Electric field-induced structural changes in pentacene-based organic thin-film transistors studied by in situ micro-Raman spectroscopy

H. L. Cheng, W. Y. Chou, C. W. Kuo, F. C. Tang, Y. W. Wang

Research output: Contribution to journalArticle

40 Citations (Scopus)

Abstract

We have investigated the electric field-induced microscopic structural changes in polycrystalline pentacene-based organic transistors by using in situ micro-Raman spectroscopy. Extra vibrational modes resulting from molecular coupling effect in pentacene film were studied. The herringbone packing of pentacene molecules in solid film is affected by external field and the process is proven to be partially irreversible. In the meantime, in-phase coupling of the C-H bending mode was found to be highly related to the carrier transport of pentacene film. Obtained results suggest that optimal intermolecular π -orbital overlap of pentacene molecules is still a critical factor impacting the carrier transportation for pentacene film featuring polycrystalline morphology.

Original languageEnglish
Article number161918
JournalApplied Physics Letters
Volume88
Issue number16
DOIs
Publication statusPublished - 2006 Apr 17

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transistors
Raman spectroscopy
electric fields
thin films
molecules
vibration mode
orbitals

All Science Journal Classification (ASJC) codes

  • Physics and Astronomy (miscellaneous)

Cite this

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abstract = "We have investigated the electric field-induced microscopic structural changes in polycrystalline pentacene-based organic transistors by using in situ micro-Raman spectroscopy. Extra vibrational modes resulting from molecular coupling effect in pentacene film were studied. The herringbone packing of pentacene molecules in solid film is affected by external field and the process is proven to be partially irreversible. In the meantime, in-phase coupling of the C-H bending mode was found to be highly related to the carrier transport of pentacene film. Obtained results suggest that optimal intermolecular π -orbital overlap of pentacene molecules is still a critical factor impacting the carrier transportation for pentacene film featuring polycrystalline morphology.",
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Electric field-induced structural changes in pentacene-based organic thin-film transistors studied by in situ micro-Raman spectroscopy. / Cheng, H. L.; Chou, W. Y.; Kuo, C. W.; Tang, F. C.; Wang, Y. W.

In: Applied Physics Letters, Vol. 88, No. 16, 161918, 17.04.2006.

Research output: Contribution to journalArticle

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AU - Cheng, H. L.

AU - Chou, W. Y.

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