Trans-Bis[1-(2-anilino-2-oxoeth-yl)-3-benzyl-1H-imidazol-2-yl]palladium(II) methanol disolvate

Hon Man Lee; Yu Chuan Chang

doi:10.1107/S1600536811007768

Trans-Bis[1-(2-anilino-2-oxoeth-yl)-3-benzyl-1H-imidazol-2-yl]palladium(II) methanol disolvate

Hon Man Lee, Yu Chuan Chang

Department of Chemistry

Research output: Contribution to journal › Article

2 Citations (Scopus)

Abstract

In the title compound, [Pd(C₁₈H₁₆N₃O) ₂]·2CH₃OH, the Pd^II atom is located on a crystallographic inversion center. It has a square-planar coordination geometry, with the two bidentate ligands coordinated in a trans fashion via the carbene C atom and the amido N atoms. The methanol solvent molecules form O - H⋯O hydrogen bonds with the complex. Additional non-classical intermolecular C - H⋯O hydrogen bonds link the complexes into a two-dimensional network parallel to (001).

Original language	English
Pages (from-to)	m467
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	67
Issue number	4
DOIs	https://doi.org/10.1107/S1600536811007768
Publication status	Published - 2011 Apr 1

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All Science Journal Classification (ASJC) codes

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

Cite this

Lee, H. M., & Chang, Y. C. (2011). Trans-Bis[1-(2-anilino-2-oxoeth-yl)-3-benzyl-1H-imidazol-2-yl]palladium(II) methanol disolvate. Acta Crystallographica Section E: Structure Reports Online, 67(4), m467. https://doi.org/10.1107/S1600536811007768

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abstract = "In the title compound, [Pd(C18H16N3O) 2]·2CH3OH, the PdII atom is located on a crystallographic inversion center. It has a square-planar coordination geometry, with the two bidentate ligands coordinated in a trans fashion via the carbene C atom and the amido N atoms. The methanol solvent molecules form O - H⋯O hydrogen bonds with the complex. Additional non-classical intermolecular C - H⋯O hydrogen bonds link the complexes into a two-dimensional network parallel to (001).",

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10.1107/S1600536811007768