Abstract
The structure of Sc3N@C80-C10H12O2, a Diels-Alder cycloadduct of Sc3N@C80, has been determined. The crystallographic data shows that cycloaddition occurs at a C-C bond of 6:5 ring junction, and that the fullerene C1-C2 bond is elongated and pulled out from the fullerene. The Sc3N unit is well-ordered within the C80 cage and positioned away from the site of addition. The proximity of the Sc atoms to the cage carbon atoms causes those carbon atoms to protrude slightly from the surface of the fullerene cage.
| Original language | English |
|---|---|
| Pages (from-to) | 3494-3495 |
| Number of pages | 2 |
| Journal | Journal of the American Chemical Society |
| Volume | 124 |
| Issue number | 14 |
| DOIs | |
| Publication status | Published - 2002 Apr 10 |
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All Science Journal Classification (ASJC) codes
- Catalysis
- Chemistry(all)
- Biochemistry
- Colloid and Surface Chemistry
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Crystallographic characterization and structural analysis of the first organic functionalization product of the endohedral fullerene Sc3N@C80. / Lee, Hon Man; Olmstead, Marilyn M.; Iezzi, Erick; Duchamp, James C.; Dorn, Harry C.; Balch, Alan L.
In: Journal of the American Chemical Society, Vol. 124, No. 14, 10.04.2002, p. 3494-3495.Research output: Contribution to journal › Article
TY - JOUR
T1 - Crystallographic characterization and structural analysis of the first organic functionalization product of the endohedral fullerene Sc3N@C80
AU - Lee, Hon Man
AU - Olmstead, Marilyn M.
AU - Iezzi, Erick
AU - Duchamp, James C.
AU - Dorn, Harry C.
AU - Balch, Alan L.
PY - 2002/4/10
Y1 - 2002/4/10
N2 - The structure of Sc3N@C80-C10H12O2, a Diels-Alder cycloadduct of Sc3N@C80, has been determined. The crystallographic data shows that cycloaddition occurs at a C-C bond of 6:5 ring junction, and that the fullerene C1-C2 bond is elongated and pulled out from the fullerene. The Sc3N unit is well-ordered within the C80 cage and positioned away from the site of addition. The proximity of the Sc atoms to the cage carbon atoms causes those carbon atoms to protrude slightly from the surface of the fullerene cage.
AB - The structure of Sc3N@C80-C10H12O2, a Diels-Alder cycloadduct of Sc3N@C80, has been determined. The crystallographic data shows that cycloaddition occurs at a C-C bond of 6:5 ring junction, and that the fullerene C1-C2 bond is elongated and pulled out from the fullerene. The Sc3N unit is well-ordered within the C80 cage and positioned away from the site of addition. The proximity of the Sc atoms to the cage carbon atoms causes those carbon atoms to protrude slightly from the surface of the fullerene cage.
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UR - http://www.scopus.com/inward/citedby.url?scp=0037051642&partnerID=8YFLogxK
U2 - 10.1021/ja020065x
DO - 10.1021/ja020065x
M3 - Article
C2 - 11929224
AN - SCOPUS:0037051642
VL - 124
SP - 3494
EP - 3495
JO - Journal of the American Chemical Society
JF - Journal of the American Chemical Society
SN - 0002-7863
IS - 14
ER -