Synthesis and Characterization of Polymeric Ag(I)-Telluroether and Cu(I)-Diorganyl Ditelluride Complexes: Crystal Structures of [Ag(MeTe(CH2)3TeMe)2]n[BF4]n, [(μ2-MeTeTeMe)Cu(μ-Cl)]n, and [Ag2(NCCH3)42-(p-C6H4F)TeTe(p-C6H4F))2][BF4]2

Wen Feng Liaw, Chia Huei Lai, Show Jen Chiou, Yih Chern Horng, Chin Cheng Chou, Ming Chi Liaw, Gene Hsiang Lee, Shie Ming Peng

Research output: Contribution to journalArticle

37 Citations (Scopus)

Abstract

Reaction of ligand MeTe(CH2)3TeMe with AgBF4 in CH3CN produced the light-sensitive polymeric coordination complex [Ag(MeTe(CH2)3TeMe)2]n[BF4]n. This compound crystallized in the monoclinic space group P21/n with a = 8.755(3) Å,b = 20.441(8) Å, c = 12.227(3) Å, β = 103.13(3)°, V= 2130.9(12) Å3, Z = 4, F(000) = 1504. Final R = 0.057 and Rw = 0.062 resulted from refinement of 2776 total reflections with 154 parameters. Reaction of (Te(p-C6H4F))2 and AgBF4 in acetonitrile at ambient temperature generated red, light-sensitive [Ag2(NCCH3)4-(μ2-(p-C6H4F)TeTe(p-C6H4F))2][BF4]2, a homodiorganyl ditelluride doubly-bridged complex. Crystal data: triclinic space group P1, a = 6.835(2) Å, b = 13.255(2) Å, c = 13.824(4) Å, a = 116.48(3)°, β = 95.95(2)°, γ = 98.90(2)°, V= 1086.2(4) Å3, Z = 1, ϱcalcd = 2.165 g cm″3, μ = 36.13 cm−1, F(000) = 668. Refinement of 3807 reflections and 254 parameters gave R = 0.027 and Rw = 0.028. Treatment of (MeTe)2 with CuCl in CH3CN at ambient temperature yielded polymeric [(μ2-MeTeTeMe)Cu(μ-Cl)]n. Crystal data: monoclinic space group P21/ c, a = 9.923(2) Å,b = 8.091(2) Å, c = 10.232(3) Å, β = 116.01(2)°, V = 738.3(3) Å3, Z = 2, F(000) = 668. Refinement of 949 reflections and 56 parameters gave R = 0.027 and Rw= 0.025.

Original languageEnglish
Pages (from-to)3755-3759
Number of pages5
JournalInorganic Chemistry
Volume34
Issue number14
DOIs
Publication statusPublished - 1995 Jul 1

Fingerprint

Crystal structure
crystal structure
ambient temperature
synthesis
Crystals
Coordination Complexes
acetonitrile
crystals
Ligands
Temperature
ligands

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

Cite this

@article{a3eaeb26513f432490dc3eb3b59acf96,
title = "Synthesis and Characterization of Polymeric Ag(I)-Telluroether and Cu(I)-Diorganyl Ditelluride Complexes: Crystal Structures of [Ag(MeTe(CH2)3TeMe)2]n[BF4]n, [(μ2-MeTeTeMe)Cu(μ-Cl)]n, and [Ag2(NCCH3)4(μ2-(p-C6H4F)TeTe(p-C6H4F))2][BF4]2",
abstract = "Reaction of ligand MeTe(CH2)3TeMe with AgBF4 in CH3CN produced the light-sensitive polymeric coordination complex [Ag(MeTe(CH2)3TeMe)2]n[BF4]n. This compound crystallized in the monoclinic space group P21/n with a = 8.755(3) {\AA},b = 20.441(8) {\AA}, c = 12.227(3) {\AA}, β = 103.13(3)°, V= 2130.9(12) {\AA}3, Z = 4, F(000) = 1504. Final R = 0.057 and Rw = 0.062 resulted from refinement of 2776 total reflections with 154 parameters. Reaction of (Te(p-C6H4F))2 and AgBF4 in acetonitrile at ambient temperature generated red, light-sensitive [Ag2(NCCH3)4-(μ2-(p-C6H4F)TeTe(p-C6H4F))2][BF4]2, a homodiorganyl ditelluride doubly-bridged complex. Crystal data: triclinic space group P1, a = 6.835(2) {\AA}, b = 13.255(2) {\AA}, c = 13.824(4) {\AA}, a = 116.48(3)°, β = 95.95(2)°, γ = 98.90(2)°, V= 1086.2(4) {\AA}3, Z = 1, ϱcalcd = 2.165 g cm″3, μ = 36.13 cm−1, F(000) = 668. Refinement of 3807 reflections and 254 parameters gave R = 0.027 and Rw = 0.028. Treatment of (MeTe)2 with CuCl in CH3CN at ambient temperature yielded polymeric [(μ2-MeTeTeMe)Cu(μ-Cl)]n. Crystal data: monoclinic space group P21/ c, a = 9.923(2) {\AA},b = 8.091(2) {\AA}, c = 10.232(3) {\AA}, β = 116.01(2)°, V = 738.3(3) {\AA}3, Z = 2, F(000) = 668. Refinement of 949 reflections and 56 parameters gave R = 0.027 and Rw= 0.025.",
author = "Liaw, {Wen Feng} and Lai, {Chia Huei} and Chiou, {Show Jen} and Horng, {Yih Chern} and Chou, {Chin Cheng} and Liaw, {Ming Chi} and Lee, {Gene Hsiang} and Peng, {Shie Ming}",
year = "1995",
month = "7",
day = "1",
doi = "10.1021/ic00118a024",
language = "English",
volume = "34",
pages = "3755--3759",
journal = "Inorganic Chemistry",
issn = "0020-1669",
publisher = "American Chemical Society",
number = "14",

}

Synthesis and Characterization of Polymeric Ag(I)-Telluroether and Cu(I)-Diorganyl Ditelluride Complexes : Crystal Structures of [Ag(MeTe(CH2)3TeMe)2]n[BF4]n, [(μ2-MeTeTeMe)Cu(μ-Cl)]n, and [Ag2(NCCH3)42-(p-C6H4F)TeTe(p-C6H4F))2][BF4]2. / Liaw, Wen Feng; Lai, Chia Huei; Chiou, Show Jen; Horng, Yih Chern; Chou, Chin Cheng; Liaw, Ming Chi; Lee, Gene Hsiang; Peng, Shie Ming.

