Synthesis characterization of magnetic properties in La 0.7-xLnxPb0.3MnO3 (Ln=Pr, Nd, Gd, Dy, Sm and Y) perovskite compounds

S. L. Young; H. Z. Chen; J. Y. Shen; Lance Horng; Y. W. Ho; J. B. Shi; C. C. Lin

Synthesis characterization of magnetic properties in La _0.7-xLn_xPb_0.3MnO₃ (Ln=Pr, Nd, Gd, Dy, Sm and Y) perovskite compounds

S. L. Young, H. Z. Chen, J. Y. Shen, Lance Horng, Y. W. Ho, J. B. Shi, C. C. Lin

Department of Physics

Research output: Contribution to journal › Conference article › peer-review

Abstract

The magnetization behaviors of perovskite oxides, La_0.7-xLn _xPb_0.3MnO₃ (Ln=Pr, Nd, Gd, Dy, Sm and Y), have been synthesized. The replacement of La ion by Pr, Nd, Gd, Dy, Sm or Y results in a considerable decrease in the ferromagnetic ordering temperature T _c and clearly irreversible behavior in the FC-ZFC curves showing a short-range spin order phase. The fact is in agreement with the smaller ionic radii of Pr, Nd, Gd, Dy, Sm and Y ions in contrast to La ion and the corresponding larger distortion of perovskite structures. The saturation magnetization M_S increases as Pr or Nd content increases while M _S decreases as Sm or Y content increases. Moreover, the saturation magnetization M_S increases and then decreases as Gd and Dy content increases. These results can be explained in terms of the competition between the increase of ferromagnetically interacting spins due to the introduction of magnetic Pr or Sm ions with f-shell electrons and suppression of ferromagnetism due to structure tuning induced by the small ionic radius of the interpolated cation into the La-site.

Original language	English
Pages (from-to)	2073-2080
Number of pages	8
Journal	International SAMPE Symposium and Exhibition (Proceedings)
Volume	50
Publication status	Published - 2005 Dec 1
Event	50th International SAMPE Symposium and Exhibition - Long Beach, CA, United States Duration: 2005 May 1 → 2005 May 5

All Science Journal Classification (ASJC) codes

Materials Science(all)
Mechanics of Materials
Mechanical Engineering

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@article{0538b547a14b45f09e56ad015c282f43,

title = "Synthesis characterization of magnetic properties in La 0.7-xLnxPb0.3MnO3 (Ln=Pr, Nd, Gd, Dy, Sm and Y) perovskite compounds",

abstract = "The magnetization behaviors of perovskite oxides, La0.7-xLn xPb0.3MnO3 (Ln=Pr, Nd, Gd, Dy, Sm and Y), have been synthesized. The replacement of La ion by Pr, Nd, Gd, Dy, Sm or Y results in a considerable decrease in the ferromagnetic ordering temperature T c and clearly irreversible behavior in the FC-ZFC curves showing a short-range spin order phase. The fact is in agreement with the smaller ionic radii of Pr, Nd, Gd, Dy, Sm and Y ions in contrast to La ion and the corresponding larger distortion of perovskite structures. The saturation magnetization MS increases as Pr or Nd content increases while M S decreases as Sm or Y content increases. Moreover, the saturation magnetization MS increases and then decreases as Gd and Dy content increases. These results can be explained in terms of the competition between the increase of ferromagnetically interacting spins due to the introduction of magnetic Pr or Sm ions with f-shell electrons and suppression of ferromagnetism due to structure tuning induced by the small ionic radius of the interpolated cation into the La-site.",

author = "Young, {S. L.} and Chen, {H. Z.} and Shen, {J. Y.} and Lance Horng and Ho, {Y. W.} and Shi, {J. B.} and Lin, {C. C.}",

year = "2005",

month = dec,

day = "1",

language = "English",

volume = "50",

pages = "2073--2080",

journal = "International SAMPE Symposium and Exhibition",

issn = "0891-0138",

publisher = "Soc. for the Advancement of Material and Process Engineering",

note = "50th International SAMPE Symposium and Exhibition ; Conference date: 01-05-2005 Through 05-05-2005",

}

Synthesis characterization of magnetic properties in La _0.7-xLn_xPb_0.3MnO₃ (Ln=Pr, Nd, Gd, Dy, Sm and Y) perovskite compounds. / Young, S. L.; Chen, H. Z.; Shen, J. Y.; Horng, Lance; Ho, Y. W.; Shi, J. B.; Lin, C. C.

In: International SAMPE Symposium and Exhibition (Proceedings), Vol. 50, 01.12.2005, p. 2073-2080.

Research output: Contribution to journal › Conference article › peer-review

TY - JOUR

T1 - Synthesis characterization of magnetic properties in La 0.7-xLnxPb0.3MnO3 (Ln=Pr, Nd, Gd, Dy, Sm and Y) perovskite compounds

AU - Young, S. L.

AU - Chen, H. Z.

AU - Shen, J. Y.

AU - Horng, Lance

AU - Ho, Y. W.

AU - Shi, J. B.

AU - Lin, C. C.

PY - 2005/12/1

Y1 - 2005/12/1

N2 - The magnetization behaviors of perovskite oxides, La0.7-xLn xPb0.3MnO3 (Ln=Pr, Nd, Gd, Dy, Sm and Y), have been synthesized. The replacement of La ion by Pr, Nd, Gd, Dy, Sm or Y results in a considerable decrease in the ferromagnetic ordering temperature T c and clearly irreversible behavior in the FC-ZFC curves showing a short-range spin order phase. The fact is in agreement with the smaller ionic radii of Pr, Nd, Gd, Dy, Sm and Y ions in contrast to La ion and the corresponding larger distortion of perovskite structures. The saturation magnetization MS increases as Pr or Nd content increases while M S decreases as Sm or Y content increases. Moreover, the saturation magnetization MS increases and then decreases as Gd and Dy content increases. These results can be explained in terms of the competition between the increase of ferromagnetically interacting spins due to the introduction of magnetic Pr or Sm ions with f-shell electrons and suppression of ferromagnetism due to structure tuning induced by the small ionic radius of the interpolated cation into the La-site.

AB - The magnetization behaviors of perovskite oxides, La0.7-xLn xPb0.3MnO3 (Ln=Pr, Nd, Gd, Dy, Sm and Y), have been synthesized. The replacement of La ion by Pr, Nd, Gd, Dy, Sm or Y results in a considerable decrease in the ferromagnetic ordering temperature T c and clearly irreversible behavior in the FC-ZFC curves showing a short-range spin order phase. The fact is in agreement with the smaller ionic radii of Pr, Nd, Gd, Dy, Sm and Y ions in contrast to La ion and the corresponding larger distortion of perovskite structures. The saturation magnetization MS increases as Pr or Nd content increases while M S decreases as Sm or Y content increases. Moreover, the saturation magnetization MS increases and then decreases as Gd and Dy content increases. These results can be explained in terms of the competition between the increase of ferromagnetically interacting spins due to the introduction of magnetic Pr or Sm ions with f-shell electrons and suppression of ferromagnetism due to structure tuning induced by the small ionic radius of the interpolated cation into the La-site.

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M3 - Conference article

AN - SCOPUS:31944442035

VL - 50

SP - 2073

EP - 2080

JO - International SAMPE Symposium and Exhibition

JF - International SAMPE Symposium and Exhibition

SN - 0891-0138

T2 - 50th International SAMPE Symposium and Exhibition

Y2 - 1 May 2005 through 5 May 2005

ER -