Abstract
Gotcha: The binding and activation of oxygen by a manganese complex is reported. A PS 3 coordination sphere built around a manganese(I) center facilitates the isolation of a monomeric manganese(IV) peroxo complex that is stable at ambient temperature (see picture). The activation of molecular oxygen is proposed via a manganese(II) intermediate with an empty site for the binding of the substrate.
| Original language | English |
|---|---|
| Pages (from-to) | 5427-5430 |
| Number of pages | 4 |
| Journal | Angewandte Chemie - International Edition |
| Volume | 51 |
| Issue number | 22 |
| DOIs | |
| Publication status | Published - 2012 May 29 |
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All Science Journal Classification (ASJC) codes
- Catalysis
- Chemistry(all)
Cite this
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Structural and spectroscopic characterization of a monomeric side-on manganese(IV) peroxo complex. / Lee, Chien Ming; Chuo, Chi He; Chen, Ching Hui; Hu, Cho Chun; Chiang, Ming Hsi; Tseng, Yu Jan; Hu, Ching Han; Lee, Gene Hsiang.
In: Angewandte Chemie - International Edition, Vol. 51, No. 22, 29.05.2012, p. 5427-5430.Research output: Contribution to journal › Article
TY - JOUR
T1 - Structural and spectroscopic characterization of a monomeric side-on manganese(IV) peroxo complex
AU - Lee, Chien Ming
AU - Chuo, Chi He
AU - Chen, Ching Hui
AU - Hu, Cho Chun
AU - Chiang, Ming Hsi
AU - Tseng, Yu Jan
AU - Hu, Ching Han
AU - Lee, Gene Hsiang
PY - 2012/5/29
Y1 - 2012/5/29
N2 - Gotcha: The binding and activation of oxygen by a manganese complex is reported. A PS 3 coordination sphere built around a manganese(I) center facilitates the isolation of a monomeric manganese(IV) peroxo complex that is stable at ambient temperature (see picture). The activation of molecular oxygen is proposed via a manganese(II) intermediate with an empty site for the binding of the substrate.
AB - Gotcha: The binding and activation of oxygen by a manganese complex is reported. A PS 3 coordination sphere built around a manganese(I) center facilitates the isolation of a monomeric manganese(IV) peroxo complex that is stable at ambient temperature (see picture). The activation of molecular oxygen is proposed via a manganese(II) intermediate with an empty site for the binding of the substrate.
UR - http://www.scopus.com/inward/record.url?scp=84861487229&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84861487229&partnerID=8YFLogxK
U2 - 10.1002/anie.201201735
DO - 10.1002/anie.201201735
M3 - Article
C2 - 22511384
AN - SCOPUS:84861487229
VL - 51
SP - 5427
EP - 5430
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
SN - 1433-7851
IS - 22
ER -