Diaqua{2,2′-dimethoxy-6,6′-[(1E,1′E)-propane-1, 3-diylbis(azanylylidene)bis(methanylylidene)]diphenolato}nickel(II)

Amitabha Datta, Barbara Machura, Jui Hsien Huang, Shiann Cherng Sheu

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

In the molecule of the title compound, [Ni(C19H20N2O4)(H2O)2], the central NiII ion lies on a mirror plane and is surrounded by an N2O4 coordination set in the form of a distorted octahedron defined by the O atoms of two water molecules and by two phenolic O and two imine N atoms of the tetradentate Schiff base ligand. In the crystal, O - H...O hydrogen bonds between the water molecules and the phenolic and methoxy O atoms of neighbouring molecules lead to the formation of rods propagating parallel to [100].

Original languageEnglish
Pages (from-to)m399
JournalActa Crystallographica Section E: Structure Reports Online
Volume69
Issue number7
DOIs
Publication statusPublished - 2013 Jul 1

Fingerprint

Propane
Nickel
propane
nickel
Molecules
Atoms
imines
molecules
atoms
Imines
Schiff Bases
Water
water
Hydrogen bonds
Mirrors
rods
Ligands
Ions
mirrors
hydrogen bonds

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

Cite this

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title = "Diaqua{2,2′-dimethoxy-6,6′-[(1E,1′E)-propane-1, 3-diylbis(azanylylidene)bis(methanylylidene)]diphenolato}nickel(II)",
abstract = "In the molecule of the title compound, [Ni(C19H20N2O4)(H2O)2], the central NiII ion lies on a mirror plane and is surrounded by an N2O4 coordination set in the form of a distorted octahedron defined by the O atoms of two water molecules and by two phenolic O and two imine N atoms of the tetradentate Schiff base ligand. In the crystal, O - H...O hydrogen bonds between the water molecules and the phenolic and methoxy O atoms of neighbouring molecules lead to the formation of rods propagating parallel to [100].",
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Diaqua{2,2′-dimethoxy-6,6′-[(1E,1′E)-propane-1, 3-diylbis(azanylylidene)bis(methanylylidene)]diphenolato}nickel(II). / Datta, Amitabha; Machura, Barbara; Huang, Jui Hsien; Sheu, Shiann Cherng.

In: Acta Crystallographica Section E: Structure Reports Online, Vol. 69, No. 7, 01.07.2013, p. m399.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Diaqua{2,2′-dimethoxy-6,6′-[(1E,1′E)-propane-1, 3-diylbis(azanylylidene)bis(methanylylidene)]diphenolato}nickel(II)

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AU - Huang, Jui Hsien

AU - Sheu, Shiann Cherng

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N2 - In the molecule of the title compound, [Ni(C19H20N2O4)(H2O)2], the central NiII ion lies on a mirror plane and is surrounded by an N2O4 coordination set in the form of a distorted octahedron defined by the O atoms of two water molecules and by two phenolic O and two imine N atoms of the tetradentate Schiff base ligand. In the crystal, O - H...O hydrogen bonds between the water molecules and the phenolic and methoxy O atoms of neighbouring molecules lead to the formation of rods propagating parallel to [100].

AB - In the molecule of the title compound, [Ni(C19H20N2O4)(H2O)2], the central NiII ion lies on a mirror plane and is surrounded by an N2O4 coordination set in the form of a distorted octahedron defined by the O atoms of two water molecules and by two phenolic O and two imine N atoms of the tetradentate Schiff base ligand. In the crystal, O - H...O hydrogen bonds between the water molecules and the phenolic and methoxy O atoms of neighbouring molecules lead to the formation of rods propagating parallel to [100].

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