Dichloro{1-[2-(diphenylphosphino-κP)ethyl]-1,3-dihydro-3-(2,4, 6-trimethylphenyl)-2H-imidazol-2-ylidene-κC}palladium(II) diethyl ether solvate

Hon Man Lee; Pei Ling Chiu

doi:10.1107/S1600536804023086

Dichloro{1-[2-(diphenylphosphino-κP)ethyl]-1,3-dihydro-3-(2,4, 6-trimethylphenyl)-2H-imidazol-2-ylidene-κC}palladium(II) diethyl ether solvate

Hon Man Lee, Pei Ling Chiu

Department of Chemistry

Research output: Contribution to journal › Article

13 Citations (Scopus)

Abstract

The structure of the title compound, [PdCl₂(C₂₆H ₂₇N₂P)]·-C₄H₁₀O, was determined at 150 K. The palladium center is in a square-planar coordination geometry. A non-classical hydrogen bond (C-H···O) exists between the palladium complex and solvent molecule. The two chloride ligands are also involved in weak non-classical hydrogen bonds linking two neighboring molecules.

Original language	English
Pages (from-to)	m1473-m1474
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	60
Issue number	10
DOIs	https://doi.org/10.1107/S1600536804023086
Publication status	Published - 2004 Oct 1

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All Science Journal Classification (ASJC) codes

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

Cite this

Lee, H. M., & Chiu, P. L. (2004). Dichloro{1-[2-(diphenylphosphino-κP)ethyl]-1,3-dihydro-3-(2,4, 6-trimethylphenyl)-2H-imidazol-2-ylidene-κC}palladium(II) diethyl ether solvate. Acta Crystallographica Section E: Structure Reports Online, 60(10), m1473-m1474. https://doi.org/10.1107/S1600536804023086

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abstract = "The structure of the title compound, [PdCl2(C26H 27N2P)]·-C4H10O, was determined at 150 K. The palladium center is in a square-planar coordination geometry. A non-classical hydrogen bond (C-H···O) exists between the palladium complex and solvent molecule. The two chloride ligands are also involved in weak non-classical hydrogen bonds linking two neighboring molecules.",

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AU - Chiu, Pei Ling

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N2 - The structure of the title compound, [PdCl2(C26H 27N2P)]·-C4H10O, was determined at 150 K. The palladium center is in a square-planar coordination geometry. A non-classical hydrogen bond (C-H···O) exists between the palladium complex and solvent molecule. The two chloride ligands are also involved in weak non-classical hydrogen bonds linking two neighboring molecules.

AB - The structure of the title compound, [PdCl2(C26H 27N2P)]·-C4H10O, was determined at 150 K. The palladium center is in a square-planar coordination geometry. A non-classical hydrogen bond (C-H···O) exists between the palladium complex and solvent molecule. The two chloride ligands are also involved in weak non-classical hydrogen bonds linking two neighboring molecules.

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10.1107/S1600536804023086