Abstract
The novel hydride-bridged tetranuclear aluminum complex {AlH2[C4H2N(CH2 NMe2)2-2,5]AlH3}2 (2) and the related deuterium complex {AlD2[C4H2N(CH2 NMe2)2-2,5]AlD3}2 (2-D) have been synthesized by reaction of AlCl2[C4H2N(CH2 NMe2)2-2,5] (1) with 2 equiv of LiAlH4 or LiAlD4. The crystal structure of complex 2-D reveals an unusual structure in which the aluminum atoms are in a square-planar arrangement. Reaction of 2 with 2 equiv of H2O in diethyl ether affords the aluminum dihydride complex [C4H2N(CH2NMe2)2-2,5] AlH2 (3).
| Original language | English |
|---|---|
| Pages (from-to) | 4445-4447 |
| Number of pages | 3 |
| Journal | Organometallics |
| Volume | 20 |
| Issue number | 22 |
| DOIs | |
| Publication status | Published - 2001 Oct 29 |
All Science Journal Classification (ASJC) codes
- Physical and Theoretical Chemistry
- Organic Chemistry
- Inorganic Chemistry
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Chang, J. C., Hung, C. H., & Huang, J-H. (2001). An unusual hydride-bridged aluminum complex with a square-planar tetraaluminum core stabilized by 2,5-bis((dimethylamino)methyl)pyrrole ligands. Organometallics, 20(22), 4445-4447. https://doi.org/10.1021/om010368k