Abstract
A tridentate hydrazone precursor, N′-[1-(pyridin-2-yl)ethylidene] acetohydrazide (L) (1:1 refluxed product of acetichydrazide and 2-acetylpyridine), produced two octahedral Cu II and Ni II derivatives, [CuL 2]·NO 3 (1) and [NiL 2]·ClO 4·H 2O (2). Both are subjected to X-ray diffraction system, and structural investigation shows that the central metal atom (Cu II or Ni II) adopts a distorted octahedral geometry with N 4O 2 donor sets by coordination of a pair of independent hydrazone precursors. Besides X-ray study, IR and UV-vis spectra, thermal analysis and room temperature magnetic moments are utilized for establishing significant characteristics of both complexes. It is apparent that the M-N pyridine bonds are slightly longer than the M-N imino bonds, Cu1-N1 and Cu1-N4 [2.300(2) and 2.038(2) Å] for 1 and Ni1-N1 and Ni1-N4 [2.075(2) and 2.084(1) Å] for 2, Cu1-N2 and Cu1-N5 [2.062(1) and 1.932(1) Å] for 1 and Ni1-N2 and Ni1-N5 [2.008(2) and 1.975(2) Å] for 2, respectively. As per our observation, the effective magnetic moment value (μ eff) is found to be 1.77 B.M. for 1 and 3.06 BM for 2, respectively.
| Original language | English |
|---|---|
| Pages (from-to) | 116-122 |
| Number of pages | 7 |
| Journal | Central European Journal of Chemistry |
| Volume | 11 |
| Issue number | 1 |
| DOIs | |
| Publication status | Published - 2013 Jan 1 |
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All Science Journal Classification (ASJC) codes
- Chemistry(all)
- Materials Chemistry
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Octahedral Cu II and Ni II complexes manifesting with N′-[1-(pyridin-2-yl)ethylidene] acetohydrazide : Structural outlooks and spectral characteristics. / Datta, Amitabha; Huang, Jui-Hsien; Clegg, Jack K.; Liu, Pei Hsin; Chuang, Sheng Jie.
In: Central European Journal of Chemistry, Vol. 11, No. 1, 01.01.2013, p. 116-122.Research output: Contribution to journal › Article
TY - JOUR
T1 - Octahedral Cu II and Ni II complexes manifesting with N′-[1-(pyridin-2-yl)ethylidene] acetohydrazide
T2 - Structural outlooks and spectral characteristics
AU - Datta, Amitabha
AU - Huang, Jui-Hsien
AU - Clegg, Jack K.
AU - Liu, Pei Hsin
AU - Chuang, Sheng Jie
PY - 2013/1/1
Y1 - 2013/1/1
N2 - A tridentate hydrazone precursor, N′-[1-(pyridin-2-yl)ethylidene] acetohydrazide (L) (1:1 refluxed product of acetichydrazide and 2-acetylpyridine), produced two octahedral Cu II and Ni II derivatives, [CuL 2]·NO 3 (1) and [NiL 2]·ClO 4·H 2O (2). Both are subjected to X-ray diffraction system, and structural investigation shows that the central metal atom (Cu II or Ni II) adopts a distorted octahedral geometry with N 4O 2 donor sets by coordination of a pair of independent hydrazone precursors. Besides X-ray study, IR and UV-vis spectra, thermal analysis and room temperature magnetic moments are utilized for establishing significant characteristics of both complexes. It is apparent that the M-N pyridine bonds are slightly longer than the M-N imino bonds, Cu1-N1 and Cu1-N4 [2.300(2) and 2.038(2) Å] for 1 and Ni1-N1 and Ni1-N4 [2.075(2) and 2.084(1) Å] for 2, Cu1-N2 and Cu1-N5 [2.062(1) and 1.932(1) Å] for 1 and Ni1-N2 and Ni1-N5 [2.008(2) and 1.975(2) Å] for 2, respectively. As per our observation, the effective magnetic moment value (μ eff) is found to be 1.77 B.M. for 1 and 3.06 BM for 2, respectively.
AB - A tridentate hydrazone precursor, N′-[1-(pyridin-2-yl)ethylidene] acetohydrazide (L) (1:1 refluxed product of acetichydrazide and 2-acetylpyridine), produced two octahedral Cu II and Ni II derivatives, [CuL 2]·NO 3 (1) and [NiL 2]·ClO 4·H 2O (2). Both are subjected to X-ray diffraction system, and structural investigation shows that the central metal atom (Cu II or Ni II) adopts a distorted octahedral geometry with N 4O 2 donor sets by coordination of a pair of independent hydrazone precursors. Besides X-ray study, IR and UV-vis spectra, thermal analysis and room temperature magnetic moments are utilized for establishing significant characteristics of both complexes. It is apparent that the M-N pyridine bonds are slightly longer than the M-N imino bonds, Cu1-N1 and Cu1-N4 [2.300(2) and 2.038(2) Å] for 1 and Ni1-N1 and Ni1-N4 [2.075(2) and 2.084(1) Å] for 2, Cu1-N2 and Cu1-N5 [2.062(1) and 1.932(1) Å] for 1 and Ni1-N2 and Ni1-N5 [2.008(2) and 1.975(2) Å] for 2, respectively. As per our observation, the effective magnetic moment value (μ eff) is found to be 1.77 B.M. for 1 and 3.06 BM for 2, respectively.
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U2 - 10.2478/s11532-012-0141-z
DO - 10.2478/s11532-012-0141-z
M3 - Article
AN - SCOPUS:84868596112
VL - 11
SP - 116
EP - 122
JO - Central European Journal of Chemistry
JF - Central European Journal of Chemistry
SN - 1895-1066
IS - 1
ER -