Abstract
Treatment of RhCl(ttp*) (ttp*=(S,S)-PhP(CH2CHMeCH2PPh2) 2) with NaBH4 produced Rh(BH4)(ttp*). The reaction of RuCl2(ttp*) with NaBH4 produced RuH(BH4)(ttp*). The complexes RhCl(ttp*), RuCl2(ttp*), Rh(BH4)(ttp*), and RuH(BH4)(ttp*) were found to be catalytically active for the hydrogenation of α-acetamidocinnamic acid.
| Original language | English |
|---|---|
| Pages (from-to) | 330-334 |
| Number of pages | 5 |
| Journal | Journal of Organometallic Chemistry |
| Volume | 601 |
| Issue number | 2 |
| DOIs | |
| Publication status | Published - 2000 Apr 28 |
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All Science Journal Classification (ASJC) codes
- Biochemistry
- Physical and Theoretical Chemistry
- Organic Chemistry
- Inorganic Chemistry
- Materials Chemistry
Cite this
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Preparation and catalytic hydrogenation properties of some rhodium and ruthenium complexes with chiral tridentate phosphine ligands (S,S)-PhP(CH2CHMeCH2PPh2)2 and (S)-Ph2PCH2CH(PPh2)CH2CH 2PPh2). / Lee, Hon Man; Yang, Chuluo; Jia, Guochen.
In: Journal of Organometallic Chemistry, Vol. 601, No. 2, 28.04.2000, p. 330-334.Research output: Contribution to journal › Article
TY - JOUR
T1 - Preparation and catalytic hydrogenation properties of some rhodium and ruthenium complexes with chiral tridentate phosphine ligands (S,S)-PhP(CH2CHMeCH2PPh2)2 and (S)-Ph2PCH2CH(PPh2)CH2CH 2PPh2)
AU - Lee, Hon Man
AU - Yang, Chuluo
AU - Jia, Guochen
PY - 2000/4/28
Y1 - 2000/4/28
N2 - Treatment of RhCl(ttp*) (ttp*=(S,S)-PhP(CH2CHMeCH2PPh2) 2) with NaBH4 produced Rh(BH4)(ttp*). The reaction of RuCl2(ttp*) with NaBH4 produced RuH(BH4)(ttp*). The complexes RhCl(ttp*), RuCl2(ttp*), Rh(BH4)(ttp*), and RuH(BH4)(ttp*) were found to be catalytically active for the hydrogenation of α-acetamidocinnamic acid.
AB - Treatment of RhCl(ttp*) (ttp*=(S,S)-PhP(CH2CHMeCH2PPh2) 2) with NaBH4 produced Rh(BH4)(ttp*). The reaction of RuCl2(ttp*) with NaBH4 produced RuH(BH4)(ttp*). The complexes RhCl(ttp*), RuCl2(ttp*), Rh(BH4)(ttp*), and RuH(BH4)(ttp*) were found to be catalytically active for the hydrogenation of α-acetamidocinnamic acid.
UR - http://www.scopus.com/inward/record.url?scp=0012340003&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0012340003&partnerID=8YFLogxK
U2 - 10.1016/S0022-328X(00)00104-2
DO - 10.1016/S0022-328X(00)00104-2
M3 - Article
AN - SCOPUS:0012340003
VL - 601
SP - 330
EP - 334
JO - Journal of Organometallic Chemistry
JF - Journal of Organometallic Chemistry
SN - 0022-328X
IS - 2
ER -