Sulfated and phosphated H-type niobate nanotubes as solid acid catalysts

Y. M. Huang, C. H. Lin

研究成果: Article

2 引文 (Scopus)

摘要

Highly pure sodium niobate nanotubes (NaNbNTs) were prepared by treating nonporous Nb2O5 powder with 1.0 M NaOH solution at 423 K. SEM revealed that these NaNbNTs formed nanotube-bundles with diameters of 50-250 nm and lengths of several microns. A TEM image of nanotubes indicated that they had outer diameters of 15-20 nm and inner pore diameters of 3-4 nm. BET surface area and pore volume of NaNbNTs were 65 m2 g-1 and 0.17 mL g-1, respectively. Treatment with diluted phosphoric or sulfuric solutions transformed NaNbNTs into phosphate- or sulfate-promoted protonated niobate nanotubes (PO4-3/HNbNTs and SO4-2/HNbNTs), which had a surface area of ∼80 m2 g-1, a pore volume ∼ 0.26 mL g-1 and a surface that was densely covered with acid sites (1.0-1.5 mmol g-1). Owing to the high density of its acid sites, SO4-2/HNbNTs outperformed a superacidic sulfated metal oxide like SO4-2/HfO2 in catalyzing the formation of cyclic acetals from carbonyl compounds and ethylene glycol. TPD/NH3 investigations indicated that the acid site density in PO4-3/HNbNTs was even higher than in SO4-2/HNbNTs, but its activity in catalyzing the formation of cyclic acetals was lower. These results reveal that acid sites in PO4-3/HNbNTs had a severe steric effect owing to the thick surface phosphate layer, permitting only the adsorption of small molecules. Large molecules, like heptanal, may not be easily adsorbed on a surface that is densely populated with PO4-3 groups, causing PO4-3/HNbNTs to have a lower activity than SO4-2/HNbNTs, which had a lower surface population of equally bulky SO4-2 groups.

原文English
頁(從 - 到)94-104
頁數11
期刊Microporous and Mesoporous Materials
223
DOIs
出版狀態Published - 2016 三月 15

指紋

niobates
Nanotubes
nanotubes
catalysts
acids
Catalysts
Acids
acetals
Acetals
porosity
phosphates
Phosphates
Carbonyl compounds
Molecules
carbonyl compounds
Ethylene Glycol
Temperature programmed desorption
Ethylene glycol
Powders
Oxides

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics
  • Mechanics of Materials

引用此文

@article{8735ef23c6764e7f932cadae8d2efd35,
title = "Sulfated and phosphated H-type niobate nanotubes as solid acid catalysts",
abstract = "Highly pure sodium niobate nanotubes (NaNbNTs) were prepared by treating nonporous Nb2O5 powder with 1.0 M NaOH solution at 423 K. SEM revealed that these NaNbNTs formed nanotube-bundles with diameters of 50-250 nm and lengths of several microns. A TEM image of nanotubes indicated that they had outer diameters of 15-20 nm and inner pore diameters of 3-4 nm. BET surface area and pore volume of NaNbNTs were 65 m2 g-1 and 0.17 mL g-1, respectively. Treatment with diluted phosphoric or sulfuric solutions transformed NaNbNTs into phosphate- or sulfate-promoted protonated niobate nanotubes (PO4-3/HNbNTs and SO4-2/HNbNTs), which had a surface area of ∼80 m2 g-1, a pore volume ∼ 0.26 mL g-1 and a surface that was densely covered with acid sites (1.0-1.5 mmol g-1). Owing to the high density of its acid sites, SO4-2/HNbNTs outperformed a superacidic sulfated metal oxide like SO4-2/HfO2 in catalyzing the formation of cyclic acetals from carbonyl compounds and ethylene glycol. TPD/NH3 investigations indicated that the acid site density in PO4-3/HNbNTs was even higher than in SO4-2/HNbNTs, but its activity in catalyzing the formation of cyclic acetals was lower. These results reveal that acid sites in PO4-3/HNbNTs had a severe steric effect owing to the thick surface phosphate layer, permitting only the adsorption of small molecules. Large molecules, like heptanal, may not be easily adsorbed on a surface that is densely populated with PO4-3 groups, causing PO4-3/HNbNTs to have a lower activity than SO4-2/HNbNTs, which had a lower surface population of equally bulky SO4-2 groups.",
author = "Huang, {Y. M.} and Lin, {C. H.}",
year = "2016",
month = "3",
day = "15",
doi = "10.1016/j.micromeso.2015.10.037",
language = "English",
volume = "223",
pages = "94--104",
journal = "Microporous and Mesoporous Materials",
issn = "1387-1811",
publisher = "Elsevier",

}

TY - JOUR

T1 - Sulfated and phosphated H-type niobate nanotubes as solid acid catalysts

AU - Huang, Y. M.

