TY - JOUR
T1 - Novel two-dimensional Co(II) and Cd(II) coordination polymers with intriguing net topologies
AU - Lee, Jhen Yi
AU - Lee, Jing Yi
AU - Lee, Hon Man
N1 - Publisher Copyright:
© 2014 Elsevier B.V. All rights reserved.
Copyright:
Copyright 2020 Elsevier B.V., All rights reserved.
PY - 2015/2
Y1 - 2015/2
N2 - Three new two-dimensional coordination polymers were constructed from 2,6-bis(imidazole-1-yl)pyridine (2.6-bip), terephthalic acid (1,4-bdcH2), and M(NO3)·nH2O (M = Co, Cd). [M(2,6-bip)(1,4-bdc)] (1: M = Co; 2:M=Cd) were prepared under hydrothermal condition,whereas [Cd(2,6-bip)(1,4-bdc)·xDMF] (3) was obtained under solvothermal condition in DMF solvent. Single-crystal X-ray analyses revealed the first example of a 2D 4-connected net of 66 topology in 1 and 2 and a rare 2D 4,5-connected net of 4,5 L20 topology in 3. All these complexes were thermally robust and emissive in solid-states. Thiswork confirmed the versatility of using hingelike 2,6-bip as a linker and the importance of solvent effect in the process of framework formation.
AB - Three new two-dimensional coordination polymers were constructed from 2,6-bis(imidazole-1-yl)pyridine (2.6-bip), terephthalic acid (1,4-bdcH2), and M(NO3)·nH2O (M = Co, Cd). [M(2,6-bip)(1,4-bdc)] (1: M = Co; 2:M=Cd) were prepared under hydrothermal condition,whereas [Cd(2,6-bip)(1,4-bdc)·xDMF] (3) was obtained under solvothermal condition in DMF solvent. Single-crystal X-ray analyses revealed the first example of a 2D 4-connected net of 66 topology in 1 and 2 and a rare 2D 4,5-connected net of 4,5 L20 topology in 3. All these complexes were thermally robust and emissive in solid-states. Thiswork confirmed the versatility of using hingelike 2,6-bip as a linker and the importance of solvent effect in the process of framework formation.
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U2 - 10.1016/j.inoche.2014.12.003
DO - 10.1016/j.inoche.2014.12.003
M3 - Article
AN - SCOPUS:84917729373
VL - 52
SP - 16
EP - 19
JO - Inorganic Chemistry Communication
JF - Inorganic Chemistry Communication
SN - 1387-7003
ER -