Abstract
The dimeric title compound, [Cu2(C9H 10N3O)2(N3)2], is located on a crystallographic inversion center. The Cu atom is coordinated by a tridentate anionic hydrazone ligand and two bridging azide ligands in a distorted square-pyramidal coordination geometry. The non-bonding Cu⋯Cu distance is 3.238 (1) Å. Non-classical inter-molecular C - H⋯N hydrogen bonds link the dimers into chains along the c axis.
| Original language | English |
|---|---|
| Pages (from-to) | m1271 |
| Journal | Acta Crystallographica Section E: Structure Reports Online |
| Volume | 66 |
| Issue number | 10 |
| DOIs | |
| Publication status | Published - 2010 Oct 1 |
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All Science Journal Classification (ASJC) codes
- Chemistry(all)
- Materials Science(all)
- Condensed Matter Physics
Cite this
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Di-μ-azido-bis({N′-[1-(2-pyridyl-κN)ethylidene] acetohydrazidato-κ2 N′,O}dicopper(II)). / Datta, Amitabha; Das, Kuheli; Jhou, Yan Ming; Huang, Jui Hsien; Lee, Hon Man.
In: Acta Crystallographica Section E: Structure Reports Online, Vol. 66, No. 10, 01.10.2010, p. m1271.Research output: Contribution to journal › Article
TY - JOUR
T1 - Di-μ-azido-bis({N′-[1-(2-pyridyl-κN)ethylidene] acetohydrazidato-κ2 N′,O}dicopper(II))
AU - Datta, Amitabha
AU - Das, Kuheli
AU - Jhou, Yan Ming
AU - Huang, Jui Hsien
AU - Lee, Hon Man
PY - 2010/10/1
Y1 - 2010/10/1
N2 - The dimeric title compound, [Cu2(C9H 10N3O)2(N3)2], is located on a crystallographic inversion center. The Cu atom is coordinated by a tridentate anionic hydrazone ligand and two bridging azide ligands in a distorted square-pyramidal coordination geometry. The non-bonding Cu⋯Cu distance is 3.238 (1) Å. Non-classical inter-molecular C - H⋯N hydrogen bonds link the dimers into chains along the c axis.
AB - The dimeric title compound, [Cu2(C9H 10N3O)2(N3)2], is located on a crystallographic inversion center. The Cu atom is coordinated by a tridentate anionic hydrazone ligand and two bridging azide ligands in a distorted square-pyramidal coordination geometry. The non-bonding Cu⋯Cu distance is 3.238 (1) Å. Non-classical inter-molecular C - H⋯N hydrogen bonds link the dimers into chains along the c axis.
UR - http://www.scopus.com/inward/record.url?scp=77957852901&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=77957852901&partnerID=8YFLogxK
U2 - 10.1107/S1600536810034860
DO - 10.1107/S1600536810034860
M3 - Article
C2 - 21587416
AN - SCOPUS:77957852901
VL - 66
SP - m1271
JO - Acta Crystallographica Section E: Structure Reports Online
JF - Acta Crystallographica Section E: Structure Reports Online
SN - 1600-5368
IS - 10
ER -