Abstract
The demetalation of MIII(HCTPPO)Br (M = Mn or Fe) afforded two hydroxylated N-confused porphyrinoids. CTPPOH retains the tautomer form of the N-confused porphyrin with a hydroxyl group substituted in the inner-core carbon. The further attack of OH- to the meso carbon afforded a dihydroxylated N-confused macrocycle, CTPP(OH)2.
Original language | English |
---|---|
Pages (from-to) | 1393-1396 |
Number of pages | 4 |
Journal | Organic Letters |
Volume | 6 |
Issue number | 9 |
DOIs | |
Publication status | Published - 2004 Apr 29 |
All Science Journal Classification (ASJC) codes
- Biochemistry
- Physical and Theoretical Chemistry
- Organic Chemistry