In: Inorganic Chemistry, Vol. 34, No. 14, 01.07.1995, p. 3755-3759.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Synthesis and Characterization of Polymeric Ag(I)-Telluroether and Cu(I)-Diorganyl Ditelluride Complexes

T2 - Crystal Structures of [Ag(MeTe(CH2)3TeMe)2]n[BF4]n, [(μ2-MeTeTeMe)Cu(μ-Cl)]n, and [Ag2(NCCH3)4(μ2-(p-C6H4F)TeTe(p-C6H4F))2][BF4]2

AU - Liaw, Wen Feng

AU - Lai, Chia Huei

AU - Chiou, Show Jen

AU - Horng, Yih Chern

AU - Chou, Chin Cheng

AU - Liaw, Ming Chi

AU - Lee, Gene Hsiang

AU - Peng, Shie Ming

PY - 1995/7/1

Y1 - 1995/7/1

N2 - Reaction of ligand MeTe(CH2)3TeMe with AgBF4 in CH3CN produced the light-sensitive polymeric coordination complex [Ag(MeTe(CH2)3TeMe)2]n[BF4]n. This compound crystallized in the monoclinic space group P21/n with a = 8.755(3) Å,b = 20.441(8) Å, c = 12.227(3) Å, β = 103.13(3)°, V= 2130.9(12) Å3, Z = 4, F(000) = 1504. Final R = 0.057 and Rw = 0.062 resulted from refinement of 2776 total reflections with 154 parameters. Reaction of (Te(p-C6H4F))2 and AgBF4 in acetonitrile at ambient temperature generated red, light-sensitive [Ag2(NCCH3)4-(μ2-(p-C6H4F)TeTe(p-C6H4F))2][BF4]2, a homodiorganyl ditelluride doubly-bridged complex. Crystal data: triclinic space group P1, a = 6.835(2) Å, b = 13.255(2) Å, c = 13.824(4) Å, a = 116.48(3)°, β = 95.95(2)°, γ = 98.90(2)°, V= 1086.2(4) Å3, Z = 1, ϱcalcd = 2.165 g cm″3, μ = 36.13 cm−1, F(000) = 668. Refinement of 3807 reflections and 254 parameters gave R = 0.027 and Rw = 0.028. Treatment of (MeTe)2 with CuCl in CH3CN at ambient temperature yielded polymeric [(μ2-MeTeTeMe)Cu(μ-Cl)]n. Crystal data: monoclinic space group P21/ c, a = 9.923(2) Å,b = 8.091(2) Å, c = 10.232(3) Å, β = 116.01(2)°, V = 738.3(3) Å3, Z = 2, F(000) = 668. Refinement of 949 reflections and 56 parameters gave R = 0.027 and Rw= 0.025.

AB - Reaction of ligand MeTe(CH2)3TeMe with AgBF4 in CH3CN produced the light-sensitive polymeric coordination complex [Ag(MeTe(CH2)3TeMe)2]n[BF4]n. This compound crystallized in the monoclinic space group P21/n with a = 8.755(3) Å,b = 20.441(8) Å, c = 12.227(3) Å, β = 103.13(3)°, V= 2130.9(12) Å3, Z = 4, F(000) = 1504. Final R = 0.057 and Rw = 0.062 resulted from refinement of 2776 total reflections with 154 parameters. Reaction of (Te(p-C6H4F))2 and AgBF4 in acetonitrile at ambient temperature generated red, light-sensitive [Ag2(NCCH3)4-(μ2-(p-C6H4F)TeTe(p-C6H4F))2][BF4]2, a homodiorganyl ditelluride doubly-bridged complex. Crystal data: triclinic space group P1, a = 6.835(2) Å, b = 13.255(2) Å, c = 13.824(4) Å, a = 116.48(3)°, β = 95.95(2)°, γ = 98.90(2)°, V= 1086.2(4) Å3, Z = 1, ϱcalcd = 2.165 g cm″3, μ = 36.13 cm−1, F(000) = 668. Refinement of 3807 reflections and 254 parameters gave R = 0.027 and Rw = 0.028. Treatment of (MeTe)2 with CuCl in CH3CN at ambient temperature yielded polymeric [(μ2-MeTeTeMe)Cu(μ-Cl)]n. Crystal data: monoclinic space group P21/ c, a = 9.923(2) Å,b = 8.091(2) Å, c = 10.232(3) Å, β = 116.01(2)°, V = 738.3(3) Å3, Z = 2, F(000) = 668. Refinement of 949 reflections and 56 parameters gave R = 0.027 and Rw= 0.025.

UR - http://www.scopus.com/inward/record.url?scp=0000320651&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0000320651&partnerID=8YFLogxK

U2 - 10.1021/ic00118a024

DO - 10.1021/ic00118a024

M3 - Article

AN - SCOPUS:0000320651

VL - 34

SP - 3755

EP - 3759

JO - Inorganic Chemistry

JF - Inorganic Chemistry

SN - 0020-1669

IS - 14

ER -