Preparation and catalytic hydrogenation properties of some rhodium and ruthenium complexes with chiral tridentate phosphine ligands (S,S)-PhP(CH2CHMeCH2PPh2)2 and (S)-Ph2PCH2CH(PPh2)CH2CH 2PPh2)

Hon Man Lee, Chuluo Yang, Guochen Jia

Research output: Contribution to journalArticle

12 Citations (Scopus)

Abstract

Treatment of RhCl(ttp*) (ttp*=(S,S)-PhP(CH2CHMeCH2PPh2) 2) with NaBH4 produced Rh(BH4)(ttp*). The reaction of RuCl2(ttp*) with NaBH4 produced RuH(BH4)(ttp*). The complexes RhCl(ttp*), RuCl2(ttp*), Rh(BH4)(ttp*), and RuH(BH4)(ttp*) were found to be catalytically active for the hydrogenation of α-acetamidocinnamic acid.

Original languageEnglish
Pages (from-to)330-334
Number of pages5
JournalJournal of Organometallic Chemistry
Volume601
Issue number2
DOIs
Publication statusPublished - 2000 Apr 28

Fingerprint

phosphine
Rhodium
Hydrogenation
Ruthenium
rhodium
phosphines
ruthenium
hydrogenation
Ligands
preparation
ligands
acids
Acids

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

Cite this

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title = "Preparation and catalytic hydrogenation properties of some rhodium and ruthenium complexes with chiral tridentate phosphine ligands (S,S)-PhP(CH2CHMeCH2PPh2)2 and (S)-Ph2PCH2CH(PPh2)CH2CH 2PPh2)",
abstract = "Treatment of RhCl(ttp*) (ttp*=(S,S)-PhP(CH2CHMeCH2PPh2) 2) with NaBH4 produced Rh(BH4)(ttp*). The reaction of RuCl2(ttp*) with NaBH4 produced RuH(BH4)(ttp*). The complexes RhCl(ttp*), RuCl2(ttp*), Rh(BH4)(ttp*), and RuH(BH4)(ttp*) were found to be catalytically active for the hydrogenation of α-acetamidocinnamic acid.",
author = "Lee, {Hon Man} and Chuluo Yang and Guochen Jia",
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journal = "Journal of Organometallic Chemistry",
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T1 - Preparation and catalytic hydrogenation properties of some rhodium and ruthenium complexes with chiral tridentate phosphine ligands (S,S)-PhP(CH2CHMeCH2PPh2)2 and (S)-Ph2PCH2CH(PPh2)CH2CH 2PPh2)

AU - Lee, Hon Man

AU - Yang, Chuluo

AU - Jia, Guochen

PY - 2000/4/28

Y1 - 2000/4/28

N2 - Treatment of RhCl(ttp*) (ttp*=(S,S)-PhP(CH2CHMeCH2PPh2) 2) with NaBH4 produced Rh(BH4)(ttp*). The reaction of RuCl2(ttp*) with NaBH4 produced RuH(BH4)(ttp*). The complexes RhCl(ttp*), RuCl2(ttp*), Rh(BH4)(ttp*), and RuH(BH4)(ttp*) were found to be catalytically active for the hydrogenation of α-acetamidocinnamic acid.

AB - Treatment of RhCl(ttp*) (ttp*=(S,S)-PhP(CH2CHMeCH2PPh2) 2) with NaBH4 produced Rh(BH4)(ttp*). The reaction of RuCl2(ttp*) with NaBH4 produced RuH(BH4)(ttp*). The complexes RhCl(ttp*), RuCl2(ttp*), Rh(BH4)(ttp*), and RuH(BH4)(ttp*) were found to be catalytically active for the hydrogenation of α-acetamidocinnamic acid.

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U2 - 10.1016/S0022-328X(00)00104-2

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VL - 601

SP - 330

EP - 334

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

SN - 0022-328X

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