray absorption spectra, the Co oxidation number for bi-layer hydrateNa0.33K0.02(H2O)1.33CoO2 is higher than that of mono-layer hydrate Na0.07K0.21(H2O)0.63CoO2 with a chemical shift of 3.5 eV, which is in sharp contrast with Co Kedgex-ray absorption spectroscopy and cerimetric titration results for Nax(H2O)yCoO2,where there is essentially no difference of the oxidation number of Co between bi-layerand mono-layer sodium cobalt oxyhydrates.

原文English
主出版物標題Cobalt
主出版物子標題Characteristics, Compounds and Applications
發行者Nova Science Publishers, Inc.
頁面225-260
頁數36
ISBN(列印)9781613241035
出版狀態Published - 2011 三月 1

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

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