Abstract
A hydroxo-bridged 1-D coordination polymer, [Cu(L)(H 2O)]n (1), has been synthesized in good yield by employing a tetradentate Schiff base ligand, (6,6′-(1E,1′E)-(2-hydroxypropane-1,3-diyl)bis(azan-1-yl-1- ylidene)bis(methan-1-yl-1-ylidene)bis(2-methoxyphenol)), generated by condensation of o-vanillin with 1,3-diaminopropane-2-ol. Compound 1 has been fully characterized by elemental analyses, fourier transform IR, UV/vis and EPR measurements. Single crystal X-ray structure reveals that the central Cu II atom adopts a distorted octahedral geometry, to form 1-D network manifesting by the bridging participation of hydroxo group from neighboring Schiff base unit. The magnetic behavior of 1 shows that the χ MT product at 300 K is 0.47 cm 3 kmol - 1.
| Original language | English |
|---|---|
| Pages (from-to) | 216-220 |
| Number of pages | 5 |
| Journal | Inorganic Chemistry Communications |
| Volume | 24 |
| DOIs | |
| Publication status | Published - 2012 Oct 1 |
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All Science Journal Classification (ASJC) codes
- Inorganic Chemistry
- Physical and Theoretical Chemistry
- Materials Chemistry
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Hydroxo-bridged 1-D coordination polymer of Cu(II) incorporating with salicyladimine precursor : Spectral and temperature dependent magneto structural correlation. / Datta, Amitabha; Clegg, Jack K.; Huang, Jui-Hsien; Pevec, Andrej; Garribba, Eugenio; Fondo, Matilde.
In: Inorganic Chemistry Communications, Vol. 24, 01.10.2012, p. 216-220.Research output: Contribution to journal › Article
TY - JOUR
T1 - Hydroxo-bridged 1-D coordination polymer of Cu(II) incorporating with salicyladimine precursor
T2 - Spectral and temperature dependent magneto structural correlation
AU - Datta, Amitabha
AU - Clegg, Jack K.
AU - Huang, Jui-Hsien
AU - Pevec, Andrej
AU - Garribba, Eugenio
AU - Fondo, Matilde
PY - 2012/10/1
Y1 - 2012/10/1
N2 - A hydroxo-bridged 1-D coordination polymer, [Cu(L)(H 2O)]n (1), has been synthesized in good yield by employing a tetradentate Schiff base ligand, (6,6′-(1E,1′E)-(2-hydroxypropane-1,3-diyl)bis(azan-1-yl-1- ylidene)bis(methan-1-yl-1-ylidene)bis(2-methoxyphenol)), generated by condensation of o-vanillin with 1,3-diaminopropane-2-ol. Compound 1 has been fully characterized by elemental analyses, fourier transform IR, UV/vis and EPR measurements. Single crystal X-ray structure reveals that the central Cu II atom adopts a distorted octahedral geometry, to form 1-D network manifesting by the bridging participation of hydroxo group from neighboring Schiff base unit. The magnetic behavior of 1 shows that the χ MT product at 300 K is 0.47 cm 3 kmol - 1.
AB - A hydroxo-bridged 1-D coordination polymer, [Cu(L)(H 2O)]n (1), has been synthesized in good yield by employing a tetradentate Schiff base ligand, (6,6′-(1E,1′E)-(2-hydroxypropane-1,3-diyl)bis(azan-1-yl-1- ylidene)bis(methan-1-yl-1-ylidene)bis(2-methoxyphenol)), generated by condensation of o-vanillin with 1,3-diaminopropane-2-ol. Compound 1 has been fully characterized by elemental analyses, fourier transform IR, UV/vis and EPR measurements. Single crystal X-ray structure reveals that the central Cu II atom adopts a distorted octahedral geometry, to form 1-D network manifesting by the bridging participation of hydroxo group from neighboring Schiff base unit. The magnetic behavior of 1 shows that the χ MT product at 300 K is 0.47 cm 3 kmol - 1.
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UR - http://www.scopus.com/inward/citedby.url?scp=84866613547&partnerID=8YFLogxK
U2 - 10.1016/j.inoche.2012.07.017
DO - 10.1016/j.inoche.2012.07.017
M3 - Article
AN - SCOPUS:84866613547
VL - 24
SP - 216
EP - 220
JO - Inorganic Chemistry Communication
JF - Inorganic Chemistry Communication
SN - 1387-7003
ER -