Tuning of net architectures of Ni(ii) and Zn(ii) coordination polymers using isomeric organic linkers

Shuang De Liu; Bing Chiuan Kuo; Yen Wen Liu; Jing Yi Lee; Kwun Yip Wong; Hon Man Lee

doi:10.1039/c4ce01072h

Tuning of net architectures of Ni(ii) and Zn(ii) coordination polymers using isomeric organic linkers

Shuang De Liu, Bing Chiuan Kuo, Yen Wen Liu, Jing Yi Lee, Kwun Yip Wong, Hon Man Lee

Department of Chemistry

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9 Citations (Scopus)

Abstract

Solvothermal syntheses involving the hybrid ligands {3-pyridin-3- ylimidazo[1,2-a]pyridine (L1) and 3-pyridin-4-ylimidazo[1,2-a]pyridine (L2)}, aromatic polycarboxylates [1,4-benzenedicarboxylate (1,4-bdc), 1,3-benzenedicarboxylate (1,3-bdc), and 1,3,5-benzenetricarboxylate (1,3,5-btc)], and transition metal ions [Ni(ii) and Zn(ii) ions] afforded five new coordination polymers, namely, [Ni(1,4-bdc)(L1)(H₂O) ₂]_n (1), [Ni₂(1,3-bdc)₂(L1) ₂(H₂O)]_n (2), [Zn₂(1,4-bdc) _1.5(L1)(OH)]_n (3), and [Zn₂(1,3,5-btc)(L1) O_0.5(H₂O)_0.5·0.5H₂O] _n (4), and [Zn₂(1,3,5-btc)(L2)(OCOH)(H₂O)] _n (5). A diversity of net topologies was observed including a rare 2D 4-connected net with the point symbol of (4⁴·6 ³·8) in 1, a dia net in 2, a twofold interpenetrating pcu net in 3, a rare 3D (3,8)-connected binodal 3,8T35 net in 4, and sra and rtl nets in 5. Four different secondary building units were involved in the construction of the 3D nets. The three Zn(ii) complexes exhibit photoluminescence. This journal is

Original language	English
Pages (from-to)	8874-8884
Number of pages	11
Journal	CrystEngComm
Volume	16
Issue number	37
DOIs	https://doi.org/10.1039/c4ce01072h
Publication status	Published - 2014 Oct 7

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All Science Journal Classification (ASJC) codes

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

Cite this

Liu, S. D., Kuo, B. C., Liu, Y. W., Lee, J. Y., Wong, K. Y., & Lee, H. M. (2014). Tuning of net architectures of Ni(ii) and Zn(ii) coordination polymers using isomeric organic linkers. CrystEngComm, 16(37), 8874-8884. https://doi.org/10.1039/c4ce01072h

@article{ec7050e67c3e4334a2600f4e134130c5,

title = "Tuning of net architectures of Ni(ii) and Zn(ii) coordination polymers using isomeric organic linkers",

abstract = "Solvothermal syntheses involving the hybrid ligands {3-pyridin-3- ylimidazo[1,2-a]pyridine (L1) and 3-pyridin-4-ylimidazo[1,2-a]pyridine (L2)}, aromatic polycarboxylates [1,4-benzenedicarboxylate (1,4-bdc), 1,3-benzenedicarboxylate (1,3-bdc), and 1,3,5-benzenetricarboxylate (1,3,5-btc)], and transition metal ions [Ni(ii) and Zn(ii) ions] afforded five new coordination polymers, namely, [Ni(1,4-bdc)(L1)(H2O) 2]n (1), [Ni2(1,3-bdc)2(L1) 2(H2O)]n (2), [Zn2(1,4-bdc) 1.5(L1)(OH)]n (3), and [Zn2(1,3,5-btc)(L1) O0.5(H2O)0.5·0.5H2O] n (4), and [Zn2(1,3,5-btc)(L2)(OCOH)(H2O)] n (5). A diversity of net topologies was observed including a rare 2D 4-connected net with the point symbol of (44·6 3·8) in 1, a dia net in 2, a twofold interpenetrating pcu net in 3, a rare 3D (3,8)-connected binodal 3,8T35 net in 4, and sra and rtl nets in 5. Four different secondary building units were involved in the construction of the 3D nets. The three Zn(ii) complexes exhibit photoluminescence. This journal is",

