Dichlorido{N′-[(pyridin-2-yl)methylidene-κN] acetohydrazide-κ2 N′,O}copper(II)

Amitabha Datta, Shiann Cherng Sheu, Pei Hsin Liu, Jui-Hsien Huang

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

In the title compound, [CuCl2(C8H9N 3O)], the CuII atom has a distorted square-pyramidal CuCl2N2O coordination geometry. The tridentate acetohydrazide ligand occupies three basal positions, the fourth basal position being defined by a chloride anion at a distance of 2.2116 (6) Å. The second chloride anion is in the apical position and forms a longer Cu - Cl distance of 2.4655 (7) Å. intermolecular N-H⋯Cl hydrogen bonds are present in the crystal, leading to the formation of chains along [101̄]..

Original languageEnglish
JournalActa Crystallographica Section E: Structure Reports Online
Volume67
Issue number12
DOIs
Publication statusPublished - 2011 Dec 1

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Anions
Chlorides
Copper
Negative ions
copper
chlorides
anions
Hydrogen bonds
Ligands
Atoms
Crystals
Geometry
hydrogen bonds
ligands
geometry
crystals
atoms
cupric chloride

All Science Journal Classification (ASJC) codes

  • Condensed Matter Physics
  • Materials Science(all)
  • Chemistry(all)

Cite this

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title = "Dichlorido{N′-[(pyridin-2-yl)methylidene-κN] acetohydrazide-κ2 N′,O}copper(II)",
abstract = "In the title compound, [CuCl2(C8H9N 3O)], the CuII atom has a distorted square-pyramidal CuCl2N2O coordination geometry. The tridentate acetohydrazide ligand occupies three basal positions, the fourth basal position being defined by a chloride anion at a distance of 2.2116 (6) {\AA}. The second chloride anion is in the apical position and forms a longer Cu - Cl distance of 2.4655 (7) {\AA}. intermolecular N-H⋯Cl hydrogen bonds are present in the crystal, leading to the formation of chains along [101̄]..",
author = "Amitabha Datta and Sheu, {Shiann Cherng} and Liu, {Pei Hsin} and Jui-Hsien Huang",
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Dichlorido{N′-[(pyridin-2-yl)methylidene-κN] acetohydrazide-κ2 N′,O}copper(II). / Datta, Amitabha; Sheu, Shiann Cherng; Liu, Pei Hsin; Huang, Jui-Hsien.

In: Acta Crystallographica Section E: Structure Reports Online, Vol. 67, No. 12, 01.12.2011.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Dichlorido{N′-[(pyridin-2-yl)methylidene-κN] acetohydrazide-κ2 N′,O}copper(II)

AU - Datta, Amitabha

AU - Sheu, Shiann Cherng

AU - Liu, Pei Hsin

AU - Huang, Jui-Hsien

PY - 2011/12/1

Y1 - 2011/12/1

N2 - In the title compound, [CuCl2(C8H9N 3O)], the CuII atom has a distorted square-pyramidal CuCl2N2O coordination geometry. The tridentate acetohydrazide ligand occupies three basal positions, the fourth basal position being defined by a chloride anion at a distance of 2.2116 (6) Å. The second chloride anion is in the apical position and forms a longer Cu - Cl distance of 2.4655 (7) Å. intermolecular N-H⋯Cl hydrogen bonds are present in the crystal, leading to the formation of chains along [101̄]..

AB - In the title compound, [CuCl2(C8H9N 3O)], the CuII atom has a distorted square-pyramidal CuCl2N2O coordination geometry. The tridentate acetohydrazide ligand occupies three basal positions, the fourth basal position being defined by a chloride anion at a distance of 2.2116 (6) Å. The second chloride anion is in the apical position and forms a longer Cu - Cl distance of 2.4655 (7) Å. intermolecular N-H⋯Cl hydrogen bonds are present in the crystal, leading to the formation of chains along [101̄]..

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JO - Acta Crystallographica Section E: Structure Reports Online

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