Abstract
In the title complex, [Cu(C 14H 13N 3O) (C 14H 12N 3O)](CCl3COO), the central Cu(II) ion exhibits a distorted octa-hedral geometry with the two ligands coordinating in an meridional format. The N 4O 2 ligand environment is defined by two benzoyl O atoms, two pyridyl N atoms and imino N atoms. As evidenced by the bond lengths, the two benzohydrazone ligands exist in distinctively different forms, one of them as a regular neutral ligand and the other as an anionic enolate arising from deprotonation. The much longer Cu-O bond and longer Cu-N bond lengths in the neutral benzohydrazone ligand imply weak ligation in comparison with the anionic enolate form. The acute angles of the five-membered rings cause a significant deviation from a regular octahedral geometry.
| Original language | English |
|---|---|
| Journal | Acta Crystallographica Section E: Structure Reports Online |
| Volume | 67 |
| Issue number | 10 |
| DOIs | |
| Publication status | Published - 2011 Oct 1 |
Fingerprint
All Science Journal Classification (ASJC) codes
- Chemistry(all)
- Materials Science(all)
- Condensed Matter Physics
Cite this
}
{N′-[1-(2-pyridyl)ethylidene-kN]benzohydrazidato-k 2 N′,O}{N′-[1-(2-pyridyl)ethylidene-N]benzohydrazide-k 2 N′,O}copper(II) trichloroacetate. / Datta, Amitabha; Chuang, Nien Tsu; Wen, Yun Sheng; Huang, Jui-Hsien; Sheu, Shiann Cherng.
In: Acta Crystallographica Section E: Structure Reports Online, Vol. 67, No. 10, 01.10.2011.Research output: Contribution to journal › Article
TY - JOUR
T1 - {N′-[1-(2-pyridyl)ethylidene-kN]benzohydrazidato-k 2 N′,O}{N′-[1-(2-pyridyl)ethylidene-N]benzohydrazide-k 2 N′,O}copper(II) trichloroacetate
AU - Datta, Amitabha
AU - Chuang, Nien Tsu
AU - Wen, Yun Sheng
AU - Huang, Jui-Hsien
AU - Sheu, Shiann Cherng
PY - 2011/10/1
Y1 - 2011/10/1
N2 - In the title complex, [Cu(C 14H 13N 3O) (C 14H 12N 3O)](CCl3COO), the central Cu(II) ion exhibits a distorted octa-hedral geometry with the two ligands coordinating in an meridional format. The N 4O 2 ligand environment is defined by two benzoyl O atoms, two pyridyl N atoms and imino N atoms. As evidenced by the bond lengths, the two benzohydrazone ligands exist in distinctively different forms, one of them as a regular neutral ligand and the other as an anionic enolate arising from deprotonation. The much longer Cu-O bond and longer Cu-N bond lengths in the neutral benzohydrazone ligand imply weak ligation in comparison with the anionic enolate form. The acute angles of the five-membered rings cause a significant deviation from a regular octahedral geometry.
AB - In the title complex, [Cu(C 14H 13N 3O) (C 14H 12N 3O)](CCl3COO), the central Cu(II) ion exhibits a distorted octa-hedral geometry with the two ligands coordinating in an meridional format. The N 4O 2 ligand environment is defined by two benzoyl O atoms, two pyridyl N atoms and imino N atoms. As evidenced by the bond lengths, the two benzohydrazone ligands exist in distinctively different forms, one of them as a regular neutral ligand and the other as an anionic enolate arising from deprotonation. The much longer Cu-O bond and longer Cu-N bond lengths in the neutral benzohydrazone ligand imply weak ligation in comparison with the anionic enolate form. The acute angles of the five-membered rings cause a significant deviation from a regular octahedral geometry.
UR - http://www.scopus.com/inward/record.url?scp=80054983167&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=80054983167&partnerID=8YFLogxK
U2 - 10.1107/S1600536811036592
DO - 10.1107/S1600536811036592
M3 - Article
VL - 67
JO - Acta Crystallographica Section E: Structure Reports Online
JF - Acta Crystallographica Section E: Structure Reports Online
SN - 1600-5368
IS - 10
ER -