Di-μ-azido-bis({N′-[1-(2-pyridyl-κN)ethylidene] acetohydrazidato-κ2 N′,O}dicopper(II))

Amitabha Datta; Kuheli Das; Yan Ming Jhou; Jui Hsien Huang; Hon Man Lee

doi:10.1107/S1600536810034860

Di-μ-azido-bis({N′-[1-(2-pyridyl-κN)ethylidene] acetohydrazidato-κ² N′,O}dicopper(II))

Amitabha Datta, Kuheli Das, Yan Ming Jhou, Jui Hsien Huang, Hon Man Lee

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

The dimeric title compound, [Cu₂(C₉H ₁₀N₃O)₂(N₃)₂], is located on a crystallographic inversion center. The Cu atom is coordinated by a tridentate anionic hydrazone ligand and two bridging azide ligands in a distorted square-pyramidal coordination geometry. The non-bonding Cu⋯Cu distance is 3.238 (1) Å. Non-classical inter-molecular C - H⋯N hydrogen bonds link the dimers into chains along the c axis.

Original language	English
Pages (from-to)	m1271
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	66
Issue number	10
DOIs	https://doi.org/10.1107/S1600536810034860
Publication status	Published - 2010 Oct

All Science Journal Classification (ASJC) codes

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

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@article{bc9589d8eccd4bd8b44908fc85eb2e19,

title = "Di-μ-azido-bis({N′-[1-(2-pyridyl-κN)ethylidene] acetohydrazidato-κ2 N′,O}dicopper(II))",

abstract = "The dimeric title compound, [Cu2(C9H 10N3O)2(N3)2], is located on a crystallographic inversion center. The Cu atom is coordinated by a tridentate anionic hydrazone ligand and two bridging azide ligands in a distorted square-pyramidal coordination geometry. The non-bonding Cu⋯Cu distance is 3.238 (1) {\AA}. Non-classical inter-molecular C - H⋯N hydrogen bonds link the dimers into chains along the c axis.",

author = "Amitabha Datta and Kuheli Das and Jhou, {Yan Ming} and Huang, {Jui Hsien} and Lee, {Hon Man}",

year = "2010",

month = oct,

doi = "10.1107/S1600536810034860",

language = "English",

volume = "66",

pages = "m1271",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "10",

}

TY - JOUR

T1 - Di-μ-azido-bis({N′-[1-(2-pyridyl-κN)ethylidene] acetohydrazidato-κ2 N′,O}dicopper(II))

AU - Datta, Amitabha

AU - Das, Kuheli

AU - Jhou, Yan Ming

AU - Huang, Jui Hsien

AU - Lee, Hon Man

PY - 2010/10

Y1 - 2010/10

N2 - The dimeric title compound, [Cu2(C9H 10N3O)2(N3)2], is located on a crystallographic inversion center. The Cu atom is coordinated by a tridentate anionic hydrazone ligand and two bridging azide ligands in a distorted square-pyramidal coordination geometry. The non-bonding Cu⋯Cu distance is 3.238 (1) Å. Non-classical inter-molecular C - H⋯N hydrogen bonds link the dimers into chains along the c axis.

AB - The dimeric title compound, [Cu2(C9H 10N3O)2(N3)2], is located on a crystallographic inversion center. The Cu atom is coordinated by a tridentate anionic hydrazone ligand and two bridging azide ligands in a distorted square-pyramidal coordination geometry. The non-bonding Cu⋯Cu distance is 3.238 (1) Å. Non-classical inter-molecular C - H⋯N hydrogen bonds link the dimers into chains along the c axis.

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U2 - 10.1107/S1600536810034860

DO - 10.1107/S1600536810034860

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SP - m1271

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

SN - 1600-5368

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