Abstract
In the title compound, [CuCl2(C8H9N 3O)], the CuII atom has a distorted square-pyramidal CuCl2N2O coordination geometry. The tridentate acetohydrazide ligand occupies three basal positions, the fourth basal position being defined by a chloride anion at a distance of 2.2116 (6) Å. The second chloride anion is in the apical position and forms a longer Cu - Cl distance of 2.4655 (7) Å. intermolecular N-H⋯Cl hydrogen bonds are present in the crystal, leading to the formation of chains along [101̄]..
| Original language | English |
|---|---|
| Journal | Acta Crystallographica Section E: Structure Reports Online |
| Volume | 67 |
| Issue number | 12 |
| DOIs | |
| Publication status | Published - 2011 Dec 1 |
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All Science Journal Classification (ASJC) codes
- Condensed Matter Physics
- Materials Science(all)
- Chemistry(all)
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Dichlorido{N′-[(pyridin-2-yl)methylidene-κN] acetohydrazide-κ2 N′,O}copper(II). / Datta, Amitabha; Sheu, Shiann Cherng; Liu, Pei Hsin; Huang, Jui-Hsien.
In: Acta Crystallographica Section E: Structure Reports Online, Vol. 67, No. 12, 01.12.2011.Research output: Contribution to journal › Article
TY - JOUR
T1 - Dichlorido{N′-[(pyridin-2-yl)methylidene-κN] acetohydrazide-κ2 N′,O}copper(II)
AU - Datta, Amitabha
AU - Sheu, Shiann Cherng
AU - Liu, Pei Hsin
AU - Huang, Jui-Hsien
PY - 2011/12/1
Y1 - 2011/12/1
N2 - In the title compound, [CuCl2(C8H9N 3O)], the CuII atom has a distorted square-pyramidal CuCl2N2O coordination geometry. The tridentate acetohydrazide ligand occupies three basal positions, the fourth basal position being defined by a chloride anion at a distance of 2.2116 (6) Å. The second chloride anion is in the apical position and forms a longer Cu - Cl distance of 2.4655 (7) Å. intermolecular N-H⋯Cl hydrogen bonds are present in the crystal, leading to the formation of chains along [101̄]..
AB - In the title compound, [CuCl2(C8H9N 3O)], the CuII atom has a distorted square-pyramidal CuCl2N2O coordination geometry. The tridentate acetohydrazide ligand occupies three basal positions, the fourth basal position being defined by a chloride anion at a distance of 2.2116 (6) Å. The second chloride anion is in the apical position and forms a longer Cu - Cl distance of 2.4655 (7) Å. intermolecular N-H⋯Cl hydrogen bonds are present in the crystal, leading to the formation of chains along [101̄]..
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U2 - 10.1107/S1600536811049671
DO - 10.1107/S1600536811049671
M3 - Article
VL - 67
JO - Acta Crystallographica Section E: Structure Reports Online
JF - Acta Crystallographica Section E: Structure Reports Online
SN - 1600-5368
IS - 12
ER -