Abstract
The chiral triphosphine ligand (S,S)-PhP(CH2CHMeCH2PPh2)2, ttp*, was synthesized by the reaction of (S)-Ph2PCH2CHMeCH2Cl and PhPH2 in the presence of LDA. Reactions of ttp* with RuCl2(PPh3)3, [RhCl(COD)]2, and CoCl2 produced RuCl2(ttp*), RhCl(ttp*), and CoCl2-(ttp*), respectively. These compounds were characterized by elemental analysis and multinuclear NMR spectroscopy. The structure of RhCl(ttp*) has been determined by X-ray diffraction.
| Original language | English |
|---|---|
| Pages (from-to) | 4235-4239 |
| Number of pages | 5 |
| Journal | Organometallics |
| Volume | 15 |
| Issue number | 20 |
| Publication status | Published - 1996 Oct 1 |
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All Science Journal Classification (ASJC) codes
- Physical and Theoretical Chemistry
- Organic Chemistry
- Inorganic Chemistry
Cite this
Jia, G., Lee, H. M., & Williams, I. D. (1996). Synthesis of the chiral triphosphine (S,S)-PhP(CH2CHMeCH2PPh2)2 and its metal complexes. Organometallics, 15(20), 4235-4239.