Dichlorido{N′-[1-(2-pyridin-2-yl)ethylidene] acetohydrazide- κ2N′,O}copper(II)

Amitabha Datta, Kuheli Das, Yan Ming Jhou, Jui Hsien Huang, Hon Man Lee

Research output: Contribution to journalArticle

11 Citations (Scopus)

Abstract

In the title compound, [CuCl2(C9H11N 3O)], the CuII atom is in a distorted square-pyramidal CuCl2N2O coordination geometry. The tridentate acetohydrazide ligand chelates in a meridional fashion. The chloride ligand in the axial position forms a long Cu-Cl distance of 2.4892 (9) Å. In contrast, the Cu-Cl distance from the equatorial chloride ligand is much shorter [2.2110 (7) Å]. Intermolecular N - H⋯Cl and C - H⋯Cl hydrogen bonds link the complexes into a threedimensional network.

Original languageEnglish
Pages (from-to)m123
JournalActa Crystallographica Section E: Structure Reports Online
Volume67
Issue number1
DOIs
Publication statusPublished - 2011 Jan

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

Fingerprint Dive into the research topics of 'Dichlorido{N′-[1-(2-pyridin-2-yl)ethylidene] acetohydrazide- κ<sup>2</sup>N′,O}copper(II)'. Together they form a unique fingerprint.

  • Cite this