Rhenium(I) Tellurolate, Telluroether and Bidentate‐Telluroether Complexes: Crystal Structures of Re(CO)3Br(PhTe(CH2)3TePh), PhTeRe(CO)5 Re2(μ‐SePh)2(CO)8 and [(PhTeMe)Re(CO)5][BF4]

Wen‐Feng ‐F Liaw, Yih‐Chern ‐C Horng, Der‐Shiaw ‐S On, Chin‐Yuan ‐Y Chuang, Chen‐Kang ‐K Lee, Gene‐Hsiang ‐H Lee, Shie‐Ming ‐M Peng

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Abstract

The monomeric rhenium(I) complex with bidentate telluroether ligand Re(CO)3Br(PhTe(CH2)3TePh) (1) was accessible via reaction of the PhTe(CH2)3TePh with Re(CO)5Br. This chelate complex crystallized in triclinic space group \documentclass{article}\pagestyle{empty}\begin{document}$ {\rm P}\bar 1 $\end{document} with a = 9.390(5) Å, b = 10.961(3) Å, c = 11.849(4) Å a = 63.30(3)°, β = 87.49(4)° γ = 69.31(4)°, V = 1009.5(7) Å3 Z = 2, R = 0.033, and Rw = 0.034. Reaction of Re(CO)5Cl with NaTePh yielded the Re(I) specics PhTeRe(CO)5 (2). This complex crystallized in triclinic space group \documentclass{article}\pagestyle{empty}\begin{document}$ {\rm P}\bar 1 $\end{document} with a = 7.085(1) Å, b = 9.203(1) Å, c = 11.341(1) Å, α = 107.24(1)°, β = 100.56(1)°, γ = 96.47(1)°, V = 683.2(2) Å3, Z = 2, R = 0.027, Rw = 0.022. Reaction of PhTeRe(CO)5 and (PhSe)2 in THF at 65 °C yielded a product that was confirmed crystallographically to be the known species Re2(μ‐SePh)2(CO)8 (3), in which two phenylselenolate ligands bridge the two Re(I). Compound 3 crystallized in monoclinic space group P21/n with a = 7.210(2) Å, b = 18.862(6) Å, c = 9.083(3) Å, β = 107.48(3)° V = 1178.2(7) Å3, Z = 2, R = 0.046, and Rw = 0.051. Methylation of PhTeRe(CO)5 with [Me3O][BF4] afforded Re(I) product [(PhTeMe)Re(CO)5][BF4] (4). This monodentate telluroether species crystallized in monoclinic space group P21/n with a = 8.405(1) Å, b = 13.438(3) Å, c = 15.560(2) Å, β = 92.59(1)° V = 1755.5(5) Å3, Z = 4, R = 0.035, and Rw = 0.035.

Original languageEnglish
Pages (from-to)59-65
Number of pages7
JournalJournal of the Chinese Chemical Society
Volume42
Issue number1
DOIs
Publication statusPublished - 1995 Feb

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Rhenium
Carbon Monoxide
Crystal structure
Ligands
Methylation

