Biphenolate phosphine complexes of tin(IV)

Lan Chang Liang, Yu Ning Chang, Han Sheng Chen, Man Lee Hon

Research output: Contribution to journalArticle

18 Citations (Scopus)

Abstract

The preparation and structural characterization of tin(IV) complexes supported by (2,2′-phenylphosphino)bis(4,6-di-tert-butylphenolate) ([OPO]2-) are described. The reaction of in-situ prepared Li 2[OPO] with SnCl4 in THF at -35°C produced [OPO]SnCl2(THF) as a THF adduct. Addition of SnCl4 to a THF solution of H2[OPO] in the presence of 2 equiv of NEt3 at room temperature led to the formation of the "ate" complex {[OPO]SnCl3}(HNEt3). The metathetical reactions of Li 2[OPO] with R2SnCl2 (R = Me, n-Bu) in THF at -35°C generated the corresponding five-coordinate dialkyl complexes [OPO]SnR2. In addition to the multinuclear NMR spectroscopic data for all new compounds, X-ray structures of [OPO]SnCl2(THF), [OPO]SnMe2, and [OPO]Sn(n-Bu)2 are presented.

Original languageEnglish
Pages (from-to)7587-7593
Number of pages7
JournalInorganic Chemistry
Volume46
Issue number18
DOIs
Publication statusPublished - 2007 Sep 3

Fingerprint

phosphine
Tin
phosphines
tin
adducts
Nuclear magnetic resonance
X rays
preparation
nuclear magnetic resonance
room temperature
x rays
Temperature
stannic chloride

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

Cite this

Liang, Lan Chang ; Chang, Yu Ning ; Chen, Han Sheng ; Hon, Man Lee. / Biphenolate phosphine complexes of tin(IV). In: Inorganic Chemistry. 2007 ; Vol. 46, No. 18. pp. 7587-7593.
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Liang, LC, Chang, YN, Chen, HS & Hon, ML 2007, 'Biphenolate phosphine complexes of tin(IV)', Inorganic Chemistry, vol. 46, no. 18, pp. 7587-7593. https://doi.org/10.1021/ic701006r

Biphenolate phosphine complexes of tin(IV). / Liang, Lan Chang; Chang, Yu Ning; Chen, Han Sheng; Hon, Man Lee.

In: Inorganic Chemistry, Vol. 46, No. 18, 03.09.2007, p. 7587-7593.

Research output: Contribution to journalArticle

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