Abstract
The CuII atom in the title complex, [Cu(C18H21N2O2)(C2H3O2)], is tetra-coordinated by two N atoms and two O atoms, of which one O atom is attributed to the acetate group and the other atoms are from the tridentate salicylideneiminate ligand, forming a slight distorted square-planar environment. The other acetate O atom exhibits a very weak intra-molecular inter-action toward the Cu atom, the Cu - O distance of 2.771 (2) Å being shorter than the van der Waals radii for Cu and O atoms (2.92 Å). Furthermore, there are weak inter-molecular inter-actions, in which the bonding O atom of the acetate group can bridge to the Cu atom of another complex, and the distance of 2.523 (2) Å is about 0.4 Å shorter than the van der Waals Cu - O distance in other crystal structures.
| Original language | English |
|---|---|
| Pages (from-to) | m1434 |
| Journal | Acta Crystallographica Section E: Structure Reports Online |
| Volume | 64 |
| Issue number | 11 |
| DOIs | |
| Publication status | Published - 2008 Nov 14 |
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All Science Journal Classification (ASJC) codes
- Chemistry(all)
- Materials Science(all)
- Condensed Matter Physics
Cite this
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(Acetato-κO)(2-{[2-(dimethyl-amino)-ethyl-imino](phen-yl)meth-yl} -5-methoxy-phenolatoκ-κ3 N,N′,O 1)copper(II). / Lin, Chieh Shen; Len, Chia Her; Huang, Jui Hsien; Ko, Bao Tsan.
In: Acta Crystallographica Section E: Structure Reports Online, Vol. 64, No. 11, 14.11.2008, p. m1434.Research output: Contribution to journal › Article
TY - JOUR
T1 - (Acetato-κO)(2-{[2-(dimethyl-amino)-ethyl-imino](phen-yl)meth-yl} -5-methoxy-phenolatoκ-κ3 N,N′,O 1)copper(II)
AU - Lin, Chieh Shen
AU - Len, Chia Her
AU - Huang, Jui Hsien
AU - Ko, Bao Tsan
PY - 2008/11/14
Y1 - 2008/11/14
N2 - The CuII atom in the title complex, [Cu(C18H21N2O2)(C2H3O2)], is tetra-coordinated by two N atoms and two O atoms, of which one O atom is attributed to the acetate group and the other atoms are from the tridentate salicylideneiminate ligand, forming a slight distorted square-planar environment. The other acetate O atom exhibits a very weak intra-molecular inter-action toward the Cu atom, the Cu - O distance of 2.771 (2) Å being shorter than the van der Waals radii for Cu and O atoms (2.92 Å). Furthermore, there are weak inter-molecular inter-actions, in which the bonding O atom of the acetate group can bridge to the Cu atom of another complex, and the distance of 2.523 (2) Å is about 0.4 Å shorter than the van der Waals Cu - O distance in other crystal structures.
AB - The CuII atom in the title complex, [Cu(C18H21N2O2)(C2H3O2)], is tetra-coordinated by two N atoms and two O atoms, of which one O atom is attributed to the acetate group and the other atoms are from the tridentate salicylideneiminate ligand, forming a slight distorted square-planar environment. The other acetate O atom exhibits a very weak intra-molecular inter-action toward the Cu atom, the Cu - O distance of 2.771 (2) Å being shorter than the van der Waals radii for Cu and O atoms (2.92 Å). Furthermore, there are weak inter-molecular inter-actions, in which the bonding O atom of the acetate group can bridge to the Cu atom of another complex, and the distance of 2.523 (2) Å is about 0.4 Å shorter than the van der Waals Cu - O distance in other crystal structures.
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U2 - 10.1107/S1600536808033114
DO - 10.1107/S1600536808033114
M3 - Article
C2 - 21580877
AN - SCOPUS:55749111050
VL - 64
SP - m1434
JO - Acta Crystallographica Section E: Structure Reports Online
JF - Acta Crystallographica Section E: Structure Reports Online
SN - 1600-5368
IS - 11
ER -