Hydroxo-bridged 1-D coordination polymer of Cu(II) incorporating with salicyladimine precursor: Spectral and temperature dependent magneto structural correlation

Amitabha Datta, Jack K. Clegg, Jui-Hsien Huang, Andrej Pevec, Eugenio Garribba, Matilde Fondo

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

A hydroxo-bridged 1-D coordination polymer, [Cu(L)(H 2O)]n (1), has been synthesized in good yield by employing a tetradentate Schiff base ligand, (6,6′-(1E,1′E)-(2-hydroxypropane-1,3-diyl)bis(azan-1-yl-1- ylidene)bis(methan-1-yl-1-ylidene)bis(2-methoxyphenol)), generated by condensation of o-vanillin with 1,3-diaminopropane-2-ol. Compound 1 has been fully characterized by elemental analyses, fourier transform IR, UV/vis and EPR measurements. Single crystal X-ray structure reveals that the central Cu II atom adopts a distorted octahedral geometry, to form 1-D network manifesting by the bridging participation of hydroxo group from neighboring Schiff base unit. The magnetic behavior of 1 shows that the χ MT product at 300 K is 0.47 cm 3 kmol - 1.

Original languageEnglish
Pages (from-to)216-220
Number of pages5
JournalInorganic Chemistry Communications
Volume24
DOIs
Publication statusPublished - 2012 Oct 1

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Schiff Bases
coordination polymers
imines
Paramagnetic resonance
Condensation
Fourier transforms
Polymers
Ligands
Single crystals
Guaiacol
X rays
Atoms
Geometry
condensation
Temperature
ligands
temperature
single crystals
products
geometry

All Science Journal Classification (ASJC) codes

  • Inorganic Chemistry
  • Physical and Theoretical Chemistry
  • Materials Chemistry

Cite this

@article{d1b2f337f6fa4a3ab733691031630ae7,
title = "Hydroxo-bridged 1-D coordination polymer of Cu(II) incorporating with salicyladimine precursor: Spectral and temperature dependent magneto structural correlation",
abstract = "A hydroxo-bridged 1-D coordination polymer, [Cu(L)(H 2O)]n (1), has been synthesized in good yield by employing a tetradentate Schiff base ligand, (6,6′-(1E,1′E)-(2-hydroxypropane-1,3-diyl)bis(azan-1-yl-1- ylidene)bis(methan-1-yl-1-ylidene)bis(2-methoxyphenol)), generated by condensation of o-vanillin with 1,3-diaminopropane-2-ol. Compound 1 has been fully characterized by elemental analyses, fourier transform IR, UV/vis and EPR measurements. Single crystal X-ray structure reveals that the central Cu II atom adopts a distorted octahedral geometry, to form 1-D network manifesting by the bridging participation of hydroxo group from neighboring Schiff base unit. The magnetic behavior of 1 shows that the χ MT product at 300 K is 0.47 cm 3 kmol - 1.",
author = "Amitabha Datta and Clegg, {Jack K.} and Jui-Hsien Huang and Andrej Pevec and Eugenio Garribba and Matilde Fondo",
year = "2012",
month = "10",
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doi = "10.1016/j.inoche.2012.07.017",
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Hydroxo-bridged 1-D coordination polymer of Cu(II) incorporating with salicyladimine precursor : Spectral and temperature dependent magneto structural correlation. / Datta, Amitabha; Clegg, Jack K.; Huang, Jui-Hsien; Pevec, Andrej; Garribba, Eugenio; Fondo, Matilde.

In: Inorganic Chemistry Communications, Vol. 24, 01.10.2012, p. 216-220.

Research output: Contribution to journalArticle

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T1 - Hydroxo-bridged 1-D coordination polymer of Cu(II) incorporating with salicyladimine precursor

T2 - Spectral and temperature dependent magneto structural correlation

AU - Datta, Amitabha

AU - Clegg, Jack K.

AU - Huang, Jui-Hsien

AU - Pevec, Andrej

AU - Garribba, Eugenio

AU - Fondo, Matilde

PY - 2012/10/1

Y1 - 2012/10/1

N2 - A hydroxo-bridged 1-D coordination polymer, [Cu(L)(H 2O)]n (1), has been synthesized in good yield by employing a tetradentate Schiff base ligand, (6,6′-(1E,1′E)-(2-hydroxypropane-1,3-diyl)bis(azan-1-yl-1- ylidene)bis(methan-1-yl-1-ylidene)bis(2-methoxyphenol)), generated by condensation of o-vanillin with 1,3-diaminopropane-2-ol. Compound 1 has been fully characterized by elemental analyses, fourier transform IR, UV/vis and EPR measurements. Single crystal X-ray structure reveals that the central Cu II atom adopts a distorted octahedral geometry, to form 1-D network manifesting by the bridging participation of hydroxo group from neighboring Schiff base unit. The magnetic behavior of 1 shows that the χ MT product at 300 K is 0.47 cm 3 kmol - 1.

AB - A hydroxo-bridged 1-D coordination polymer, [Cu(L)(H 2O)]n (1), has been synthesized in good yield by employing a tetradentate Schiff base ligand, (6,6′-(1E,1′E)-(2-hydroxypropane-1,3-diyl)bis(azan-1-yl-1- ylidene)bis(methan-1-yl-1-ylidene)bis(2-methoxyphenol)), generated by condensation of o-vanillin with 1,3-diaminopropane-2-ol. Compound 1 has been fully characterized by elemental analyses, fourier transform IR, UV/vis and EPR measurements. Single crystal X-ray structure reveals that the central Cu II atom adopts a distorted octahedral geometry, to form 1-D network manifesting by the bridging participation of hydroxo group from neighboring Schiff base unit. The magnetic behavior of 1 shows that the χ MT product at 300 K is 0.47 cm 3 kmol - 1.

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