Direct C-H arylations of unactivated arenes catalyzed by amido-functionalized imidazolium salts

Debalina Ghosh; Jhen Yi Lee; Chian Yu Liu; Yen Hsin Chiang; Hon Man Lee

doi:10.1002/adsc.201300877

Direct C-H arylations of unactivated arenes catalyzed by amido-functionalized imidazolium salts

Debalina Ghosh, Jhen Yi Lee, Chian Yu Liu, Yen Hsin Chiang, Hon Man Lee

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

29 Citations (Scopus)

Abstract

The synthesis of biaryls from unactivated arenes and a broad range of aryl bromides and chlorides via the direct C-H functionalization can be efficiently performed with the aid of amido-functionalized imidazolium salts as organocatalysts. This method avoids the use of toxic transition metal catalysts and organometallic reagents.

Original language	English
Pages (from-to)	406-410
Number of pages	5
Journal	Advanced Synthesis and Catalysis
Volume	356
Issue number	2-3
DOIs	https://doi.org/10.1002/adsc.201300877
Publication status	Published - 2014 Feb 10

All Science Journal Classification (ASJC) codes

Catalysis
Organic Chemistry

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abstract = "The synthesis of biaryls from unactivated arenes and a broad range of aryl bromides and chlorides via the direct C-H functionalization can be efficiently performed with the aid of amido-functionalized imidazolium salts as organocatalysts. This method avoids the use of toxic transition metal catalysts and organometallic reagents.",

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AU - Chiang, Yen Hsin

AU - Lee, Hon Man

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AB - The synthesis of biaryls from unactivated arenes and a broad range of aryl bromides and chlorides via the direct C-H functionalization can be efficiently performed with the aid of amido-functionalized imidazolium salts as organocatalysts. This method avoids the use of toxic transition metal catalysts and organometallic reagents.

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