Dichlorido{2-[2-(dimethyl-ammonio)ethyl-imino-meth-yl]-6-methoxy-phenolato} zinc(II)

Amitabha Datta; Nien Tsu Chuang; Jui Hsien Huang; Hon Man Lee

doi:10.1107/S1600536809028220

Dichlorido{2-[2-(dimethyl-ammonio)ethyl-imino-meth-yl]-6-methoxy-phenolato} zinc(II)

Amitabha Datta, Nien Tsu Chuang, Jui Hsien Huang, Hon Man Lee

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

The structure of the title complex, [ZnCl₂(C₁₂H ₁₈N₂O₂)], contains a zwitterionic Schiff base ligand. The complex adopts a distorted tetra-hedral coordination geometry around the metal centre with the Schiff base ligand coordinated in a bidentate fashion via the imine N and phenolate O atoms. In the crystal, inter-molecular N - H⋯O and C - H⋯Cl hydrogen bonds link the mol-ecules into chains parallel to the c-glide planes.

Original language	English
Pages (from-to)	m964
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	65
Issue number	8
DOIs	https://doi.org/10.1107/S1600536809028220
Publication status	Published - 2009

All Science Journal Classification (ASJC) codes

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

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title = "Dichlorido{2-[2-(dimethyl-ammonio)ethyl-imino-meth-yl]-6-methoxy-phenolato} zinc(II)",

abstract = "The structure of the title complex, [ZnCl2(C12H 18N2O2)], contains a zwitterionic Schiff base ligand. The complex adopts a distorted tetra-hedral coordination geometry around the metal centre with the Schiff base ligand coordinated in a bidentate fashion via the imine N and phenolate O atoms. In the crystal, inter-molecular N - H⋯O and C - H⋯Cl hydrogen bonds link the mol-ecules into chains parallel to the c-glide planes.",

author = "Amitabha Datta and Chuang, {Nien Tsu} and Huang, {Jui Hsien} and Lee, {Hon Man}",

year = "2009",

doi = "10.1107/S1600536809028220",

language = "English",

volume = "65",

pages = "m964",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

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T1 - Dichlorido{2-[2-(dimethyl-ammonio)ethyl-imino-meth-yl]-6-methoxy-phenolato} zinc(II)

AU - Datta, Amitabha

AU - Chuang, Nien Tsu

AU - Huang, Jui Hsien

AU - Lee, Hon Man

PY - 2009

Y1 - 2009

N2 - The structure of the title complex, [ZnCl2(C12H 18N2O2)], contains a zwitterionic Schiff base ligand. The complex adopts a distorted tetra-hedral coordination geometry around the metal centre with the Schiff base ligand coordinated in a bidentate fashion via the imine N and phenolate O atoms. In the crystal, inter-molecular N - H⋯O and C - H⋯Cl hydrogen bonds link the mol-ecules into chains parallel to the c-glide planes.

AB - The structure of the title complex, [ZnCl2(C12H 18N2O2)], contains a zwitterionic Schiff base ligand. The complex adopts a distorted tetra-hedral coordination geometry around the metal centre with the Schiff base ligand coordinated in a bidentate fashion via the imine N and phenolate O atoms. In the crystal, inter-molecular N - H⋯O and C - H⋯Cl hydrogen bonds link the mol-ecules into chains parallel to the c-glide planes.

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U2 - 10.1107/S1600536809028220

DO - 10.1107/S1600536809028220

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JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

SN - 1600-5368

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ER -