Dichloro{1-[2-(diphenylphosphino-κP)ethyl]-1,3-dihydro-3-(2,4, 6-trimethylphenyl)-2H-imidazol-2-ylidene-κC}palladium(II) diethyl ether solvate

Hon Man Lee, Pei Ling Chiu

Research output: Contribution to journalArticle

13 Citations (Scopus)

Abstract

The structure of the title compound, [PdCl2(C26H 27N2P)]·-C4H10O, was determined at 150 K. The palladium center is in a square-planar coordination geometry. A non-classical hydrogen bond (C-H···O) exists between the palladium complex and solvent molecule. The two chloride ligands are also involved in weak non-classical hydrogen bonds linking two neighboring molecules.

Original languageEnglish
JournalActa Crystallographica Section E: Structure Reports Online
Volume60
Issue number10
DOIs
Publication statusPublished - 2004 Oct 1

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diethyl ether
Palladium
imidazoles
Ether
palladium
Hydrogen
Ethers
Hydrogen bonds
hydrogen bonds
Molecules
Chlorides
molecules
chlorides
Ligands
ligands
Geometry
geometry
palladium chloride

All Science Journal Classification (ASJC) codes

  • Structural Biology
  • Condensed Matter Physics

Cite this

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abstract = "The structure of the title compound, [PdCl2(C26H 27N2P)]·-C4H10O, was determined at 150 K. The palladium center is in a square-planar coordination geometry. A non-classical hydrogen bond (C-H···O) exists between the palladium complex and solvent molecule. The two chloride ligands are also involved in weak non-classical hydrogen bonds linking two neighboring molecules.",
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T1 - Dichloro{1-[2-(diphenylphosphino-κP)ethyl]-1,3-dihydro-3-(2,4, 6-trimethylphenyl)-2H-imidazol-2-ylidene-κC}palladium(II) diethyl ether solvate

AU - Lee, Hon Man

AU - Chiu, Pei Ling

PY - 2004/10/1

Y1 - 2004/10/1

N2 - The structure of the title compound, [PdCl2(C26H 27N2P)]·-C4H10O, was determined at 150 K. The palladium center is in a square-planar coordination geometry. A non-classical hydrogen bond (C-H···O) exists between the palladium complex and solvent molecule. The two chloride ligands are also involved in weak non-classical hydrogen bonds linking two neighboring molecules.

AB - The structure of the title compound, [PdCl2(C26H 27N2P)]·-C4H10O, was determined at 150 K. The palladium center is in a square-planar coordination geometry. A non-classical hydrogen bond (C-H···O) exists between the palladium complex and solvent molecule. The two chloride ligands are also involved in weak non-classical hydrogen bonds linking two neighboring molecules.

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U2 - 10.1107/S1600536804023086

DO - 10.1107/S1600536804023086

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JO - Acta Crystallographica Section E: Structure Reports Online

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