Di-μ-azido-bis({N′-[1-(2-pyridyl-κN)ethylidene] acetohydrazidato-κ2 N′,O}dicopper(II))

Amitabha Datta, Kuheli Das, Yan Ming Jhou, Jui Hsien Huang, Hon Man Lee

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

The dimeric title compound, [Cu2(C9H 10N3O)2(N3)2], is located on a crystallographic inversion center. The Cu atom is coordinated by a tridentate anionic hydrazone ligand and two bridging azide ligands in a distorted square-pyramidal coordination geometry. The non-bonding Cu⋯Cu distance is 3.238 (1) Å. Non-classical inter-molecular C - H⋯N hydrogen bonds link the dimers into chains along the c axis.

Original languageEnglish
Pages (from-to)m1271
JournalActa Crystallographica Section E: Structure Reports Online
Volume66
Issue number10
DOIs
Publication statusPublished - 2010 Oct 1

Fingerprint

Ligands
Hydrazones
hydrazones
ligands
Azides
Dimers
Hydrogen bonds
dimers
inversions
hydrogen bonds
Atoms
Geometry
geometry
atoms

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

Cite this

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title = "Di-μ-azido-bis({N′-[1-(2-pyridyl-κN)ethylidene] acetohydrazidato-κ2 N′,O}dicopper(II))",
abstract = "The dimeric title compound, [Cu2(C9H 10N3O)2(N3)2], is located on a crystallographic inversion center. The Cu atom is coordinated by a tridentate anionic hydrazone ligand and two bridging azide ligands in a distorted square-pyramidal coordination geometry. The non-bonding Cu⋯Cu distance is 3.238 (1) {\AA}. Non-classical inter-molecular C - H⋯N hydrogen bonds link the dimers into chains along the c axis.",
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Di-μ-azido-bis({N′-[1-(2-pyridyl-κN)ethylidene] acetohydrazidato-κ2 N′,O}dicopper(II)). / Datta, Amitabha; Das, Kuheli; Jhou, Yan Ming; Huang, Jui Hsien; Lee, Hon Man.

In: Acta Crystallographica Section E: Structure Reports Online, Vol. 66, No. 10, 01.10.2010, p. m1271.

Research output: Contribution to journalArticle

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T1 - Di-μ-azido-bis({N′-[1-(2-pyridyl-κN)ethylidene] acetohydrazidato-κ2 N′,O}dicopper(II))

AU - Datta, Amitabha

AU - Das, Kuheli

AU - Jhou, Yan Ming

AU - Huang, Jui Hsien

AU - Lee, Hon Man

PY - 2010/10/1

Y1 - 2010/10/1

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AB - The dimeric title compound, [Cu2(C9H 10N3O)2(N3)2], is located on a crystallographic inversion center. The Cu atom is coordinated by a tridentate anionic hydrazone ligand and two bridging azide ligands in a distorted square-pyramidal coordination geometry. The non-bonding Cu⋯Cu distance is 3.238 (1) Å. Non-classical inter-molecular C - H⋯N hydrogen bonds link the dimers into chains along the c axis.

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