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

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Liaw, Wen‐Feng ‐F ; Horng, Yih‐Chern ‐C ; On, Der‐Shiaw ‐S ; Chuang, Chin‐Yuan ‐Y ; Lee, Chen‐Kang ‐K ; Lee, Gene‐Hsiang ‐H ; Peng, Shie‐Ming ‐M. / Rhenium(I) Tellurolate, Telluroether and Bidentate‐Telluroether Complexes : Crystal Structures of Re(CO)3Br(PhTe(CH2)3TePh), PhTeRe(CO)5 Re2(μ‐SePh)2(CO)8 and [(PhTeMe)Re(CO)5][BF4]. In: Journal of the Chinese Chemical Society. 1995 ; Vol. 42, No. 1. pp. 59-65.
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title = "Rhenium(I) Tellurolate, Telluroether and Bidentate‐Telluroether Complexes: Crystal Structures of Re(CO)3Br(PhTe(CH2)3TePh), PhTeRe(CO)5 Re2(μ‐SePh)2(CO)8 and [(PhTeMe)Re(CO)5][BF4]",
abstract = "The monomeric rhenium(I) complex with bidentate telluroether ligand Re(CO)3Br(PhTe(CH2)3TePh) (1) was accessible via reaction of the PhTe(CH2)3TePh with Re(CO)5Br. This chelate complex crystallized in triclinic space group \documentclass{article}\pagestyle{empty}\begin{document}$ {\rm P}\bar 1 $\end{document} with a = 9.390(5) {\AA}, b = 10.961(3) {\AA}, c = 11.849(4) {\AA} a = 63.30(3)°, β = 87.49(4)° γ = 69.31(4)°, V = 1009.5(7) {\AA}3 Z = 2, R = 0.033, and Rw = 0.034. Reaction of Re(CO)5Cl with NaTePh yielded the Re(I) specics PhTeRe(CO)5 (2). This complex crystallized in triclinic space group \documentclass{article}\pagestyle{empty}\begin{document}$ {\rm P}\bar 1 $\end{document} with a = 7.085(1) {\AA}, b = 9.203(1) {\AA}, c = 11.341(1) {\AA}, α = 107.24(1)°, β = 100.56(1)°, γ = 96.47(1)°, V = 683.2(2) {\AA}3, Z = 2, R = 0.027, Rw = 0.022. Reaction of PhTeRe(CO)5 and (PhSe)2 in THF at 65 °C yielded a product that was confirmed crystallographically to be the known species Re2(μ‐SePh)2(CO)8 (3), in which two phenylselenolate ligands bridge the two Re(I). Compound 3 crystallized in monoclinic space group P21/n with a = 7.210(2) {\AA}, b = 18.862(6) {\AA}, c = 9.083(3) {\AA}, β = 107.48(3)° V = 1178.2(7) {\AA}3, Z = 2, R = 0.046, and Rw = 0.051. Methylation of PhTeRe(CO)5 with [Me3O][BF4] afforded Re(I) product [(PhTeMe)Re(CO)5][BF4] (4). This monodentate telluroether species crystallized in monoclinic space group P21/n with a = 8.405(1) {\AA}, b = 13.438(3) {\AA}, c = 15.560(2) {\AA}, β = 92.59(1)° V = 1755.5(5) {\AA}3, Z = 4, R = 0.035, and Rw = 0.035.",
author = "Liaw, {Wen‐Feng ‐F} and Horng, {Yih‐Chern ‐C} and On, {Der‐Shiaw ‐S} and Chuang, {Chin‐Yuan ‐Y} and Lee, {Chen‐Kang ‐K} and Lee, {Gene‐Hsiang ‐H} and Peng, {Shie‐Ming ‐M}",
year = "1995",
month = "2",
doi = "10.1002/jccs.199500010",
language = "English",
volume = "42",
pages = "59--65",
journal = "Journal of the Chinese Chemical Society",
issn = "0009-4536",
publisher = "Chinese Chemical Society",
number = "1",

}

Rhenium(I) Tellurolate, Telluroether and Bidentate‐Telluroether Complexes : Crystal Structures of Re(CO)3Br(PhTe(CH2)3TePh), PhTeRe(CO)5 Re2(μ‐SePh)2(CO)8 and [(PhTeMe)Re(CO)5][BF4]. / Liaw, Wen‐Feng ‐F; Horng, Yih‐Chern ‐C; On, Der‐Shiaw ‐S; Chuang, Chin‐Yuan ‐Y; Lee, Chen‐Kang ‐K; Lee, Gene‐Hsiang ‐H; Peng, Shie‐Ming ‐M.

In: Journal of the Chinese Chemical Society, Vol. 42, No. 1, 02.1995, p. 59-65.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Rhenium(I) Tellurolate, Telluroether and Bidentate‐Telluroether Complexes

T2 - Crystal Structures of Re(CO)3Br(PhTe(CH2)3TePh), PhTeRe(CO)5 Re2(μ‐SePh)2(CO)8 and [(PhTeMe)Re(CO)5][BF4]

