Dichlorido{2-[2-(dimethyl-ammonio)ethyl-imino-meth-yl]-6-methoxy-phenolato} zinc(II)

Amitabha Datta, Nien Tsu Chuang, Jui Hsien Huang, Hon Man Lee

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

The structure of the title complex, [ZnCl2(C12H 18N2O2)], contains a zwitterionic Schiff base ligand. The complex adopts a distorted tetra-hedral coordination geometry around the metal centre with the Schiff base ligand coordinated in a bidentate fashion via the imine N and phenolate O atoms. In the crystal, inter-molecular N - H⋯O and C - H⋯Cl hydrogen bonds link the mol-ecules into chains parallel to the c-glide planes.

Original languageEnglish
Pages (from-to)m964
JournalActa Crystallographica Section E: Structure Reports Online
Volume65
Issue number8
DOIs
Publication statusPublished - 2009 Aug 20

Fingerprint

Schiff Bases
imines
Zinc
zinc
Ligands
Imines
Hydrogen bonds
ligands
Metals
Atoms
Crystals
Geometry
hydrogen bonds
geometry
metals
crystals
atoms

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

Cite this

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abstract = "The structure of the title complex, [ZnCl2(C12H 18N2O2)], contains a zwitterionic Schiff base ligand. The complex adopts a distorted tetra-hedral coordination geometry around the metal centre with the Schiff base ligand coordinated in a bidentate fashion via the imine N and phenolate O atoms. In the crystal, inter-molecular N - H⋯O and C - H⋯Cl hydrogen bonds link the mol-ecules into chains parallel to the c-glide planes.",
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Dichlorido{2-[2-(dimethyl-ammonio)ethyl-imino-meth-yl]-6-methoxy-phenolato} zinc(II). / Datta, Amitabha; Chuang, Nien Tsu; Huang, Jui Hsien; Lee, Hon Man.

In: Acta Crystallographica Section E: Structure Reports Online, Vol. 65, No. 8, 20.08.2009, p. m964.

Research output: Contribution to journalArticle

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T1 - Dichlorido{2-[2-(dimethyl-ammonio)ethyl-imino-meth-yl]-6-methoxy-phenolato} zinc(II)

AU - Datta, Amitabha

AU - Chuang, Nien Tsu

AU - Huang, Jui Hsien

AU - Lee, Hon Man

PY - 2009/8/20

Y1 - 2009/8/20

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AB - The structure of the title complex, [ZnCl2(C12H 18N2O2)], contains a zwitterionic Schiff base ligand. The complex adopts a distorted tetra-hedral coordination geometry around the metal centre with the Schiff base ligand coordinated in a bidentate fashion via the imine N and phenolate O atoms. In the crystal, inter-molecular N - H⋯O and C - H⋯Cl hydrogen bonds link the mol-ecules into chains parallel to the c-glide planes.

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