Preparation and catalytic hydrogenation properties of some rhodium and ruthenium complexes with chiral tridentate phosphine ligands (S,S)-PhP(CH2CHMeCH2PPh2)2 and (S)-Ph2PCH2CH(PPh2)CH2CH 2PPh2)

Hon Man Lee; Chuluo Yang; Guochen Jia

doi:10.1016/S0022-328X(00)00104-2

Preparation and catalytic hydrogenation properties of some rhodium and ruthenium complexes with chiral tridentate phosphine ligands (S,S)-PhP(CH₂CHMeCH₂PPh₂)₂ and (S)-Ph₂PCH₂CH(PPh₂)CH₂CH ₂PPh₂)

Hon Man Lee, Chuluo Yang, Guochen Jia

Department of Chemistry

Research output: Contribution to journal › Article

12 Citations (Scopus)

Abstract

Treatment of RhCl(ttp*) (ttp*=(S,S)-PhP(CH₂CHMeCH₂PPh₂) ₂) with NaBH₄ produced Rh(BH₄)(ttp*). The reaction of RuCl₂(ttp*) with NaBH₄ produced RuH(BH₄)(ttp*). The complexes RhCl(ttp*), RuCl₂(ttp*), Rh(BH₄)(ttp*), and RuH(BH₄)(ttp*) were found to be catalytically active for the hydrogenation of α-acetamidocinnamic acid.

Original language	English
Pages (from-to)	330-334
Number of pages	5
Journal	Journal of Organometallic Chemistry
Volume	601
Issue number	2
DOIs	https://doi.org/10.1016/S0022-328X(00)00104-2
Publication status	Published - 2000 Apr 28

Fingerprint

All Science Journal Classification (ASJC) codes

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

Cite this

Lee, H. M., Yang, C., & Jia, G. (2000). Preparation and catalytic hydrogenation properties of some rhodium and ruthenium complexes with chiral tridentate phosphine ligands (S,S)-PhP(CH₂CHMeCH₂PPh₂)₂ and (S)-Ph₂PCH₂CH(PPh₂)CH₂CH ₂PPh₂). Journal of Organometallic Chemistry, 601(2), 330-334. https://doi.org/10.1016/S0022-328X(00)00104-2

@article{ed41a6fb60d74173bca3f915094fd3d7,

title = "Preparation and catalytic hydrogenation properties of some rhodium and ruthenium complexes with chiral tridentate phosphine ligands (S,S)-PhP(CH2CHMeCH2PPh2)2 and (S)-Ph2PCH2CH(PPh2)CH2CH 2PPh2)",

abstract = "Treatment of RhCl(ttp*) (ttp*=(S,S)-PhP(CH2CHMeCH2PPh2) 2) with NaBH4 produced Rh(BH4)(ttp*). The reaction of RuCl2(ttp*) with NaBH4 produced RuH(BH4)(ttp*). The complexes RhCl(ttp*), RuCl2(ttp*), Rh(BH4)(ttp*), and RuH(BH4)(ttp*) were found to be catalytically active for the hydrogenation of α-acetamidocinnamic acid.",

author = "Lee, {Hon Man} and Chuluo Yang and Guochen Jia",

year = "2000",

month = apr

day = "28",

doi = "10.1016/S0022-328X(00)00104-2",

language = "English",

volume = "601",

pages = "330--334",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier",

number = "2",

}

Preparation and catalytic hydrogenation properties of some rhodium and ruthenium complexes with chiral tridentate phosphine ligands (S,S)-PhP(CH₂CHMeCH₂PPh₂)₂ and (S)-Ph₂PCH₂CH(PPh₂)CH₂CH ₂PPh₂). / Lee, Hon Man; Yang, Chuluo; Jia, Guochen.

In: Journal of Organometallic Chemistry, Vol. 601, No. 2, 28.04.2000, p. 330-334.

Research output: Contribution to journal › Article

TY - JOUR

T1 - Preparation and catalytic hydrogenation properties of some rhodium and ruthenium complexes with chiral tridentate phosphine ligands (S,S)-PhP(CH2CHMeCH2PPh2)2 and (S)-Ph2PCH2CH(PPh2)CH2CH 2PPh2)

AU - Lee, Hon Man

AU - Yang, Chuluo

AU - Jia, Guochen

PY - 2000/4/28

Y1 - 2000/4/28

N2 - Treatment of RhCl(ttp*) (ttp*=(S,S)-PhP(CH2CHMeCH2PPh2) 2) with NaBH4 produced Rh(BH4)(ttp*). The reaction of RuCl2(ttp*) with NaBH4 produced RuH(BH4)(ttp*). The complexes RhCl(ttp*), RuCl2(ttp*), Rh(BH4)(ttp*), and RuH(BH4)(ttp*) were found to be catalytically active for the hydrogenation of α-acetamidocinnamic acid.

AB - Treatment of RhCl(ttp*) (ttp*=(S,S)-PhP(CH2CHMeCH2PPh2) 2) with NaBH4 produced Rh(BH4)(ttp*). The reaction of RuCl2(ttp*) with NaBH4 produced RuH(BH4)(ttp*). The complexes RhCl(ttp*), RuCl2(ttp*), Rh(BH4)(ttp*), and RuH(BH4)(ttp*) were found to be catalytically active for the hydrogenation of α-acetamidocinnamic acid.

UR - http://www.scopus.com/inward/record.url?scp=0012340003&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0012340003&partnerID=8YFLogxK

U2 - 10.1016/S0022-328X(00)00104-2

DO - 10.1016/S0022-328X(00)00104-2

M3 - Article

AN - SCOPUS:0012340003

VL - 601

SP - 330

EP - 334

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

SN - 0022-328X

IS - 2

ER -

Access to Document

10.1016/S0022-328X(00)00104-2