AU - Liaw, Wen‐Feng ‐F

AU - Horng, Yih‐Chern ‐C

AU - On, Der‐Shiaw ‐S

AU - Chuang, Chin‐Yuan ‐Y

AU - Lee, Chen‐Kang ‐K

AU - Lee, Gene‐Hsiang ‐H

AU - Peng, Shie‐Ming ‐M

PY - 1995/2

Y1 - 1995/2

N2 - The monomeric rhenium(I) complex with bidentate telluroether ligand Re(CO)3Br(PhTe(CH2)3TePh) (1) was accessible via reaction of the PhTe(CH2)3TePh with Re(CO)5Br. This chelate complex crystallized in triclinic space group \documentclass{article}\pagestyle{empty}\begin{document}$ {\rm P}\bar 1 $\end{document} with a = 9.390(5) Å, b = 10.961(3) Å, c = 11.849(4) Å a = 63.30(3)°, β = 87.49(4)° γ = 69.31(4)°, V = 1009.5(7) Å3 Z = 2, R = 0.033, and Rw = 0.034. Reaction of Re(CO)5Cl with NaTePh yielded the Re(I) specics PhTeRe(CO)5 (2). This complex crystallized in triclinic space group \documentclass{article}\pagestyle{empty}\begin{document}$ {\rm P}\bar 1 $\end{document} with a = 7.085(1) Å, b = 9.203(1) Å, c = 11.341(1) Å, α = 107.24(1)°, β = 100.56(1)°, γ = 96.47(1)°, V = 683.2(2) Å3, Z = 2, R = 0.027, Rw = 0.022. Reaction of PhTeRe(CO)5 and (PhSe)2 in THF at 65 °C yielded a product that was confirmed crystallographically to be the known species Re2(μ‐SePh)2(CO)8 (3), in which two phenylselenolate ligands bridge the two Re(I). Compound 3 crystallized in monoclinic space group P21/n with a = 7.210(2) Å, b = 18.862(6) Å, c = 9.083(3) Å, β = 107.48(3)° V = 1178.2(7) Å3, Z = 2, R = 0.046, and Rw = 0.051. Methylation of PhTeRe(CO)5 with [Me3O][BF4] afforded Re(I) product [(PhTeMe)Re(CO)5][BF4] (4). This monodentate telluroether species crystallized in monoclinic space group P21/n with a = 8.405(1) Å, b = 13.438(3) Å, c = 15.560(2) Å, β = 92.59(1)° V = 1755.5(5) Å3, Z = 4, R = 0.035, and Rw = 0.035.

AB - The monomeric rhenium(I) complex with bidentate telluroether ligand Re(CO)3Br(PhTe(CH2)3TePh) (1) was accessible via reaction of the PhTe(CH2)3TePh with Re(CO)5Br. This chelate complex crystallized in triclinic space group \documentclass{article}\pagestyle{empty}\begin{document}$ {\rm P}\bar 1 $\end{document} with a = 9.390(5) Å, b = 10.961(3) Å, c = 11.849(4) Å a = 63.30(3)°, β = 87.49(4)° γ = 69.31(4)°, V = 1009.5(7) Å3 Z = 2, R = 0.033, and Rw = 0.034. Reaction of Re(CO)5Cl with NaTePh yielded the Re(I) specics PhTeRe(CO)5 (2). This complex crystallized in triclinic space group \documentclass{article}\pagestyle{empty}\begin{document}$ {\rm P}\bar 1 $\end{document} with a = 7.085(1) Å, b = 9.203(1) Å, c = 11.341(1) Å, α = 107.24(1)°, β = 100.56(1)°, γ = 96.47(1)°, V = 683.2(2) Å3, Z = 2, R = 0.027, Rw = 0.022. Reaction of PhTeRe(CO)5 and (PhSe)2 in THF at 65 °C yielded a product that was confirmed crystallographically to be the known species Re2(μ‐SePh)2(CO)8 (3), in which two phenylselenolate ligands bridge the two Re(I). Compound 3 crystallized in monoclinic space group P21/n with a = 7.210(2) Å, b = 18.862(6) Å, c = 9.083(3) Å, β = 107.48(3)° V = 1178.2(7) Å3, Z = 2, R = 0.046, and Rw = 0.051. Methylation of PhTeRe(CO)5 with [Me3O][BF4] afforded Re(I) product [(PhTeMe)Re(CO)5][BF4] (4). This monodentate telluroether species crystallized in monoclinic space group P21/n with a = 8.405(1) Å, b = 13.438(3) Å, c = 15.560(2) Å, β = 92.59(1)° V = 1755.5(5) Å3, Z = 4, R = 0.035, and Rw = 0.035.

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