Novel two-dimensional Co(II) and Cd(II) coordination polymers with intriguing net topologies

Jhen Yi Lee, Jing Yi Lee, Hon Man Lee

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

Three new two-dimensional coordination polymers were constructed from 2,6-bis(imidazole-1-yl)pyridine (2.6-bip), terephthalic acid (1,4-bdcH2), and M(NO3)·nH2O (M = Co, Cd). [M(2,6-bip)(1,4-bdc)] (1: M = Co; 2:M=Cd) were prepared under hydrothermal condition,whereas [Cd(2,6-bip)(1,4-bdc)·xDMF] (3) was obtained under solvothermal condition in DMF solvent. Single-crystal X-ray analyses revealed the first example of a 2D 4-connected net of 66 topology in 1 and 2 and a rare 2D 4,5-connected net of 4,5 L20 topology in 3. All these complexes were thermally robust and emissive in solid-states. Thiswork confirmed the versatility of using hingelike 2,6-bip as a linker and the importance of solvent effect in the process of framework formation.

Original languageEnglish
Pages (from-to)16-19
Number of pages4
JournalInorganic Chemistry Communications
Volume52
DOIs
Publication statusPublished - 2015 Jan 1

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coordination polymers
Polymers
topology
Topology
versatility
imidazoles
Pyridine
pyridines
Single crystals
solid state
X rays
acids
Acids
single crystals
x rays
terephthalic acid
pyridine
imidazole

All Science Journal Classification (ASJC) codes

  • Inorganic Chemistry
  • Physical and Theoretical Chemistry
  • Materials Chemistry

Cite this

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title = "Novel two-dimensional Co(II) and Cd(II) coordination polymers with intriguing net topologies",
abstract = "Three new two-dimensional coordination polymers were constructed from 2,6-bis(imidazole-1-yl)pyridine (2.6-bip), terephthalic acid (1,4-bdcH2), and M(NO3)·nH2O (M = Co, Cd). [M(2,6-bip)(1,4-bdc)] (1: M = Co; 2:M=Cd) were prepared under hydrothermal condition,whereas [Cd(2,6-bip)(1,4-bdc)·xDMF] (3) was obtained under solvothermal condition in DMF solvent. Single-crystal X-ray analyses revealed the first example of a 2D 4-connected net of 66 topology in 1 and 2 and a rare 2D 4,5-connected net of 4,5 L20 topology in 3. All these complexes were thermally robust and emissive in solid-states. Thiswork confirmed the versatility of using hingelike 2,6-bip as a linker and the importance of solvent effect in the process of framework formation.",
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Novel two-dimensional Co(II) and Cd(II) coordination polymers with intriguing net topologies. / Lee, Jhen Yi; Lee, Jing Yi; Lee, Hon Man.

In: Inorganic Chemistry Communications, Vol. 52, 01.01.2015, p. 16-19.

Research output: Contribution to journalArticle

TY - JOUR

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AU - Lee, Jhen Yi

AU - Lee, Jing Yi

AU - Lee, Hon Man

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N2 - Three new two-dimensional coordination polymers were constructed from 2,6-bis(imidazole-1-yl)pyridine (2.6-bip), terephthalic acid (1,4-bdcH2), and M(NO3)·nH2O (M = Co, Cd). [M(2,6-bip)(1,4-bdc)] (1: M = Co; 2:M=Cd) were prepared under hydrothermal condition,whereas [Cd(2,6-bip)(1,4-bdc)·xDMF] (3) was obtained under solvothermal condition in DMF solvent. Single-crystal X-ray analyses revealed the first example of a 2D 4-connected net of 66 topology in 1 and 2 and a rare 2D 4,5-connected net of 4,5 L20 topology in 3. All these complexes were thermally robust and emissive in solid-states. Thiswork confirmed the versatility of using hingelike 2,6-bip as a linker and the importance of solvent effect in the process of framework formation.

AB - Three new two-dimensional coordination polymers were constructed from 2,6-bis(imidazole-1-yl)pyridine (2.6-bip), terephthalic acid (1,4-bdcH2), and M(NO3)·nH2O (M = Co, Cd). [M(2,6-bip)(1,4-bdc)] (1: M = Co; 2:M=Cd) were prepared under hydrothermal condition,whereas [Cd(2,6-bip)(1,4-bdc)·xDMF] (3) was obtained under solvothermal condition in DMF solvent. Single-crystal X-ray analyses revealed the first example of a 2D 4-connected net of 66 topology in 1 and 2 and a rare 2D 4,5-connected net of 4,5 L20 topology in 3. All these complexes were thermally robust and emissive in solid-states. Thiswork confirmed the versatility of using hingelike 2,6-bip as a linker and the importance of solvent effect in the process of framework formation.

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