Abstract
A series of ruthenium complexes with the orthometallated ligand [2,6-(Ph2PCH2)2C6H3]- (PCP) was synthesized. Reaction of RuCl2(PPh3)3 with 1,3-(Ph2PCH2)2C6H4 produced the coordinatively unsaturated complex RuCl(PPh3)(PCP), which was characterized by X-ray crystallography. Treatment of RuCl(PPh3)(PCP) with 4-phenylpyridine (pyph) yielded RuCl(pyph)(PPh3)(PCP). Treatment of RuCl(PPh3)(PCP) with PMe3 and CO generated RuCl(PMe3)2(PCP) and RuCl(CO)2(PCP) respectively. Reactions of RuCl(PPh3)(PCP) with NaH in THF and NaBH4 in methanol gave RuH(PPh3)(PCP) and RuH(CO)(PPh3)(PCP) respectively. The hydride complex RuH(PMe3)2(PCP) was prepared by the reaction of RuCl(PMe3)2(PCP) with NaBH4.
| Original language | English |
|---|---|
| Pages (from-to) | 173-180 |
| Number of pages | 8 |
| Journal | Journal of Organometallic Chemistry |
| Volume | 534 |
| Issue number | 1-2 |
| DOIs | |
| Publication status | Published - 1997 Apr 28 |
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All Science Journal Classification (ASJC) codes
- Biochemistry
- Physical and Theoretical Chemistry
- Organic Chemistry
- Inorganic Chemistry
- Materials Chemistry
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Five- and six-coordinate ruthenium complexes with the tridentate orthometallated aryl bisphosphine ligand [2,6-(Ph2PCH2)2C6H3]-. / Jia, Guochen; Lee, Hon Man; Williams, Ian D.
In: Journal of Organometallic Chemistry, Vol. 534, No. 1-2, 28.04.1997, p. 173-180.Research output: Contribution to journal › Article
TY - JOUR
T1 - Five- and six-coordinate ruthenium complexes with the tridentate orthometallated aryl bisphosphine ligand [2,6-(Ph2PCH2)2C6H3]-
AU - Jia, Guochen
AU - Lee, Hon Man
AU - Williams, Ian D.
PY - 1997/4/28
Y1 - 1997/4/28
N2 - A series of ruthenium complexes with the orthometallated ligand [2,6-(Ph2PCH2)2C6H3]- (PCP) was synthesized. Reaction of RuCl2(PPh3)3 with 1,3-(Ph2PCH2)2C6H4 produced the coordinatively unsaturated complex RuCl(PPh3)(PCP), which was characterized by X-ray crystallography. Treatment of RuCl(PPh3)(PCP) with 4-phenylpyridine (pyph) yielded RuCl(pyph)(PPh3)(PCP). Treatment of RuCl(PPh3)(PCP) with PMe3 and CO generated RuCl(PMe3)2(PCP) and RuCl(CO)2(PCP) respectively. Reactions of RuCl(PPh3)(PCP) with NaH in THF and NaBH4 in methanol gave RuH(PPh3)(PCP) and RuH(CO)(PPh3)(PCP) respectively. The hydride complex RuH(PMe3)2(PCP) was prepared by the reaction of RuCl(PMe3)2(PCP) with NaBH4.
AB - A series of ruthenium complexes with the orthometallated ligand [2,6-(Ph2PCH2)2C6H3]- (PCP) was synthesized. Reaction of RuCl2(PPh3)3 with 1,3-(Ph2PCH2)2C6H4 produced the coordinatively unsaturated complex RuCl(PPh3)(PCP), which was characterized by X-ray crystallography. Treatment of RuCl(PPh3)(PCP) with 4-phenylpyridine (pyph) yielded RuCl(pyph)(PPh3)(PCP). Treatment of RuCl(PPh3)(PCP) with PMe3 and CO generated RuCl(PMe3)2(PCP) and RuCl(CO)2(PCP) respectively. Reactions of RuCl(PPh3)(PCP) with NaH in THF and NaBH4 in methanol gave RuH(PPh3)(PCP) and RuH(CO)(PPh3)(PCP) respectively. The hydride complex RuH(PMe3)2(PCP) was prepared by the reaction of RuCl(PMe3)2(PCP) with NaBH4.
UR - http://www.scopus.com/inward/record.url?scp=0031589101&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0031589101&partnerID=8YFLogxK
U2 - 10.1016/S0022-328X(96)06926-4
DO - 10.1016/S0022-328X(96)06926-4
M3 - Article
AN - SCOPUS:0031589101
VL - 534
SP - 173
EP - 180
JO - Journal of Organometallic Chemistry
JF - Journal of Organometallic Chemistry
SN - 0022-328X
IS - 1-2
ER -