AU - Lin, C. H.

PY - 2016/3/15

Y1 - 2016/3/15

N2 - Highly pure sodium niobate nanotubes (NaNbNTs) were prepared by treating nonporous Nb2O5 powder with 1.0 M NaOH solution at 423 K. SEM revealed that these NaNbNTs formed nanotube-bundles with diameters of 50-250 nm and lengths of several microns. A TEM image of nanotubes indicated that they had outer diameters of 15-20 nm and inner pore diameters of 3-4 nm. BET surface area and pore volume of NaNbNTs were 65 m2 g-1 and 0.17 mL g-1, respectively. Treatment with diluted phosphoric or sulfuric solutions transformed NaNbNTs into phosphate- or sulfate-promoted protonated niobate nanotubes (PO4-3/HNbNTs and SO4-2/HNbNTs), which had a surface area of ∼80 m2 g-1, a pore volume ∼ 0.26 mL g-1 and a surface that was densely covered with acid sites (1.0-1.5 mmol g-1). Owing to the high density of its acid sites, SO4-2/HNbNTs outperformed a superacidic sulfated metal oxide like SO4-2/HfO2 in catalyzing the formation of cyclic acetals from carbonyl compounds and ethylene glycol. TPD/NH3 investigations indicated that the acid site density in PO4-3/HNbNTs was even higher than in SO4-2/HNbNTs, but its activity in catalyzing the formation of cyclic acetals was lower. These results reveal that acid sites in PO4-3/HNbNTs had a severe steric effect owing to the thick surface phosphate layer, permitting only the adsorption of small molecules. Large molecules, like heptanal, may not be easily adsorbed on a surface that is densely populated with PO4-3 groups, causing PO4-3/HNbNTs to have a lower activity than SO4-2/HNbNTs, which had a lower surface population of equally bulky SO4-2 groups.

AB - Highly pure sodium niobate nanotubes (NaNbNTs) were prepared by treating nonporous Nb2O5 powder with 1.0 M NaOH solution at 423 K. SEM revealed that these NaNbNTs formed nanotube-bundles with diameters of 50-250 nm and lengths of several microns. A TEM image of nanotubes indicated that they had outer diameters of 15-20 nm and inner pore diameters of 3-4 nm. BET surface area and pore volume of NaNbNTs were 65 m2 g-1 and 0.17 mL g-1, respectively. Treatment with diluted phosphoric or sulfuric solutions transformed NaNbNTs into phosphate- or sulfate-promoted protonated niobate nanotubes (PO4-3/HNbNTs and SO4-2/HNbNTs), which had a surface area of ∼80 m2 g-1, a pore volume ∼ 0.26 mL g-1 and a surface that was densely covered with acid sites (1.0-1.5 mmol g-1). Owing to the high density of its acid sites, SO4-2/HNbNTs outperformed a superacidic sulfated metal oxide like SO4-2/HfO2 in catalyzing the formation of cyclic acetals from carbonyl compounds and ethylene glycol. TPD/NH3 investigations indicated that the acid site density in PO4-3/HNbNTs was even higher than in SO4-2/HNbNTs, but its activity in catalyzing the formation of cyclic acetals was lower. These results reveal that acid sites in PO4-3/HNbNTs had a severe steric effect owing to the thick surface phosphate layer, permitting only the adsorption of small molecules. Large molecules, like heptanal, may not be easily adsorbed on a surface that is densely populated with PO4-3 groups, causing PO4-3/HNbNTs to have a lower activity than SO4-2/HNbNTs, which had a lower surface population of equally bulky SO4-2 groups.

UR - http://www.scopus.com/inward/record.url?scp=84947259126&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84947259126&partnerID=8YFLogxK

U2 - 10.1016/j.micromeso.2015.10.037

DO - 10.1016/j.micromeso.2015.10.037

M3 - Article

AN - SCOPUS:84947259126

VL - 223

SP - 94

EP - 104

JO - Microporous and Mesoporous Materials

JF - Microporous and Mesoporous Materials

SN - 1387-1811

ER -