Bis[2-(amino-meth-yl)pyridine-κ2 N,N′]bis-(thio- cyanato-κN)copper(II)

Nirmal Kumar Karan, Kai Ting Chan, Hon Man Lee

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

In the title complex, [Cu(NCS)2(C6H8N2)2], the CuII atom, lying on an inversion center, adopts a Jahn-Teller distorted octahedral CuN6 coordination geometry. The two bidentate 2-amino-methyl-pyridine ligands are coordinated in a trans fashion, while the two thio-cyanate ligands are at the axial positions and coordinate to the Cu atom in a bent mode with a C - N - Cu angle of 127.49 (10)°. Inter-molecular N - H⋯N and N - H⋯S hydrogen bonds link the copper complex mol-ecules into an infinite two-dimensional network.

Original languageEnglish
Pages (from-to)m525
JournalActa Crystallographica Section E: Structure Reports Online
Volume65
Issue number5
DOIs
Publication statusPublished - 2009 Jun 15

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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