The spectral heterogeneity and size distribution of the carbon dots derived from time-resolved fluorescence studies

Ying Feng Hsu, Yu Hsun Chen, Chih Wei Chang

Research output: Contribution to journalArticle

9 Citations (Scopus)

Abstract

We performed comprehensive studies on the photoluminescence properties of the carbon dots prepared from citric acid (C-dotsCA) and citric acid + ethylenediamine (C-dotsCA+EDA). The cryogenic experiment confirmed that the excitation dependent fluorescence and the spectral relaxation dynamics of the C-dots are associated with the presence of multiple emissive states/species in the C-dots instead of solvation dynamics. Moreover, we also compared the size of the C-dots estimated from the TEM/AFM images and fluorescence anisotropy methods. The experimental results indicate that the fluorescence anisotropy method not only avoids the formation of aggregates during the sample preparation processes, but also selectively detects the size of emissive C-dots in the solution. Therefore, the fluorescence anisotropy method is ideal for studying the size dependent optical properties of the C-dots.

Original languageEnglish
Pages (from-to)30086-30092
Number of pages7
JournalPhysical Chemistry Chemical Physics
Volume18
Issue number43
DOIs
Publication statusPublished - 2016 Jan 1

Fingerprint

Carbon
Fluorescence
fluorescence
ethylenediamine
Anisotropy
citric acid
carbon
Citric Acid
anisotropy
Solvation
Cryogenics
cryogenics
solvation
Photoluminescence
Optical properties
atomic force microscopy
Transmission electron microscopy
photoluminescence
optical properties
preparation

All Science Journal Classification (ASJC) codes

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

Cite this

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abstract = "We performed comprehensive studies on the photoluminescence properties of the carbon dots prepared from citric acid (C-dotsCA) and citric acid + ethylenediamine (C-dotsCA+EDA). The cryogenic experiment confirmed that the excitation dependent fluorescence and the spectral relaxation dynamics of the C-dots are associated with the presence of multiple emissive states/species in the C-dots instead of solvation dynamics. Moreover, we also compared the size of the C-dots estimated from the TEM/AFM images and fluorescence anisotropy methods. The experimental results indicate that the fluorescence anisotropy method not only avoids the formation of aggregates during the sample preparation processes, but also selectively detects the size of emissive C-dots in the solution. Therefore, the fluorescence anisotropy method is ideal for studying the size dependent optical properties of the C-dots.",
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The spectral heterogeneity and size distribution of the carbon dots derived from time-resolved fluorescence studies. / Hsu, Ying Feng; Chen, Yu Hsun; Chang, Chih Wei.

In: Physical Chemistry Chemical Physics, Vol. 18, No. 43, 01.01.2016, p. 30086-30092.

Research output: Contribution to journalArticle

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