{N′-[1-(2-pyridyl)ethylidene-kN]benzohydrazidato-k 2 N′,O}{N′-[1-(2-pyridyl)ethylidene-N]benzohydrazide-k 2 N′,O}copper(II) trichloroacetate

Amitabha Datta, Nien Tsu Chuang, Yun Sheng Wen, Jui Hsien Huang, Shiann Cherng Sheu

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

In the title complex, [Cu(C 14H 13N 3O) (C 14H 12N 3O)](CCl3COO), the central Cu(II) ion exhibits a distorted octa-hedral geometry with the two ligands coordinating in an meridional format. The N 4O 2 ligand environment is defined by two benzoyl O atoms, two pyridyl N atoms and imino N atoms. As evidenced by the bond lengths, the two benzohydrazone ligands exist in distinctively different forms, one of them as a regular neutral ligand and the other as an anionic enolate arising from deprotonation. The much longer Cu-O bond and longer Cu-N bond lengths in the neutral benzohydrazone ligand imply weak ligation in comparison with the anionic enolate form. The acute angles of the five-membered rings cause a significant deviation from a regular octahedral geometry.

Original languageEnglish
Pages (from-to)m1388
JournalActa Crystallographica Section E: Structure Reports Online
Volume67
Issue number10
DOIs
Publication statusPublished - 2011 Oct

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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