Abstract
The dimeric title compound, [Cu2(C9H 10N3O)2(N3)2], is located on a crystallographic inversion center. The Cu atom is coordinated by a tridentate anionic hydrazone ligand and two bridging azide ligands in a distorted square-pyramidal coordination geometry. The non-bonding Cu⋯Cu distance is 3.238 (1) Å. Non-classical inter-molecular C - H⋯N hydrogen bonds link the dimers into chains along the c axis.
| Original language | English |
|---|---|
| Pages (from-to) | m1271 |
| Journal | Acta Crystallographica Section E: Structure Reports Online |
| Volume | 66 |
| Issue number | 10 |
| DOIs | |
| Publication status | Published - 2010 Oct |
All Science Journal Classification (ASJC) codes
- Chemistry(all)
- Materials Science(all)
- Condensed Matter Physics
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Cite this
Datta, A., Das, K., Jhou, Y. M., Huang, J. H., & Lee, H. M. (2010). Di-μ-azido-bis({N′-[1-(2-pyridyl-κN)ethylidene] acetohydrazidato-κ2 N′,O}dicopper(II)). Acta Crystallographica Section E: Structure Reports Online, 66(10), m1271. https://doi.org/10.1107/S1600536810034860