Trans-Bis[1-(2-anilino-2-oxoeth-yl)-3-benzyl-1H-imidazol-2-yl]palladium(II) methanol disolvate

Hon Man Lee, Yu Chuan Chang

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

In the title compound, [Pd(C18H16N3O) 2]·2CH3OH, the PdII atom is located on a crystallographic inversion center. It has a square-planar coordination geometry, with the two bidentate ligands coordinated in a trans fashion via the carbene C atom and the amido N atoms. The methanol solvent molecules form O - H⋯O hydrogen bonds with the complex. Additional non-classical intermolecular C - H⋯O hydrogen bonds link the complexes into a two-dimensional network parallel to (001).

Original languageEnglish
JournalActa Crystallographica Section E: Structure Reports Online
Volume67
Issue number4
DOIs
Publication statusPublished - 2011 Apr 1

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Palladium
imidazoles
Methanol
palladium
methyl alcohol
Atoms
Hydrogen bonds
hydrogen bonds
atoms
carbenes
Ligands
inversions
ligands
Molecules
Geometry
geometry
molecules

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

Cite this

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title = "Trans-Bis[1-(2-anilino-2-oxoeth-yl)-3-benzyl-1H-imidazol-2-yl]palladium(II) methanol disolvate",
abstract = "In the title compound, [Pd(C18H16N3O) 2]·2CH3OH, the PdII atom is located on a crystallographic inversion center. It has a square-planar coordination geometry, with the two bidentate ligands coordinated in a trans fashion via the carbene C atom and the amido N atoms. The methanol solvent molecules form O - H⋯O hydrogen bonds with the complex. Additional non-classical intermolecular C - H⋯O hydrogen bonds link the complexes into a two-dimensional network parallel to (001).",
author = "Lee, {Hon Man} and Chang, {Yu Chuan}",
year = "2011",
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doi = "10.1107/S1600536811007768",
language = "English",
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journal = "Acta Crystallographica Section E: Structure Reports Online",
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publisher = "International Union of Crystallography",
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T1 - Trans-Bis[1-(2-anilino-2-oxoeth-yl)-3-benzyl-1H-imidazol-2-yl]palladium(II) methanol disolvate

AU - Lee, Hon Man

AU - Chang, Yu Chuan

PY - 2011/4/1

Y1 - 2011/4/1

N2 - In the title compound, [Pd(C18H16N3O) 2]·2CH3OH, the PdII atom is located on a crystallographic inversion center. It has a square-planar coordination geometry, with the two bidentate ligands coordinated in a trans fashion via the carbene C atom and the amido N atoms. The methanol solvent molecules form O - H⋯O hydrogen bonds with the complex. Additional non-classical intermolecular C - H⋯O hydrogen bonds link the complexes into a two-dimensional network parallel to (001).

AB - In the title compound, [Pd(C18H16N3O) 2]·2CH3OH, the PdII atom is located on a crystallographic inversion center. It has a square-planar coordination geometry, with the two bidentate ligands coordinated in a trans fashion via the carbene C atom and the amido N atoms. The methanol solvent molecules form O - H⋯O hydrogen bonds with the complex. Additional non-classical intermolecular C - H⋯O hydrogen bonds link the complexes into a two-dimensional network parallel to (001).

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JO - Acta Crystallographica Section E: Structure Reports Online

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SN - 1600-5368

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