Improvement on the low-temperature thermoelectric characteristics of Ca3-xYbxCo4O9+δ (0≤x≤0.10)

Ankam Bhaskar, Y. C. Huang, Chia Jyi Liu

Research output: Contribution to journalArticle

13 Citations (Scopus)

Abstract

The effect of ytterbium doping on the low-temperature (<300 K) thermoelectric properties of Ca3-xYbxCo4O 9+δ (x=0.00, 0.02, 0.05 and 0.10) have been investigated. The samples were prepared by conventional solid-state synthesis and their properties measured from 25 K to 300 K. The X-ray diffraction patterns revealed that all the samples are single phase. The thermopower of all the samples was positive, indicating that the predominant carriers are holes over the entire temperature range. The electrical resistivity and thermopower were increased and total thermal conductivity was decreased with an increase in ytterbium doping level. Among the doped samples, Ca2.95Yb0.05Co4O 9+δ had the highest dimensionless figure of merit of 0.037 at 300 K, representing an improvement of about 48% compared to the undoped Ca 3Co4O9+δ sample at the same temperature. These results indicate that the partial substitution of Yb3+ ion improves the thermoelectric properties of Ca3Co4O 9+δ.

Original languageEnglish
Pages (from-to)5937-5943
Number of pages7
JournalCeramics International
Volume40
Issue number4
DOIs
Publication statusPublished - 2014 May 1

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Ytterbium
Thermoelectric power
Doping (additives)
Temperature
Diffraction patterns
Thermal conductivity
Substitution reactions
Ions
X ray diffraction

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Process Chemistry and Technology
  • Surfaces, Coatings and Films
  • Materials Chemistry

Cite this

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abstract = "The effect of ytterbium doping on the low-temperature (<300 K) thermoelectric properties of Ca3-xYbxCo4O 9+δ (x=0.00, 0.02, 0.05 and 0.10) have been investigated. The samples were prepared by conventional solid-state synthesis and their properties measured from 25 K to 300 K. The X-ray diffraction patterns revealed that all the samples are single phase. The thermopower of all the samples was positive, indicating that the predominant carriers are holes over the entire temperature range. The electrical resistivity and thermopower were increased and total thermal conductivity was decreased with an increase in ytterbium doping level. Among the doped samples, Ca2.95Yb0.05Co4O 9+δ had the highest dimensionless figure of merit of 0.037 at 300 K, representing an improvement of about 48{\%} compared to the undoped Ca 3Co4O9+δ sample at the same temperature. These results indicate that the partial substitution of Yb3+ ion improves the thermoelectric properties of Ca3Co4O 9+δ.",
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Improvement on the low-temperature thermoelectric characteristics of Ca3-xYbxCo4O9+δ (0≤x≤0.10). / Bhaskar, Ankam; Huang, Y. C.; Liu, Chia Jyi.

In: Ceramics International, Vol. 40, No. 4, 01.05.2014, p. 5937-5943.

Research output: Contribution to journalArticle

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AB - The effect of ytterbium doping on the low-temperature (<300 K) thermoelectric properties of Ca3-xYbxCo4O 9+δ (x=0.00, 0.02, 0.05 and 0.10) have been investigated. The samples were prepared by conventional solid-state synthesis and their properties measured from 25 K to 300 K. The X-ray diffraction patterns revealed that all the samples are single phase. The thermopower of all the samples was positive, indicating that the predominant carriers are holes over the entire temperature range. The electrical resistivity and thermopower were increased and total thermal conductivity was decreased with an increase in ytterbium doping level. Among the doped samples, Ca2.95Yb0.05Co4O 9+δ had the highest dimensionless figure of merit of 0.037 at 300 K, representing an improvement of about 48% compared to the undoped Ca 3Co4O9+δ sample at the same temperature. These results indicate that the partial substitution of Yb3+ ion improves the thermoelectric properties of Ca3Co4O 9+δ.

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