Abstract
In the title compound, [Pd(C18H16N3O) 2]·2CH3OH, the PdII atom is located on a crystallographic inversion center. It has a square-planar coordination geometry, with the two bidentate ligands coordinated in a trans fashion via the carbene C atom and the amido N atoms. The methanol solvent molecules form O - H⋯O hydrogen bonds with the complex. Additional non-classical intermolecular C - H⋯O hydrogen bonds link the complexes into a two-dimensional network parallel to (001).
| Original language | English |
|---|---|
| Journal | Acta Crystallographica Section E: Structure Reports Online |
| Volume | 67 |
| Issue number | 4 |
| DOIs | |
| Publication status | Published - 2011 Apr 1 |
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All Science Journal Classification (ASJC) codes
- Chemistry(all)
- Materials Science(all)
- Condensed Matter Physics
Cite this
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Trans-Bis[1-(2-anilino-2-oxoeth-yl)-3-benzyl-1H-imidazol-2-yl]palladium(II) methanol disolvate. / Lee, Hon Man; Chang, Yu Chuan.
In: Acta Crystallographica Section E: Structure Reports Online, Vol. 67, No. 4, 01.04.2011.Research output: Contribution to journal › Article
TY - JOUR
T1 - Trans-Bis[1-(2-anilino-2-oxoeth-yl)-3-benzyl-1H-imidazol-2-yl]palladium(II) methanol disolvate
AU - Lee, Hon Man
AU - Chang, Yu Chuan
PY - 2011/4/1
Y1 - 2011/4/1
N2 - In the title compound, [Pd(C18H16N3O) 2]·2CH3OH, the PdII atom is located on a crystallographic inversion center. It has a square-planar coordination geometry, with the two bidentate ligands coordinated in a trans fashion via the carbene C atom and the amido N atoms. The methanol solvent molecules form O - H⋯O hydrogen bonds with the complex. Additional non-classical intermolecular C - H⋯O hydrogen bonds link the complexes into a two-dimensional network parallel to (001).
AB - In the title compound, [Pd(C18H16N3O) 2]·2CH3OH, the PdII atom is located on a crystallographic inversion center. It has a square-planar coordination geometry, with the two bidentate ligands coordinated in a trans fashion via the carbene C atom and the amido N atoms. The methanol solvent molecules form O - H⋯O hydrogen bonds with the complex. Additional non-classical intermolecular C - H⋯O hydrogen bonds link the complexes into a two-dimensional network parallel to (001).
UR - http://www.scopus.com/inward/record.url?scp=79953798443&partnerID=8YFLogxK
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U2 - 10.1107/S1600536811007768
DO - 10.1107/S1600536811007768
M3 - Article
VL - 67
JO - Acta Crystallographica Section E: Structure Reports Online
JF - Acta Crystallographica Section E: Structure Reports Online
SN - 1600-5368
IS - 4
ER -