Abstract
The hydroformylation of 1-hexene with syngas (40 bar of 1:1 CO/H2) in the presence of the catalyst precursor RhH(CO)(PPh3)3 has been studied by high-pressure NMR spectroscopy in a 10 mm sapphire tube equipped with a Ti-alloy valve. Except for RhH(CO)2(PPh3)2, no direct observation of labile intermediates involved in the catalytic cycle has been detected; however as many as four rhodium resting states have been seen, and some factors controlling their formation/interconversion/inhibition have been identified. The information gathered from this in situ investigation is particularly relevant to a better understanding of the inhibiting action of the CO pressure as well as the positive action of PPh3 addition.
| Original language | English |
|---|---|
| Pages (from-to) | 849-852 |
| Number of pages | 4 |
| Journal | Organometallics |
| Volume | 19 |
| Issue number | 5 |
| Publication status | Published - 2000 Mar 6 |
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All Science Journal Classification (ASJC) codes
- Physical and Theoretical Chemistry
- Organic Chemistry
- Inorganic Chemistry
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In Situ High-Pressure 31P{1H} NMR Studies of the Hydroformylation of 1-Hexene by RhH(CO)(PPh3)3. / Bianchini, Claudio; Lee, Hon Man; Meli, Andrea; Vizza, Francesco.
In: Organometallics, Vol. 19, No. 5, 06.03.2000, p. 849-852.Research output: Contribution to journal › Article
TY - JOUR
T1 - In Situ High-Pressure 31P{1H} NMR Studies of the Hydroformylation of 1-Hexene by RhH(CO)(PPh3)3
AU - Bianchini, Claudio
AU - Lee, Hon Man
AU - Meli, Andrea
AU - Vizza, Francesco
PY - 2000/3/6
Y1 - 2000/3/6
N2 - The hydroformylation of 1-hexene with syngas (40 bar of 1:1 CO/H2) in the presence of the catalyst precursor RhH(CO)(PPh3)3 has been studied by high-pressure NMR spectroscopy in a 10 mm sapphire tube equipped with a Ti-alloy valve. Except for RhH(CO)2(PPh3)2, no direct observation of labile intermediates involved in the catalytic cycle has been detected; however as many as four rhodium resting states have been seen, and some factors controlling their formation/interconversion/inhibition have been identified. The information gathered from this in situ investigation is particularly relevant to a better understanding of the inhibiting action of the CO pressure as well as the positive action of PPh3 addition.
AB - The hydroformylation of 1-hexene with syngas (40 bar of 1:1 CO/H2) in the presence of the catalyst precursor RhH(CO)(PPh3)3 has been studied by high-pressure NMR spectroscopy in a 10 mm sapphire tube equipped with a Ti-alloy valve. Except for RhH(CO)2(PPh3)2, no direct observation of labile intermediates involved in the catalytic cycle has been detected; however as many as four rhodium resting states have been seen, and some factors controlling their formation/interconversion/inhibition have been identified. The information gathered from this in situ investigation is particularly relevant to a better understanding of the inhibiting action of the CO pressure as well as the positive action of PPh3 addition.
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M3 - Article
VL - 19
SP - 849
EP - 852
JO - Organometallics
JF - Organometallics
SN - 0276-7333
IS - 5
ER -