Structural and spectroscopic characterization of a monomeric side-on manganese(IV) peroxo complex

Chien Ming Lee, Chi He Chuo, Ching Hui Chen, Cho Chun Hu, Ming Hsi Chiang, Yu Jan Tseng, Ching Han Hu, Gene Hsiang Lee

Research output: Contribution to journalArticle

23 Citations (Scopus)

Abstract

Gotcha: The binding and activation of oxygen by a manganese complex is reported. A PS 3 coordination sphere built around a manganese(I) center facilitates the isolation of a monomeric manganese(IV) peroxo complex that is stable at ambient temperature (see picture). The activation of molecular oxygen is proposed via a manganese(II) intermediate with an empty site for the binding of the substrate.

Original languageEnglish
Pages (from-to)5427-5430
Number of pages4
JournalAngewandte Chemie - International Edition
Volume51
Issue number22
DOIs
Publication statusPublished - 2012 May 29

Fingerprint

Manganese
Chemical activation
Molecular oxygen
Binding Sites
Oxygen
Substrates
Temperature

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

Cite this

Lee, C. M., Chuo, C. H., Chen, C. H., Hu, C. C., Chiang, M. H., Tseng, Y. J., ... Lee, G. H. (2012). Structural and spectroscopic characterization of a monomeric side-on manganese(IV) peroxo complex. Angewandte Chemie - International Edition, 51(22), 5427-5430. https://doi.org/10.1002/anie.201201735
Lee, Chien Ming ; Chuo, Chi He ; Chen, Ching Hui ; Hu, Cho Chun ; Chiang, Ming Hsi ; Tseng, Yu Jan ; Hu, Ching Han ; Lee, Gene Hsiang. / Structural and spectroscopic characterization of a monomeric side-on manganese(IV) peroxo complex. In: Angewandte Chemie - International Edition. 2012 ; Vol. 51, No. 22. pp. 5427-5430.
@article{7242d744ece04307a30fa735bc1ccefc,
title = "Structural and spectroscopic characterization of a monomeric side-on manganese(IV) peroxo complex",
abstract = "Gotcha: The binding and activation of oxygen by a manganese complex is reported. A PS 3 coordination sphere built around a manganese(I) center facilitates the isolation of a monomeric manganese(IV) peroxo complex that is stable at ambient temperature (see picture). The activation of molecular oxygen is proposed via a manganese(II) intermediate with an empty site for the binding of the substrate.",
author = "Lee, {Chien Ming} and Chuo, {Chi He} and Chen, {Ching Hui} and Hu, {Cho Chun} and Chiang, {Ming Hsi} and Tseng, {Yu Jan} and Hu, {Ching Han} and Lee, {Gene Hsiang}",
year = "2012",
month = "5",
day = "29",
doi = "10.1002/anie.201201735",
language = "English",
volume = "51",
pages = "5427--5430",
journal = "Angewandte Chemie - International Edition",
issn = "1433-7851",
publisher = "John Wiley and Sons Ltd",
number = "22",

}

Structural and spectroscopic characterization of a monomeric side-on manganese(IV) peroxo complex. / Lee, Chien Ming; Chuo, Chi He; Chen, Ching Hui; Hu, Cho Chun; Chiang, Ming Hsi; Tseng, Yu Jan; Hu, Ching Han; Lee, Gene Hsiang.

In: Angewandte Chemie - International Edition, Vol. 51, No. 22, 29.05.2012, p. 5427-5430.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Structural and spectroscopic characterization of a monomeric side-on manganese(IV) peroxo complex

AU - Lee, Chien Ming

AU - Chuo, Chi He

AU - Chen, Ching Hui

AU - Hu, Cho Chun

AU - Chiang, Ming Hsi

AU - Tseng, Yu Jan

AU - Hu, Ching Han

AU - Lee, Gene Hsiang

PY - 2012/5/29

Y1 - 2012/5/29

N2 - Gotcha: The binding and activation of oxygen by a manganese complex is reported. A PS 3 coordination sphere built around a manganese(I) center facilitates the isolation of a monomeric manganese(IV) peroxo complex that is stable at ambient temperature (see picture). The activation of molecular oxygen is proposed via a manganese(II) intermediate with an empty site for the binding of the substrate.

AB - Gotcha: The binding and activation of oxygen by a manganese complex is reported. A PS 3 coordination sphere built around a manganese(I) center facilitates the isolation of a monomeric manganese(IV) peroxo complex that is stable at ambient temperature (see picture). The activation of molecular oxygen is proposed via a manganese(II) intermediate with an empty site for the binding of the substrate.

UR - http://www.scopus.com/inward/record.url?scp=84861487229&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84861487229&partnerID=8YFLogxK

U2 - 10.1002/anie.201201735

DO - 10.1002/anie.201201735

M3 - Article

C2 - 22511384

AN - SCOPUS:84861487229

VL - 51

SP - 5427

EP - 5430

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

SN - 1433-7851

IS - 22

ER -