Trans-Bis[1-(2-anilino-2-oxoeth-yl)-3-benzyl-1H-imidazol-2-yl]palladium(II) methanol disolvate

Hon Man Lee; Yu Chuan Chang

doi:10.1107/S1600536811007768

Trans-Bis[1-(2-anilino-2-oxoeth-yl)-3-benzyl-1H-imidazol-2-yl]palladium(II) methanol disolvate

Hon Man Lee, Yu Chuan Chang

Department of Chemistry

Research output: Contribution to journal › Article

2 Citations (Scopus)

Abstract

In the title compound, [Pd(C₁₈H₁₆N₃O) ₂]·2CH₃OH, the Pd^II atom is located on a crystallographic inversion center. It has a square-planar coordination geometry, with the two bidentate ligands coordinated in a trans fashion via the carbene C atom and the amido N atoms. The methanol solvent molecules form O - H⋯O hydrogen bonds with the complex. Additional non-classical intermolecular C - H⋯O hydrogen bonds link the complexes into a two-dimensional network parallel to (001).

Original language	English
Pages (from-to)	m467
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	67
Issue number	4
DOIs	https://doi.org/10.1107/S1600536811007768
Publication status	Published - 2011 Apr

All Science Journal Classification (ASJC) codes

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

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title = "Trans-Bis[1-(2-anilino-2-oxoeth-yl)-3-benzyl-1H-imidazol-2-yl]palladium(II) methanol disolvate",

abstract = "In the title compound, [Pd(C18H16N3O) 2]·2CH3OH, the PdII atom is located on a crystallographic inversion center. It has a square-planar coordination geometry, with the two bidentate ligands coordinated in a trans fashion via the carbene C atom and the amido N atoms. The methanol solvent molecules form O - H⋯O hydrogen bonds with the complex. Additional non-classical intermolecular C - H⋯O hydrogen bonds link the complexes into a two-dimensional network parallel to (001).",

author = "Lee, {Hon Man} and Chang, {Yu Chuan}",

year = "2011",

month = apr,

doi = "10.1107/S1600536811007768",

language = "English",

volume = "67",

pages = "m467",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

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T1 - Trans-Bis[1-(2-anilino-2-oxoeth-yl)-3-benzyl-1H-imidazol-2-yl]palladium(II) methanol disolvate

AU - Lee, Hon Man

AU - Chang, Yu Chuan

PY - 2011/4

Y1 - 2011/4

N2 - In the title compound, [Pd(C18H16N3O) 2]·2CH3OH, the PdII atom is located on a crystallographic inversion center. It has a square-planar coordination geometry, with the two bidentate ligands coordinated in a trans fashion via the carbene C atom and the amido N atoms. The methanol solvent molecules form O - H⋯O hydrogen bonds with the complex. Additional non-classical intermolecular C - H⋯O hydrogen bonds link the complexes into a two-dimensional network parallel to (001).

AB - In the title compound, [Pd(C18H16N3O) 2]·2CH3OH, the PdII atom is located on a crystallographic inversion center. It has a square-planar coordination geometry, with the two bidentate ligands coordinated in a trans fashion via the carbene C atom and the amido N atoms. The methanol solvent molecules form O - H⋯O hydrogen bonds with the complex. Additional non-classical intermolecular C - H⋯O hydrogen bonds link the complexes into a two-dimensional network parallel to (001).

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