摘要
A mixed valent heterometallic CuII/NaI coordination polymer (1) is generated by the reaction of a Schiff base ligand, (6,6′-(1E,1′E)-(2-hydroxypropane-1,3-diyl)bis(azan-1-yl-1-ylidene) bis(methan-1-yl-1-ylidene)bis(2-methoxyphenol)) with copper(ii) acetate and sodium perchlorate. In addition to the presence of alcohol oxygen-sodium coordination bonds, the single crystal X-ray structure reveals that the 1D coordination polymer is stabilised by the formation of phenyl-sodium η2-bonds, face-to-face π-π contacts and Cu-π interactions. This journal is
原文 | English |
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頁(從 - 到) | 5558-5563 |
頁數 | 6 |
期刊 | Dalton Transactions |
卷 | 43 |
發行號 | 14 |
DOIs | |
出版狀態 | Published - 2014 四月 14 |
All Science Journal Classification (ASJC) codes
- Inorganic Chemistry