Crystallographic characterization of Isomer 2 of Er2@C82 and comparison with Isomer 1 of Er2@C82

Marilyn M. Olmstead; Hon Man Lee; Steve Stevenson; Harry C. Dorn; Alan L. Balch

doi:10.1039/b209270k

Crystallographic characterization of Isomer 2 of Er₂@C₈₂ and comparison with Isomer 1 of Er₂@C₈₂

Marilyn M. Olmstead, Hon Man Lee, Steve Stevenson, Harry C. Dorn, Alan L. Balch

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

57 Citations (Scopus)

Abstract

The X-ray crystal structure of (Isomer 2 of Er₂@C₈₂)·Ni^II(OEP)·2(benzene) shows that the fullerene cage in Isomer 2 of Er₂@C₈₂ is the C_3v isomer (82:8) and that the erbium ions are distributed over 23 interior sites with occupancies ranging from 0.25 to 0.03.

Original language	English
Pages (from-to)	2688-2689
Number of pages	2
Journal	Chemical Communications
Volume	2
Issue number	22
DOIs	https://doi.org/10.1039/b209270k
Publication status	Published - 2002

All Science Journal Classification (ASJC) codes

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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title = "Crystallographic characterization of Isomer 2 of Er2@C82 and comparison with Isomer 1 of Er2@C82",

abstract = "The X-ray crystal structure of (Isomer 2 of Er2@C82)·NiII(OEP)·2(benzene) shows that the fullerene cage in Isomer 2 of Er2@C82 is the C3v isomer (82:8) and that the erbium ions are distributed over 23 interior sites with occupancies ranging from 0.25 to 0.03.",

author = "Olmstead, {Marilyn M.} and Lee, {Hon Man} and Steve Stevenson and Dorn, {Harry C.} and Balch, {Alan L.}",

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AU - Dorn, Harry C.

AU - Balch, Alan L.

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AB - The X-ray crystal structure of (Isomer 2 of Er2@C82)·NiII(OEP)·2(benzene) shows that the fullerene cage in Isomer 2 of Er2@C82 is the C3v isomer (82:8) and that the erbium ions are distributed over 23 interior sites with occupancies ranging from 0.25 to 0.03.

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