Bis[2-(amino-meth-yl)pyridine-κ2 N,N′]bis-(thio- cyanato-κN)copper(II)

Nirmal Kumar Karan, Kai Ting Chan, Hon Man Lee

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

In the title complex, [Cu(NCS)2(C6H8N2)2], the CuII atom, lying on an inversion center, adopts a Jahn-Teller distorted octahedral CuN6 coordination geometry. The two bidentate 2-amino-methyl-pyridine ligands are coordinated in a trans fashion, while the two thio-cyanate ligands are at the axial positions and coordinate to the Cu atom in a bent mode with a C - N - Cu angle of 127.49 (10)°. Inter-molecular N - H⋯N and N - H⋯S hydrogen bonds link the copper complex mol-ecules into an infinite two-dimensional network.

Original languageEnglish
Pages (from-to)m525
JournalActa Crystallographica Section E: Structure Reports Online
Volume65
Issue number5
DOIs
Publication statusPublished - 2009 Jun 15

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Pyridine
Copper
pyridines
Ligands
Cyanates
cyanates
copper
Atoms
ligands
atoms
Hydrogen bonds
inversions
hydrogen bonds
Geometry
geometry
pyridine

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

Cite this

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abstract = "In the title complex, [Cu(NCS)2(C6H8N2)2], the CuII atom, lying on an inversion center, adopts a Jahn-Teller distorted octahedral CuN6 coordination geometry. The two bidentate 2-amino-methyl-pyridine ligands are coordinated in a trans fashion, while the two thio-cyanate ligands are at the axial positions and coordinate to the Cu atom in a bent mode with a C - N - Cu angle of 127.49 (10)°. Inter-molecular N - H⋯N and N - H⋯S hydrogen bonds link the copper complex mol-ecules into an infinite two-dimensional network.",
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Bis[2-(amino-meth-yl)pyridine-κ2 N,N′]bis-(thio- cyanato-κN)copper(II). / Karan, Nirmal Kumar; Chan, Kai Ting; Lee, Hon Man.

In: Acta Crystallographica Section E: Structure Reports Online, Vol. 65, No. 5, 15.06.2009, p. m525.

Research output: Contribution to journalArticle

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T1 - Bis[2-(amino-meth-yl)pyridine-κ2 N,N′]bis-(thio- cyanato-κN)copper(II)

AU - Karan, Nirmal Kumar

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Y1 - 2009/6/15

N2 - In the title complex, [Cu(NCS)2(C6H8N2)2], the CuII atom, lying on an inversion center, adopts a Jahn-Teller distorted octahedral CuN6 coordination geometry. The two bidentate 2-amino-methyl-pyridine ligands are coordinated in a trans fashion, while the two thio-cyanate ligands are at the axial positions and coordinate to the Cu atom in a bent mode with a C - N - Cu angle of 127.49 (10)°. Inter-molecular N - H⋯N and N - H⋯S hydrogen bonds link the copper complex mol-ecules into an infinite two-dimensional network.

AB - In the title complex, [Cu(NCS)2(C6H8N2)2], the CuII atom, lying on an inversion center, adopts a Jahn-Teller distorted octahedral CuN6 coordination geometry. The two bidentate 2-amino-methyl-pyridine ligands are coordinated in a trans fashion, while the two thio-cyanate ligands are at the axial positions and coordinate to the Cu atom in a bent mode with a C - N - Cu angle of 127.49 (10)°. Inter-molecular N - H⋯N and N - H⋯S hydrogen bonds link the copper complex mol-ecules into an infinite two-dimensional network.

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