Hypervalent iodine(III)-induced domino oxidative cyclization for the synthesis of cyclopenta[b]furans

Mei Huey Lin; Yu Chun Chen; Shih Hao Chiu; Yun Fan Chen; Tsung Hsun Chuang

doi:10.3390/molecules21121713

Hypervalent iodine(III)-induced domino oxidative cyclization for the synthesis of cyclopenta[b]furans

Mei Huey Lin, Yu Chun Chen, Shih Hao Chiu, Yun Fan Chen, Tsung Hsun Chuang

Department of Chemistry

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1 Citation (Scopus)

Abstract

A new strategy for cyclopenta[b]furan synthesis mediated by hypervalent iodine(III) has been described. The approach employs diacetoxyiodobenzene-induced initial dehydrogenation to a putative trienone intermediate and triggered sequential cycloisomerization to form the cyclo-penta[b]furan targets.

Original language	English
Article number	1713
Journal	Molecules
Volume	21
Issue number	12
DOIs	https://doi.org/10.3390/molecules21121713
Publication status	Published - 2016 Dec 1

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All Science Journal Classification (ASJC) codes

Analytical Chemistry
Chemistry (miscellaneous)
Molecular Medicine
Pharmaceutical Science
Drug Discovery
Physical and Theoretical Chemistry
Organic Chemistry

Cite this

Lin, M. H., Chen, Y. C., Chiu, S. H., Chen, Y. F., & Chuang, T. H. (2016). Hypervalent iodine(III)-induced domino oxidative cyclization for the synthesis of cyclopenta[b]furans. Molecules, 21(12), [1713]. https://doi.org/10.3390/molecules21121713

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10.3390/molecules21121713