Abstract
A series of ruthenium compounds containing a pyrrole-ketone bidentate ligand, 2-(2-methoxybenzoyl)pyrrole (1), have been synthesized and characterized. Reacting 1 with [(η6-cymene)RuCl2]2 and RuHCl(CO)(PPh3)3 generated Ru(η6-cymene)[C4H3N-2-(CO-C6H4-2-OMe)]Cl (2) and {RuCl(CO)(PPh3)2[C4H3N-2-(COC6H4-2-OMe)]} (3), respectively, in moderate yields. Successively reacting 2 with sodium cyanate and sodium azide gave {Ru(η6-cymene)[C4H3N-2-(CO-C6H4-2-OMe)]X} (4, X=OCN; 5, X=N3) with the elimination of sodium chloride. Compounds 2–5 were all characterized by1H and13C-NMR spectra and their structures were also determined by X-ray single crystallography.
Original language | English |
---|---|
Article number | 159 |
Journal | Molecules |
Volume | 23 |
Issue number | 1 |
DOIs | |
Publication status | Published - 2018 Jan 1 |
Fingerprint
All Science Journal Classification (ASJC) codes
- Analytical Chemistry
- Chemistry (miscellaneous)
- Molecular Medicine
- Pharmaceutical Science
- Drug Discovery
- Physical and Theoretical Chemistry
- Organic Chemistry
Cite this
}
Structural determination of ruthenium complexes containing bi-dentate pyrrole-ketone ligands. / Tsai, Ya Wen; Chen, Yun Fan; Li, Yong Jie; Chen, Kuan Hung; Lin, Chia Her; Huang, Jui Hsien.
In: Molecules, Vol. 23, No. 1, 159, 01.01.2018.Research output: Contribution to journal › Article
TY - JOUR
T1 - Structural determination of ruthenium complexes containing bi-dentate pyrrole-ketone ligands
AU - Tsai, Ya Wen
AU - Chen, Yun Fan
AU - Li, Yong Jie
AU - Chen, Kuan Hung
AU - Lin, Chia Her
AU - Huang, Jui Hsien
PY - 2018/1/1
Y1 - 2018/1/1
N2 - A series of ruthenium compounds containing a pyrrole-ketone bidentate ligand, 2-(2-methoxybenzoyl)pyrrole (1), have been synthesized and characterized. Reacting 1 with [(η6-cymene)RuCl2]2 and RuHCl(CO)(PPh3)3 generated Ru(η6-cymene)[C4H3N-2-(CO-C6H4-2-OMe)]Cl (2) and {RuCl(CO)(PPh3)2[C4H3N-2-(COC6H4-2-OMe)]} (3), respectively, in moderate yields. Successively reacting 2 with sodium cyanate and sodium azide gave {Ru(η6-cymene)[C4H3N-2-(CO-C6H4-2-OMe)]X} (4, X=OCN; 5, X=N3) with the elimination of sodium chloride. Compounds 2–5 were all characterized by1H and13C-NMR spectra and their structures were also determined by X-ray single crystallography.
AB - A series of ruthenium compounds containing a pyrrole-ketone bidentate ligand, 2-(2-methoxybenzoyl)pyrrole (1), have been synthesized and characterized. Reacting 1 with [(η6-cymene)RuCl2]2 and RuHCl(CO)(PPh3)3 generated Ru(η6-cymene)[C4H3N-2-(CO-C6H4-2-OMe)]Cl (2) and {RuCl(CO)(PPh3)2[C4H3N-2-(COC6H4-2-OMe)]} (3), respectively, in moderate yields. Successively reacting 2 with sodium cyanate and sodium azide gave {Ru(η6-cymene)[C4H3N-2-(CO-C6H4-2-OMe)]X} (4, X=OCN; 5, X=N3) with the elimination of sodium chloride. Compounds 2–5 were all characterized by1H and13C-NMR spectra and their structures were also determined by X-ray single crystallography.
UR - http://www.scopus.com/inward/record.url?scp=85040534089&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=85040534089&partnerID=8YFLogxK
U2 - 10.3390/molecules23010159
DO - 10.3390/molecules23010159
M3 - Article
C2 - 29342833
AN - SCOPUS:85040534089
VL - 23
JO - Molecules
JF - Molecules
SN - 1420-3049
IS - 1
M1 - 159
ER -