Synthesis and characterization of tungsten bis-imido complexes containing bi-dentate pyrrole-amine, pyrrole-imine or ketiminate ligands

Ching Sheng Hsiao, Hui Shan Chen, Shu Ya Hsu, Ting Yin Wang, Amitabha Datta, Chia Her Lin, Jui-Hsien Huang

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3 Citations (Scopus)

Abstract

Three new imido tungsten derivatives containing bi-dentate pyrrole-amine, pyrrole-imine or ketiminate precursor were synthesized and characterized. Reacting W(NtBu)2(NHtBu)2 with two equiv of C4H3NH(2-CH2NHtBu) and C4H3NH(2-CHNCH2Py) in diethyl ether and toluene generates [W(NtBu)2{C4H3N(2-CH 2NHtBu)}2] (1) and [W(NtBu) 2{C4H3N(2-CHNCH2Py)}2] (2) in good yield. Similarly, while subjecting two equiv of (ArNCMeCHCMeOH) (Ar = 2-MeOC6H4) with W(NtBu)2(NH tBu)2 in diethyl ether, affords [W(NtBu) 2{OCMeCHCMeNAr}2] (3) in high yield. Single crystal X-ray structure reveals that in all three complexes the 6-coordinate W atoms belong to a distorted octahedral environment.

Original languageEnglish
Pages (from-to)1-5
Number of pages5
JournalInorganica Chimica Acta
Volume413
DOIs
Publication statusPublished - 2014 Mar 24

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All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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