Bis(tert-butylimido)[2-(dimethylaminomethyl)-pyrrol-1-yl]tungsten(VI) -μ-oxo-bis(tert-butylimido)-(η 2-N,O-tert-butylnitroso)tungsten(VI)

Chia Liang Uno, Pei Cheng Kuo, Hon Man Lee, Jui Hsien Huang

Research output: Contribution to journalArticle

Abstract

The determination of [W2(C4H9N) 4(C7H 11N2)-(C4H 10NO)O] was discussed. The organoimide compounds involving monoanionic monodentate ligands were commonly observed. The two tungsten centers were linked by a μ-oxo bridge with a bond angle of 159.69 (16) Å. It was observed that the maximum and minimum electron-density peaks were 0.74 and 0.62 Å, respectively, from atom W2.

Original languageEnglish
JournalActa Crystallographica Section E: Structure Reports Online
Volume61
Issue number4
DOIs
Publication statusPublished - 2005 Apr 1

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Tungsten
Carrier concentration
tungsten
Ligands
Atoms
ligands
atoms

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

Cite this

@article{0bf06efec95744d5a4168e7d3bf2b964,
title = "Bis(tert-butylimido)[2-(dimethylaminomethyl)-pyrrol-1-yl]tungsten(VI) -μ-oxo-bis(tert-butylimido)-(η 2-N,O-tert-butylnitroso)tungsten(VI)",
abstract = "The determination of [W2(C4H9N) 4(C7H 11N2)-(C4H 10NO)O] was discussed. The organoimide compounds involving monoanionic monodentate ligands were commonly observed. The two tungsten centers were linked by a μ-oxo bridge with a bond angle of 159.69 (16) {\AA}. It was observed that the maximum and minimum electron-density peaks were 0.74 and 0.62 {\AA}, respectively, from atom W2.",
author = "Uno, {Chia Liang} and Kuo, {Pei Cheng} and Lee, {Hon Man} and Huang, {Jui Hsien}",
year = "2005",
month = "4",
day = "1",
doi = "10.1107/S1600536805007610",
language = "English",
volume = "61",
journal = "Acta Crystallographica Section E: Structure Reports Online",
issn = "1600-5368",
publisher = "International Union of Crystallography",
number = "4",

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TY - JOUR

T1 - Bis(tert-butylimido)[2-(dimethylaminomethyl)-pyrrol-1-yl]tungsten(VI) -μ-oxo-bis(tert-butylimido)-(η 2-N,O-tert-butylnitroso)tungsten(VI)

AU - Uno, Chia Liang

AU - Kuo, Pei Cheng

AU - Lee, Hon Man

AU - Huang, Jui Hsien

PY - 2005/4/1

Y1 - 2005/4/1

N2 - The determination of [W2(C4H9N) 4(C7H 11N2)-(C4H 10NO)O] was discussed. The organoimide compounds involving monoanionic monodentate ligands were commonly observed. The two tungsten centers were linked by a μ-oxo bridge with a bond angle of 159.69 (16) Å. It was observed that the maximum and minimum electron-density peaks were 0.74 and 0.62 Å, respectively, from atom W2.

AB - The determination of [W2(C4H9N) 4(C7H 11N2)-(C4H 10NO)O] was discussed. The organoimide compounds involving monoanionic monodentate ligands were commonly observed. The two tungsten centers were linked by a μ-oxo bridge with a bond angle of 159.69 (16) Å. It was observed that the maximum and minimum electron-density peaks were 0.74 and 0.62 Å, respectively, from atom W2.

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U2 - 10.1107/S1600536805007610

DO - 10.1107/S1600536805007610

M3 - Article

VL - 61

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

SN - 1600-5368

IS - 4

ER -