Synthesis and characterization of spiral carbon nanofibers containing Pd metal cluster by using Pd2(dba)3 as catalyst

C. J. Su, L. S. Hsu, T. W. Wu, Chia-Jyi Liu, S. H. Lin

Research output: Chapter in Book/Report/Conference proceedingConference contribution

1 Citation (Scopus)

Abstract

The spiral carbon nanofibers consisting of Pd metal cluster were grown by the Pd2(dba)3-catalyzed decomposition of gaseous acetylene on molecular sieves (Linde 13X) support. The phase and composition of the sample was measured with x-ray diffraction (XRD). The microstructure and composition of the spiral carbon nanofibers were characterized by transmission electron microscope (TEM) and selective area diffraction (SAD). These Pd metal clusters show a small hysteresis from magnetization (M) vs. magnetic field (H) data and insulating behavior from electrical resistivity measurement. The thermopower (S) data shows metallic behavior from Pd cluster. This is the first report of incorporation of Pd nanoparticles inside carbon nanofibers.

Original languageEnglish
Title of host publication2003 Nanotechnology Conference and Trade Show - Nanotech 2003
EditorsM. Laudon, B. Romanowicz
Pages13-16
Number of pages4
Volume3
Publication statusPublished - 2003 Dec 1
Event2003 Nanotechnology Conference and Trade Show - Nanotech 2003 - San Francisco, CA, United States
Duration: 2003 Feb 232003 Feb 27

Other

Other2003 Nanotechnology Conference and Trade Show - Nanotech 2003
CountryUnited States
CitySan Francisco, CA
Period03-02-2303-02-27

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Carbon nanofibers
Catalysts
Diffraction
Metals
Thermoelectric power
Molecular sieves
Acetylene
Chemical analysis
Hysteresis
Magnetization
Electron microscopes
Magnetic fields
Nanoparticles
Decomposition
X rays
Microstructure

All Science Journal Classification (ASJC) codes

  • Engineering(all)

Cite this

Su, C. J., Hsu, L. S., Wu, T. W., Liu, C-J., & Lin, S. H. (2003). Synthesis and characterization of spiral carbon nanofibers containing Pd metal cluster by using Pd2(dba)3 as catalyst. In M. Laudon, & B. Romanowicz (Eds.), 2003 Nanotechnology Conference and Trade Show - Nanotech 2003 (Vol. 3, pp. 13-16)
Su, C. J. ; Hsu, L. S. ; Wu, T. W. ; Liu, Chia-Jyi ; Lin, S. H. / Synthesis and characterization of spiral carbon nanofibers containing Pd metal cluster by using Pd2(dba)3 as catalyst. 2003 Nanotechnology Conference and Trade Show - Nanotech 2003. editor / M. Laudon ; B. Romanowicz. Vol. 3 2003. pp. 13-16
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abstract = "The spiral carbon nanofibers consisting of Pd metal cluster were grown by the Pd2(dba)3-catalyzed decomposition of gaseous acetylene on molecular sieves (Linde 13X) support. The phase and composition of the sample was measured with x-ray diffraction (XRD). The microstructure and composition of the spiral carbon nanofibers were characterized by transmission electron microscope (TEM) and selective area diffraction (SAD). These Pd metal clusters show a small hysteresis from magnetization (M) vs. magnetic field (H) data and insulating behavior from electrical resistivity measurement. The thermopower (S) data shows metallic behavior from Pd cluster. This is the first report of incorporation of Pd nanoparticles inside carbon nanofibers.",
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Su, CJ, Hsu, LS, Wu, TW, Liu, C-J & Lin, SH 2003, Synthesis and characterization of spiral carbon nanofibers containing Pd metal cluster by using Pd2(dba)3 as catalyst. in M Laudon & B Romanowicz (eds), 2003 Nanotechnology Conference and Trade Show - Nanotech 2003. vol. 3, pp. 13-16, 2003 Nanotechnology Conference and Trade Show - Nanotech 2003, San Francisco, CA, United States, 03-02-23.

Synthesis and characterization of spiral carbon nanofibers containing Pd metal cluster by using Pd2(dba)3 as catalyst. / Su, C. J.; Hsu, L. S.; Wu, T. W.; Liu, Chia-Jyi; Lin, S. H.

2003 Nanotechnology Conference and Trade Show - Nanotech 2003. ed. / M. Laudon; B. Romanowicz. Vol. 3 2003. p. 13-16.

Research output: Chapter in Book/Report/Conference proceedingConference contribution

TY - GEN

T1 - Synthesis and characterization of spiral carbon nanofibers containing Pd metal cluster by using Pd2(dba)3 as catalyst

AU - Su, C. J.

AU - Hsu, L. S.

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AU - Liu, Chia-Jyi

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N2 - The spiral carbon nanofibers consisting of Pd metal cluster were grown by the Pd2(dba)3-catalyzed decomposition of gaseous acetylene on molecular sieves (Linde 13X) support. The phase and composition of the sample was measured with x-ray diffraction (XRD). The microstructure and composition of the spiral carbon nanofibers were characterized by transmission electron microscope (TEM) and selective area diffraction (SAD). These Pd metal clusters show a small hysteresis from magnetization (M) vs. magnetic field (H) data and insulating behavior from electrical resistivity measurement. The thermopower (S) data shows metallic behavior from Pd cluster. This is the first report of incorporation of Pd nanoparticles inside carbon nanofibers.

AB - The spiral carbon nanofibers consisting of Pd metal cluster were grown by the Pd2(dba)3-catalyzed decomposition of gaseous acetylene on molecular sieves (Linde 13X) support. The phase and composition of the sample was measured with x-ray diffraction (XRD). The microstructure and composition of the spiral carbon nanofibers were characterized by transmission electron microscope (TEM) and selective area diffraction (SAD). These Pd metal clusters show a small hysteresis from magnetization (M) vs. magnetic field (H) data and insulating behavior from electrical resistivity measurement. The thermopower (S) data shows metallic behavior from Pd cluster. This is the first report of incorporation of Pd nanoparticles inside carbon nanofibers.

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Su CJ, Hsu LS, Wu TW, Liu C-J, Lin SH. Synthesis and characterization of spiral carbon nanofibers containing Pd metal cluster by using Pd2(dba)3 as catalyst. In Laudon M, Romanowicz B, editors, 2003 Nanotechnology Conference and Trade Show - Nanotech 2003. Vol. 3. 2003. p. 13-16