author = "Liu, {Shuang De} and Kuo, {Bing Chiuan} and Liu, {Yen Wen} and Lee, {Jing Yi} and Wong, {Kwun Yip} and Lee, {Hon Man}",

year = "2014",

month = oct

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doi = "10.1039/c4ce01072h",

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T1 - Tuning of net architectures of Ni(ii) and Zn(ii) coordination polymers using isomeric organic linkers

AU - Liu, Shuang De

AU - Kuo, Bing Chiuan

AU - Liu, Yen Wen

AU - Lee, Jing Yi

AU - Wong, Kwun Yip

AU - Lee, Hon Man

PY - 2014/10/7

Y1 - 2014/10/7

N2 - Solvothermal syntheses involving the hybrid ligands {3-pyridin-3- ylimidazo[1,2-a]pyridine (L1) and 3-pyridin-4-ylimidazo[1,2-a]pyridine (L2)}, aromatic polycarboxylates [1,4-benzenedicarboxylate (1,4-bdc), 1,3-benzenedicarboxylate (1,3-bdc), and 1,3,5-benzenetricarboxylate (1,3,5-btc)], and transition metal ions [Ni(ii) and Zn(ii) ions] afforded five new coordination polymers, namely, [Ni(1,4-bdc)(L1)(H2O) 2]n (1), [Ni2(1,3-bdc)2(L1) 2(H2O)]n (2), [Zn2(1,4-bdc) 1.5(L1)(OH)]n (3), and [Zn2(1,3,5-btc)(L1) O0.5(H2O)0.5·0.5H2O] n (4), and [Zn2(1,3,5-btc)(L2)(OCOH)(H2O)] n (5). A diversity of net topologies was observed including a rare 2D 4-connected net with the point symbol of (44·6 3·8) in 1, a dia net in 2, a twofold interpenetrating pcu net in 3, a rare 3D (3,8)-connected binodal 3,8T35 net in 4, and sra and rtl nets in 5. Four different secondary building units were involved in the construction of the 3D nets. The three Zn(ii) complexes exhibit photoluminescence. This journal is

AB - Solvothermal syntheses involving the hybrid ligands {3-pyridin-3- ylimidazo[1,2-a]pyridine (L1) and 3-pyridin-4-ylimidazo[1,2-a]pyridine (L2)}, aromatic polycarboxylates [1,4-benzenedicarboxylate (1,4-bdc), 1,3-benzenedicarboxylate (1,3-bdc), and 1,3,5-benzenetricarboxylate (1,3,5-btc)], and transition metal ions [Ni(ii) and Zn(ii) ions] afforded five new coordination polymers, namely, [Ni(1,4-bdc)(L1)(H2O) 2]n (1), [Ni2(1,3-bdc)2(L1) 2(H2O)]n (2), [Zn2(1,4-bdc) 1.5(L1)(OH)]n (3), and [Zn2(1,3,5-btc)(L1) O0.5(H2O)0.5·0.5H2O] n (4), and [Zn2(1,3,5-btc)(L2)(OCOH)(H2O)] n (5). A diversity of net topologies was observed including a rare 2D 4-connected net with the point symbol of (44·6 3·8) in 1, a dia net in 2, a twofold interpenetrating pcu net in 3, a rare 3D (3,8)-connected binodal 3,8T35 net in 4, and sra and rtl nets in 5. Four different secondary building units were involved in the construction of the 3D nets. The three Zn(ii) complexes exhibit photoluminescence. This journal is

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