An unprecedented transformation mode in aluminium oxazoline-amido-phenolate complexes

Ming Tsz Chen, Yu Yang Chen, Guan Lin Li, Kai Wen Chou, Ching Han Hu, Guo Cyuan Huang, Chi Tien Chen

研究成果: Article

摘要

This paper describes the effect of solvent-induced synthetic routes of aluminium pendant oxazoline-amido-phenolate complexes. Treatment of ligand precursor L with AlMe3 in a 1:1 ratio in diethyl ether yielded the four-coordinated complex (LAlMe)2. Reaction of ligand precursor L with AlMe3 in a 1:2 ratio in hexane generated the four-coordinated complex L(AlMe2)2. A novel transformation mode occurred from L(AlMe2)2 to (LAlMe)2 when using diethyl ether or tetrahydrofuran as solvent. A density functional theory computational study also supports a plausible mechanism. All results were supported by spectroscopic data and in agreement with single-crystal X-ray diffraction structural analysis.

原文English
文章編號e5464
期刊Applied Organometallic Chemistry
34
發行號4
DOIs
出版狀態Published - 2020 四月 1

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Inorganic Chemistry

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