Bis[N′-(2-pyridylmethyl-ene-N)benzo-hydrazide-N′] bis-(thio-cyanato-N)cobalt(II)

Amitabha Datta, Nien Tsu Chuang, Jui Hsien Huang, Hon Man Lee

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

In the title complex, [Co(NCS)2(C13H 11N3O)2], the CoII centre adopts a distorted octa-hedral coordination geometry with two cis-bidentate Schiff base ligands and two cis thio-cyanate ligands. The Schiff base ligand coordinates via the imine N and pyridine N atoms. The CoII atom lies on a crystallographic twofold rotational axis. Non-classical inter-molecular C - H⋯O hydrogen bonds link the complex mol-ecules into chains along [001].

Original languageEnglish
Pages (from-to)m996
JournalActa Crystallographica Section E: Structure Reports Online
Volume65
Issue number8
DOIs
Publication statusPublished - 2009 Aug 20

Fingerprint

hydrazides
Cobalt
imines
cobalt
Schiff Bases
Ligands
ligands
Cyanates
cyanates
Atoms
Pyridine
atoms
pyridines
Hydrogen bonds
hydrogen bonds
Geometry
geometry

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

Cite this

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title = "Bis[N′-(2-pyridylmethyl-ene-N)benzo-hydrazide-N′] bis-(thio-cyanato-N)cobalt(II)",
abstract = "In the title complex, [Co(NCS)2(C13H 11N3O)2], the CoII centre adopts a distorted octa-hedral coordination geometry with two cis-bidentate Schiff base ligands and two cis thio-cyanate ligands. The Schiff base ligand coordinates via the imine N and pyridine N atoms. The CoII atom lies on a crystallographic twofold rotational axis. Non-classical inter-molecular C - H⋯O hydrogen bonds link the complex mol-ecules into chains along [001].",
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Bis[N′-(2-pyridylmethyl-ene-N)benzo-hydrazide-N′] bis-(thio-cyanato-N)cobalt(II). / Datta, Amitabha; Chuang, Nien Tsu; Huang, Jui Hsien; Lee, Hon Man.

In: Acta Crystallographica Section E: Structure Reports Online, Vol. 65, No. 8, 20.08.2009, p. m996.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Bis[N′-(2-pyridylmethyl-ene-N)benzo-hydrazide-N′] bis-(thio-cyanato-N)cobalt(II)

AU - Datta, Amitabha

AU - Chuang, Nien Tsu

AU - Huang, Jui Hsien

AU - Lee, Hon Man

PY - 2009/8/20

Y1 - 2009/8/20

N2 - In the title complex, [Co(NCS)2(C13H 11N3O)2], the CoII centre adopts a distorted octa-hedral coordination geometry with two cis-bidentate Schiff base ligands and two cis thio-cyanate ligands. The Schiff base ligand coordinates via the imine N and pyridine N atoms. The CoII atom lies on a crystallographic twofold rotational axis. Non-classical inter-molecular C - H⋯O hydrogen bonds link the complex mol-ecules into chains along [001].

AB - In the title complex, [Co(NCS)2(C13H 11N3O)2], the CoII centre adopts a distorted octa-hedral coordination geometry with two cis-bidentate Schiff base ligands and two cis thio-cyanate ligands. The Schiff base ligand coordinates via the imine N and pyridine N atoms. The CoII atom lies on a crystallographic twofold rotational axis. Non-classical inter-molecular C - H⋯O hydrogen bonds link the complex mol-ecules into chains along [001].

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