Demetalation of the regioselective oxygenation product of an N-confused porphyrin complex

Chen Hsiung Hung, Shan Ling Wang, Jia Ling Ko, Chih Hsiung Peng, Ching Han Hu, Ming Tsung Lee

Research output: Contribution to journal › Article

31 Citations (Scopus)

Abstract

The demetalation of MIII(HCTPPO)Br (M = Mn or Fe) afforded two hydroxylated N-confused porphyrinoids. CTPPOH retains the tautomer form of the N-confused porphyrin with a hydroxyl group substituted in the inner-core carbon. The further attack of OH- to the meso carbon afforded a dihydroxylated N-confused macrocycle, CTPP(OH)2.

Original languageEnglish
Pages (from-to)1393-1396
Number of pages4
JournalOrganic Letters
Volume6
Issue number9
DOIs
Publication statusPublished - 2004 Apr 29

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Oxygenation
oxygenation
Porphyrins
porphyrins
Carbon
carbon
tautomers
products
Hydroxyl Radical
attack
hydroxide ion

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

Cite this

Hung, Chen Hsiung ; Wang, Shan Ling ; Ko, Jia Ling ; Peng, Chih Hsiung ; Hu, Ching Han ; Lee, Ming Tsung. / Demetalation of the regioselective oxygenation product of an N-confused porphyrin complex. In: Organic Letters. 2004 ; Vol. 6, No. 9. pp. 1393-1396.
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Hung, CH, Wang, SL, Ko, JL, Peng, CH, Hu, CH & Lee, MT 2004, 'Demetalation of the regioselective oxygenation product of an N-confused porphyrin complex', Organic Letters, vol. 6, no. 9, pp. 1393-1396. https://doi.org/10.1021/ol049757b

Demetalation of the regioselective oxygenation product of an N-confused porphyrin complex. / Hung, Chen Hsiung; Wang, Shan Ling; Ko, Jia Ling; Peng, Chih Hsiung; Hu, Ching Han; Lee, Ming Tsung.

In: Organic Letters, Vol. 6, No. 9, 29.04.2004, p. 1393-1396.

Research output: Contribution to journal › Article

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Hung CH, Wang SL, Ko JL, Peng CH, Hu CH, Lee MT. Demetalation of the regioselective oxygenation product of an N-confused porphyrin complex. Organic Letters. 2004 Apr 29;6(9):1393-1396. https://doi.org/10.1021/ol049757b

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