Synthesis of the chiral triphosphine (S,S)-PhP(CH2CHMeCH2PPh2)2 and its metal complexes

Guochen Jia, Hon Man Lee, Ian D. Williams

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19 Citations (Scopus)

Abstract

The chiral triphosphine ligand (S,S)-PhP(CH2CHMeCH2PPh2)2, ttp*, was synthesized by the reaction of (S)-Ph2PCH2CHMeCH2Cl and PhPH2 in the presence of LDA. Reactions of ttp* with RuCl2(PPh3)3, [RhCl(COD)]2, and CoCl2 produced RuCl2(ttp*), RhCl(ttp*), and CoCl2-(ttp*), respectively. These compounds were characterized by elemental analysis and multinuclear NMR spectroscopy. The structure of RhCl(ttp*) has been determined by X-ray diffraction.

Original languageEnglish
Pages (from-to)4235-4239
Number of pages5
JournalOrganometallics
Volume15
Issue number20
DOIs
Publication statusPublished - 1996 Oct 1

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

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