γ-halo-enones: A method for their synthesis from arylacyl halides and their application to the preparation of five-membered ring heterocycles

Mei-Huey Lin, Yen Chih Huang, Chung Kai Kuo, Chang Hsien Tsai, Yi Syuan Li, Ting Chia Hu, Tsung Hsun Chuang

研究成果: Article同行評審

11 引文 斯高帕斯(Scopus)

摘要

A simple method has been developed for synthesis of γ-halo-enones. The approach employs a sequence involving initial indium-mediated allenylation reactions of phenacyl halides with propargyl bromide. This process is followed by acid-promoted rearrangement reactions of the formed homoallenic halohydrins. The new method can be incorporated into routes for the efficient synthesis of various five-membered heterocyclic compounds.

原文English
頁(從 - 到)2751-2757
頁數7
期刊Journal of Organic Chemistry
79
發行號6
DOIs
出版狀態Published - 2014 三月 21

All Science Journal Classification (ASJC) codes

  • Organic Chemistry

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