Coordination polymers of silver(I) with bis(N-heterocyclic carbene): Structural characterization and carbene transfer

Pei Ling Chiu, Chih Yuan Chen, Jing Yao Zeng, Chi Ying Lu, Hon Man Lee

Research output: Contribution to journalShort survey

61 Citations (Scopus)

Abstract

Reactions of the ethylene- and methylene-bridged bis(imidazolium) salts with an equivalent amount of silver oxide in dichloromethane at room temperature produced readily the silver NHC compounds [Ag2LBr2]. These compounds are partially soluble in DMF. The X-ray structure determination on 3d (L = 1,1′-dibenzyl-3,3′-ethylenediimidazolin-2,2′- diylidene) reveals the formation of bromide bibridged (Ag2LBr 2)n chains and a unique supramolecular motif with weak Ag⋯Ag interactions of 3.429 Å. Similar to monomeric silver(I) NHC complexes, the silver coordination polymers can also act as carbene transfer reagents for the formation of chelating palladium NHC complexes in excellent yields.

Original languageEnglish
Pages (from-to)1682-1687
Number of pages6
JournalJournal of Organometallic Chemistry
Volume690
Issue number6
DOIs
Publication statusPublished - 2005 Mar 15

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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