Abstract
Three new two-dimensional coordination polymers were constructed from 2,6-bis(imidazole-1-yl)pyridine (2.6-bip), terephthalic acid (1,4-bdcH2), and M(NO3)·nH2O (M = Co, Cd). [M(2,6-bip)(1,4-bdc)] (1: M = Co; 2:M=Cd) were prepared under hydrothermal condition,whereas [Cd(2,6-bip)(1,4-bdc)·xDMF] (3) was obtained under solvothermal condition in DMF solvent. Single-crystal X-ray analyses revealed the first example of a 2D 4-connected net of 66 topology in 1 and 2 and a rare 2D 4,5-connected net of 4,5 L20 topology in 3. All these complexes were thermally robust and emissive in solid-states. Thiswork confirmed the versatility of using hingelike 2,6-bip as a linker and the importance of solvent effect in the process of framework formation.
| Original language | English |
|---|---|
| Pages (from-to) | 16-19 |
| Number of pages | 4 |
| Journal | Inorganic Chemistry Communications |
| Volume | 52 |
| DOIs | |
| Publication status | Published - 2015 Jan 1 |
Fingerprint
All Science Journal Classification (ASJC) codes
- Inorganic Chemistry
- Physical and Theoretical Chemistry
- Materials Chemistry
Cite this
}
Novel two-dimensional Co(II) and Cd(II) coordination polymers with intriguing net topologies. / Lee, Jhen Yi; Lee, Jing Yi; Lee, Hon Man.
In: Inorganic Chemistry Communications, Vol. 52, 01.01.2015, p. 16-19.Research output: Contribution to journal › Article
TY - JOUR
T1 - Novel two-dimensional Co(II) and Cd(II) coordination polymers with intriguing net topologies
AU - Lee, Jhen Yi
AU - Lee, Jing Yi
AU - Lee, Hon Man
PY - 2015/1/1
Y1 - 2015/1/1
N2 - Three new two-dimensional coordination polymers were constructed from 2,6-bis(imidazole-1-yl)pyridine (2.6-bip), terephthalic acid (1,4-bdcH2), and M(NO3)·nH2O (M = Co, Cd). [M(2,6-bip)(1,4-bdc)] (1: M = Co; 2:M=Cd) were prepared under hydrothermal condition,whereas [Cd(2,6-bip)(1,4-bdc)·xDMF] (3) was obtained under solvothermal condition in DMF solvent. Single-crystal X-ray analyses revealed the first example of a 2D 4-connected net of 66 topology in 1 and 2 and a rare 2D 4,5-connected net of 4,5 L20 topology in 3. All these complexes were thermally robust and emissive in solid-states. Thiswork confirmed the versatility of using hingelike 2,6-bip as a linker and the importance of solvent effect in the process of framework formation.
AB - Three new two-dimensional coordination polymers were constructed from 2,6-bis(imidazole-1-yl)pyridine (2.6-bip), terephthalic acid (1,4-bdcH2), and M(NO3)·nH2O (M = Co, Cd). [M(2,6-bip)(1,4-bdc)] (1: M = Co; 2:M=Cd) were prepared under hydrothermal condition,whereas [Cd(2,6-bip)(1,4-bdc)·xDMF] (3) was obtained under solvothermal condition in DMF solvent. Single-crystal X-ray analyses revealed the first example of a 2D 4-connected net of 66 topology in 1 and 2 and a rare 2D 4,5-connected net of 4,5 L20 topology in 3. All these complexes were thermally robust and emissive in solid-states. Thiswork confirmed the versatility of using hingelike 2,6-bip as a linker and the importance of solvent effect in the process of framework formation.
UR - http://www.scopus.com/inward/record.url?scp=84917729373&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84917729373&partnerID=8YFLogxK
U2 - 10.1016/j.inoche.2014.12.003
DO - 10.1016/j.inoche.2014.12.003
M3 - Article
AN - SCOPUS:84917729373
VL - 52
SP - 16
EP - 19
JO - Inorganic Chemistry Communication
JF - Inorganic Chemistry Communication
SN - 1387-7003
ER -