Demetalation of the regioselective oxygenation product of an N-confused porphyrin complex

Chen Hsiung Hung, Shan Ling Wang, Jia Ling Ko, Chih Hsiung Peng, Ching Han Hu, Ming Tsung Lee

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Abstract

The demetalation of MIII(HCTPPO)Br (M = Mn or Fe) afforded two hydroxylated N-confused porphyrinoids. CTPPOH retains the tautomer form of the N-confused porphyrin with a hydroxyl group substituted in the inner-core carbon. The further attack of OH- to the meso carbon afforded a dihydroxylated N-confused macrocycle, CTPP(OH)2.

Original languageEnglish
Pages (from-to)1393-1396
Number of pages4
JournalOrganic Letters
Volume6
Issue number9
DOIs
Publication statusPublished - 2004 Apr 29

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All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

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