Structural and spectroscopic characterization of a monomeric side-on manganese(IV) peroxo complex

Chien Ming Lee, Chi He Chuo, Ching Hui Chen, Cho Chun Hu, Ming Hsi Chiang, Yu Jan Tseng, Ching Han Hu, Gene Hsiang Lee

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Abstract

Gotcha: The binding and activation of oxygen by a manganese complex is reported. A PS 3 coordination sphere built around a manganese(I) center facilitates the isolation of a monomeric manganese(IV) peroxo complex that is stable at ambient temperature (see picture). The activation of molecular oxygen is proposed via a manganese(II) intermediate with an empty site for the binding of the substrate.

Original languageEnglish
Pages (from-to)5427-5430
Number of pages4
JournalAngewandte Chemie - International Edition
Volume51
Issue number22
DOIs
Publication statusPublished - 2012 May 29

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All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

Cite this

Lee, C. M., Chuo, C. H., Chen, C. H., Hu, C. C., Chiang, M. H., Tseng, Y. J., ... Lee, G. H. (2012). Structural and spectroscopic characterization of a monomeric side-on manganese(IV) peroxo complex. Angewandte Chemie - International Edition, 51(22), 5427-5430. https://doi.org/10.1002/anie.201201735