Structural and spectroscopic characterization of a monomeric side-on manganese(IV) peroxo complex

Chien Ming Lee; Chi He Chuo; Ching Hui Chen; Cho Chun Hu; Ming Hsi Chiang; Yu Jan Tseng; Ching Han Hu; Gene Hsiang Lee

doi:10.1002/anie.201201735

Structural and spectroscopic characterization of a monomeric side-on manganese(IV) peroxo complex

Chien Ming Lee, Chi He Chuo, Ching Hui Chen, Cho Chun Hu, Ming Hsi Chiang, Yu Jan Tseng, Ching Han Hu, Gene Hsiang Lee

Department of Chemistry

Research output: Contribution to journal › Article

25 Citations (Scopus)

Abstract

Gotcha: The binding and activation of oxygen by a manganese complex is reported. A PS ₃ coordination sphere built around a manganese(I) center facilitates the isolation of a monomeric manganese(IV) peroxo complex that is stable at ambient temperature (see picture). The activation of molecular oxygen is proposed via a manganese(II) intermediate with an empty site for the binding of the substrate.

Original language	English
Pages (from-to)	5427-5430
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	51
Issue number	22
DOIs	https://doi.org/10.1002/anie.201201735
Publication status	Published - 2012 May 29

All Science Journal Classification (ASJC) codes

Catalysis
Chemistry(all)

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10.1002/anie.201201735

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Lee, C. M., Chuo, C. H., Chen, C. H., Hu, C. C., Chiang, M. H., Tseng, Y. J., Hu, C. H., & Lee, G. H. (2012). Structural and spectroscopic characterization of a monomeric side-on manganese(IV) peroxo complex. Angewandte Chemie - International Edition, 51(22), 5427-5430. https://doi.org/10.1002/anie.201201735

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abstract = "Gotcha: The binding and activation of oxygen by a manganese complex is reported. A PS 3 coordination sphere built around a manganese(I) center facilitates the isolation of a monomeric manganese(IV) peroxo complex that is stable at ambient temperature (see picture). The activation of molecular oxygen is proposed via a manganese(II) intermediate with an empty site for the binding of the substrate.",

author = "Lee, {Chien Ming} and Chuo, {Chi He} and Chen, {Ching Hui} and Hu, {Cho Chun} and Chiang, {Ming Hsi} and Tseng, {Yu Jan} and Hu, {Ching Han} and Lee, {Gene Hsiang}",

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Structural and spectroscopic characterization of a monomeric side-on manganese(IV) peroxo complex. / Lee, Chien Ming; Chuo, Chi He; Chen, Ching Hui; Hu, Cho Chun; Chiang, Ming Hsi; Tseng, Yu Jan; Hu, Ching Han; Lee, Gene Hsiang.

In: Angewandte Chemie - International Edition, Vol. 51, No. 22, 29.05.2012, p. 5427-5430.

Research output: Contribution to journal › Article

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