Azido(benzoylacetonato-κ2 O,O')[1-phenyl-3-(2- pyridylmethylimino)but-1-en-1-olato-κ3 N,N',O]cobalt(III)

Amitabha Datta, Ming Han Sie, Jui-Hsien Huang, Hon Man Lee

Research output: Contribution to journalArticle

Abstract

In the title complex, [Co(C16H15N2O) (C10H9O2)(N3)], the CoII atom adopts an octa-hedral coordination geometry by a tridentate Schiff base, a bidentate benzoyl-acetonate and an azide ligand. The imine N atom of the tridentate ligand is trans to the benzoyl O atom of the bidentate ligand and the azide ligand is trans to the acetyl O atom of the bidentate ligand. Non-classical intra-molecular Car-yl - H⋯O hydrogen bonds are present in the structure.

Original languageEnglish
JournalActa Crystallographica Section E: Structure Reports Online
Volume66
Issue number3
DOIs
Publication statusPublished - 2010 Mar 19

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Cobalt
cobalt
Ligands
ligands
Atoms
Azides
imines
atoms
Imines
Schiff Bases
Hydrogen bonds
Railroad cars
hydrogen bonds
Geometry
geometry

All Science Journal Classification (ASJC) codes

  • Condensed Matter Physics
  • Materials Science(all)
  • Chemistry(all)

Cite this

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title = "Azido(benzoylacetonato-κ2 O,O')[1-phenyl-3-(2- pyridylmethylimino)but-1-en-1-olato-κ3 N,N',O]cobalt(III)",
abstract = "In the title complex, [Co(C16H15N2O) (C10H9O2)(N3)], the CoII atom adopts an octa-hedral coordination geometry by a tridentate Schiff base, a bidentate benzoyl-acetonate and an azide ligand. The imine N atom of the tridentate ligand is trans to the benzoyl O atom of the bidentate ligand and the azide ligand is trans to the acetyl O atom of the bidentate ligand. Non-classical intra-molecular Car-yl - H⋯O hydrogen bonds are present in the structure.",
author = "Amitabha Datta and Sie, {Ming Han} and Jui-Hsien Huang and Lee, {Hon Man}",
year = "2010",
month = "3",
day = "19",
doi = "10.1107/S1600536810003338",
language = "English",
volume = "66",
journal = "Acta Crystallographica Section E: Structure Reports Online",
issn = "1600-5368",
publisher = "International Union of Crystallography",
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TY - JOUR

T1 - Azido(benzoylacetonato-κ2 O,O')[1-phenyl-3-(2- pyridylmethylimino)but-1-en-1-olato-κ3 N,N',O]cobalt(III)

AU - Datta, Amitabha

AU - Sie, Ming Han

AU - Huang, Jui-Hsien

AU - Lee, Hon Man

PY - 2010/3/19

Y1 - 2010/3/19

N2 - In the title complex, [Co(C16H15N2O) (C10H9O2)(N3)], the CoII atom adopts an octa-hedral coordination geometry by a tridentate Schiff base, a bidentate benzoyl-acetonate and an azide ligand. The imine N atom of the tridentate ligand is trans to the benzoyl O atom of the bidentate ligand and the azide ligand is trans to the acetyl O atom of the bidentate ligand. Non-classical intra-molecular Car-yl - H⋯O hydrogen bonds are present in the structure.

AB - In the title complex, [Co(C16H15N2O) (C10H9O2)(N3)], the CoII atom adopts an octa-hedral coordination geometry by a tridentate Schiff base, a bidentate benzoyl-acetonate and an azide ligand. The imine N atom of the tridentate ligand is trans to the benzoyl O atom of the bidentate ligand and the azide ligand is trans to the acetyl O atom of the bidentate ligand. Non-classical intra-molecular Car-yl - H⋯O hydrogen bonds are present in the structure.

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