Demetalation of the regioselective oxygenation product of an N-confused porphyrin complex

Chen Hsiung Hung; Shan Ling Wang; Jia Ling Ko; Chih Hsiung Peng; Ching Han Hu; Ming Tsung Lee

doi:10.1021/ol049757b

Demetalation of the regioselective oxygenation product of an N-confused porphyrin complex

Chen Hsiung Hung, Shan Ling Wang, Jia Ling Ko, Chih Hsiung Peng, Ching Han Hu, Ming Tsung Lee

Department of Chemistry

Research output: Contribution to journal › Article

31 Citations (Scopus)

Abstract

The demetalation of M^III(HCTPPO)Br (M = Mn or Fe) afforded two hydroxylated N-confused porphyrinoids. CTPPOH retains the tautomer form of the N-confused porphyrin with a hydroxyl group substituted in the inner-core carbon. The further attack of OH^- to the meso carbon afforded a dihydroxylated N-confused macrocycle, CTPP(OH)₂.

Original language	English
Pages (from-to)	1393-1396
Number of pages	4
Journal	Organic Letters
Volume	6
Issue number	9
DOIs	https://doi.org/10.1021/ol049757b
Publication status	Published - 2004 Apr 29

All Science Journal Classification (ASJC) codes

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

Access to Document

10.1021/ol049757b

Fingerprint Dive into the research topics of 'Demetalation of the regioselective oxygenation product of an N-confused porphyrin complex'. Together they form a unique fingerprint.

Cite this

@article{376669ed8c414802b2bcc74e4b28dcf5,

title = "Demetalation of the regioselective oxygenation product of an N-confused porphyrin complex",

abstract = "The demetalation of MIII(HCTPPO)Br (M = Mn or Fe) afforded two hydroxylated N-confused porphyrinoids. CTPPOH retains the tautomer form of the N-confused porphyrin with a hydroxyl group substituted in the inner-core carbon. The further attack of OH- to the meso carbon afforded a dihydroxylated N-confused macrocycle, CTPP(OH)2.",

author = "Hung, {Chen Hsiung} and Wang, {Shan Ling} and Ko, {Jia Ling} and Peng, {Chih Hsiung} and Hu, {Ching Han} and Lee, {Ming Tsung}",

year = "2004",

month = apr,

day = "29",

doi = "10.1021/ol049757b",

language = "English",

volume = "6",

pages = "1393--1396",

journal = "Organic Letters",

issn = "1523-7060",

publisher = "American Chemical Society",

number = "9",

}

TY - JOUR

T1 - Demetalation of the regioselective oxygenation product of an N-confused porphyrin complex

AU - Hung, Chen Hsiung

AU - Wang, Shan Ling

AU - Ko, Jia Ling

AU - Peng, Chih Hsiung

AU - Hu, Ching Han

AU - Lee, Ming Tsung

PY - 2004/4/29

Y1 - 2004/4/29

N2 - The demetalation of MIII(HCTPPO)Br (M = Mn or Fe) afforded two hydroxylated N-confused porphyrinoids. CTPPOH retains the tautomer form of the N-confused porphyrin with a hydroxyl group substituted in the inner-core carbon. The further attack of OH- to the meso carbon afforded a dihydroxylated N-confused macrocycle, CTPP(OH)2.

AB - The demetalation of MIII(HCTPPO)Br (M = Mn or Fe) afforded two hydroxylated N-confused porphyrinoids. CTPPOH retains the tautomer form of the N-confused porphyrin with a hydroxyl group substituted in the inner-core carbon. The further attack of OH- to the meso carbon afforded a dihydroxylated N-confused macrocycle, CTPP(OH)2.

UR - http://www.scopus.com/inward/record.url?scp=2442602441&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=2442602441&partnerID=8YFLogxK

U2 - 10.1021/ol049757b

DO - 10.1021/ol049757b

M3 - Article

C2 - 15101750

AN - SCOPUS:2442602441

VL - 6

SP - 1393

EP - 1396

JO - Organic Letters

JF - Organic Letters

SN - 1523-7060

IS - 9

ER -