TY - JOUR
T1 - Dichlorido{N′-[(pyridin-2-yl)methylidene-κN] acetohydrazide-κ2 N′,O}copper(II)
AU - Datta, Amitabha
AU - Sheu, Shiann Cherng
AU - Liu, Pei Hsin
AU - Huang, Jui Hsien
PY - 2011/12
Y1 - 2011/12
N2 - In the title compound, [CuCl2(C8H9N 3O)], the CuII atom has a distorted square-pyramidal CuCl2N2O coordination geometry. The tridentate acetohydrazide ligand occupies three basal positions, the fourth basal position being defined by a chloride anion at a distance of 2.2116 (6) Å. The second chloride anion is in the apical position and forms a longer Cu - Cl distance of 2.4655 (7) Å. intermolecular N-H⋯Cl hydrogen bonds are present in the crystal, leading to the formation of chains along [101̄]..
AB - In the title compound, [CuCl2(C8H9N 3O)], the CuII atom has a distorted square-pyramidal CuCl2N2O coordination geometry. The tridentate acetohydrazide ligand occupies three basal positions, the fourth basal position being defined by a chloride anion at a distance of 2.2116 (6) Å. The second chloride anion is in the apical position and forms a longer Cu - Cl distance of 2.4655 (7) Å. intermolecular N-H⋯Cl hydrogen bonds are present in the crystal, leading to the formation of chains along [101̄]..
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U2 - 10.1107/S1600536811049671
DO - 10.1107/S1600536811049671
M3 - Article
C2 - 22199623
AN - SCOPUS:83155189095
VL - 67
SP - m1852
JO - Acta Crystallographica Section E: Structure Reports Online
JF - Acta Crystallographica Section E: Structure Reports Online
SN - 1600-5368
IS - 12
ER -