Abstract
In the title compound, [CuCl2(C8H9N 3O)], the CuII atom has a distorted square-pyramidal CuCl2N2O coordination geometry. The tridentate acetohydrazide ligand occupies three basal positions, the fourth basal position being defined by a chloride anion at a distance of 2.2116 (6) Å. The second chloride anion is in the apical position and forms a longer Cu - Cl distance of 2.4655 (7) Å. intermolecular N-H⋯Cl hydrogen bonds are present in the crystal, leading to the formation of chains along [101̄]..
| Original language | English |
|---|---|
| Pages (from-to) | m1852 |
| Journal | Acta Crystallographica Section E: Structure Reports Online |
| Volume | 67 |
| Issue number | 12 |
| DOIs | |
| Publication status | Published - 2011 Dec 1 |
All Science Journal Classification (ASJC) codes
- Chemistry(all)
- Materials Science(all)
- Condensed Matter Physics
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Datta, A., Sheu, S. C., Liu, P. H., & Huang, J. H. (2011). Dichlorido{N′-[(pyridin-2-yl)methylidene-κN] acetohydrazide-κ2 N′,O}copper(II). Acta Crystallographica Section E: Structure Reports Online, 67(12), m1852. https://doi.org/10.1107/S1600536811049671