Dichlorido{N′-[1-(2-pyridin-2-yl)ethylidene] acetohydrazide- κ2N′,O}copper(II)

Amitabha Datta, Kuheli Das, Yan Ming Jhou, Jui Hsien Huang, Hon Man Lee

Research output: Contribution to journalArticle

11 Citations (Scopus)

Abstract

In the title compound, [CuCl2(C9H11N 3O)], the CuII atom is in a distorted square-pyramidal CuCl2N2O coordination geometry. The tridentate acetohydrazide ligand chelates in a meridional fashion. The chloride ligand in the axial position forms a long Cu-Cl distance of 2.4892 (9) Å. In contrast, the Cu-Cl distance from the equatorial chloride ligand is much shorter [2.2110 (7) Å]. Intermolecular N - H⋯Cl and C - H⋯Cl hydrogen bonds link the complexes into a threedimensional network.

Original languageEnglish
Pages (from-to)m123
JournalActa Crystallographica Section E: Structure Reports Online
Volume67
Issue number1
DOIs
Publication statusPublished - 2011 Jan 1

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Copper
Ligands
copper
ligands
Chlorides
chlorides
chelates
Hydrogen bonds
hydrogen bonds
Atoms
Geometry
geometry
atoms
cupric chloride

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

Cite this

@article{937918416c2d42b2b12894346c62c5fc,
title = "Dichlorido{N′-[1-(2-pyridin-2-yl)ethylidene] acetohydrazide- κ2N′,O}copper(II)",
abstract = "In the title compound, [CuCl2(C9H11N 3O)], the CuII atom is in a distorted square-pyramidal CuCl2N2O coordination geometry. The tridentate acetohydrazide ligand chelates in a meridional fashion. The chloride ligand in the axial position forms a long Cu-Cl distance of 2.4892 (9) {\AA}. In contrast, the Cu-Cl distance from the equatorial chloride ligand is much shorter [2.2110 (7) {\AA}]. Intermolecular N - H⋯Cl and C - H⋯Cl hydrogen bonds link the complexes into a threedimensional network.",
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Dichlorido{N′-[1-(2-pyridin-2-yl)ethylidene] acetohydrazide- κ2N′,O}copper(II). / Datta, Amitabha; Das, Kuheli; Jhou, Yan Ming; Huang, Jui Hsien; Lee, Hon Man.

In: Acta Crystallographica Section E: Structure Reports Online, Vol. 67, No. 1, 01.01.2011, p. m123.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Dichlorido{N′-[1-(2-pyridin-2-yl)ethylidene] acetohydrazide- κ2N′,O}copper(II)

AU - Datta, Amitabha

AU - Das, Kuheli

AU - Jhou, Yan Ming

AU - Huang, Jui Hsien

AU - Lee, Hon Man

PY - 2011/1/1

Y1 - 2011/1/1

N2 - In the title compound, [CuCl2(C9H11N 3O)], the CuII atom is in a distorted square-pyramidal CuCl2N2O coordination geometry. The tridentate acetohydrazide ligand chelates in a meridional fashion. The chloride ligand in the axial position forms a long Cu-Cl distance of 2.4892 (9) Å. In contrast, the Cu-Cl distance from the equatorial chloride ligand is much shorter [2.2110 (7) Å]. Intermolecular N - H⋯Cl and C - H⋯Cl hydrogen bonds link the complexes into a threedimensional network.

AB - In the title compound, [CuCl2(C9H11N 3O)], the CuII atom is in a distorted square-pyramidal CuCl2N2O coordination geometry. The tridentate acetohydrazide ligand chelates in a meridional fashion. The chloride ligand in the axial position forms a long Cu-Cl distance of 2.4892 (9) Å. In contrast, the Cu-Cl distance from the equatorial chloride ligand is much shorter [2.2110 (7) Å]. Intermolecular N - H⋯Cl and C - H⋯Cl hydrogen bonds link the complexes into a threedimensional network.

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