Abstract
diagram presented A combination of palladium acetate and the imidazolium salt IPr-HCI (1, IPr = 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene) has proven to be highly efficient in the cross coupling reactions of aryl bromides and electron-deficient aryl chlorides with phenyltrimethoxysilane or vinyltrimethoxysilane. The catalytic performance of this system was found to be comparable to that of systems using PCy3 and P(o-tol)3.
| Original language | English |
|---|---|
| Pages (from-to) | 2053-2055 |
| Number of pages | 3 |
| Journal | Organic Letters |
| Volume | 2 |
| Issue number | 14 |
| DOIs | |
| Publication status | Published - 2000 Jul 13 |
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All Science Journal Classification (ASJC) codes
- Biochemistry
- Physical and Theoretical Chemistry
- Organic Chemistry
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Efficient cross-coupling reactions of aryl chlorides and bromides with phenyl- or vinyltrimethoxysilane mediated by a palladium/imidazolium chloride system. / Lee, Hon Man; Nolan, Steven P.
In: Organic Letters, Vol. 2, No. 14, 13.07.2000, p. 2053-2055.Research output: Contribution to journal › Article
TY - JOUR
T1 - Efficient cross-coupling reactions of aryl chlorides and bromides with phenyl- or vinyltrimethoxysilane mediated by a palladium/imidazolium chloride system
AU - Lee, Hon Man
AU - Nolan, Steven P.
PY - 2000/7/13
Y1 - 2000/7/13
N2 - diagram presented A combination of palladium acetate and the imidazolium salt IPr-HCI (1, IPr = 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene) has proven to be highly efficient in the cross coupling reactions of aryl bromides and electron-deficient aryl chlorides with phenyltrimethoxysilane or vinyltrimethoxysilane. The catalytic performance of this system was found to be comparable to that of systems using PCy3 and P(o-tol)3.
AB - diagram presented A combination of palladium acetate and the imidazolium salt IPr-HCI (1, IPr = 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene) has proven to be highly efficient in the cross coupling reactions of aryl bromides and electron-deficient aryl chlorides with phenyltrimethoxysilane or vinyltrimethoxysilane. The catalytic performance of this system was found to be comparable to that of systems using PCy3 and P(o-tol)3.
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U2 - 10.1021/ol005956t
DO - 10.1021/ol005956t
M3 - Article
AN - SCOPUS:0042760394
VL - 2
SP - 2053
EP - 2055
JO - Organic Letters
JF - Organic Letters
SN - 1523-7060
IS - 14
ER -