(Acetato-κO)(2-{[2-(dimethyl-amino)-ethyl-imino](phen-yl)meth-yl} -5-methoxy-phenolatoκ-κ3 N,N′,O 1)copper(II)

Chieh Shen Lin, Chia Her Len, Jui Hsien Huang, Bao Tsan Ko

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

The CuII atom in the title complex, [Cu(C18H21N2O2)(C2H3O2)], is tetra-coordinated by two N atoms and two O atoms, of which one O atom is attributed to the acetate group and the other atoms are from the tridentate salicylideneiminate ligand, forming a slight distorted square-planar environment. The other acetate O atom exhibits a very weak intra-molecular inter-action toward the Cu atom, the Cu - O distance of 2.771 (2) Å being shorter than the van der Waals radii for Cu and O atoms (2.92 Å). Furthermore, there are weak inter-molecular inter-actions, in which the bonding O atom of the acetate group can bridge to the Cu atom of another complex, and the distance of 2.523 (2) Å is about 0.4 Å shorter than the van der Waals Cu - O distance in other crystal structures.

Original languageEnglish
Pages (from-to)m1434
JournalActa Crystallographica Section E: Structure Reports Online
Volume64
Issue number11
DOIs
Publication statusPublished - 2008 Nov 14

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Copper
copper
Atoms
atoms
acetates
Acetates
Crystal structure
Ligands
ligands
crystal structure
radii

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

Cite this

@article{1eeb171b5c134fd998982a993f9f8a41,
title = "(Acetato-κO)(2-{[2-(dimethyl-amino)-ethyl-imino](phen-yl)meth-yl} -5-methoxy-phenolatoκ-κ3 N,N′,O 1)copper(II)",
abstract = "The CuII atom in the title complex, [Cu(C18H21N2O2)(C2H3O2)], is tetra-coordinated by two N atoms and two O atoms, of which one O atom is attributed to the acetate group and the other atoms are from the tridentate salicylideneiminate ligand, forming a slight distorted square-planar environment. The other acetate O atom exhibits a very weak intra-molecular inter-action toward the Cu atom, the Cu - O distance of 2.771 (2) {\AA} being shorter than the van der Waals radii for Cu and O atoms (2.92 {\AA}). Furthermore, there are weak inter-molecular inter-actions, in which the bonding O atom of the acetate group can bridge to the Cu atom of another complex, and the distance of 2.523 (2) {\AA} is about 0.4 {\AA} shorter than the van der Waals Cu - O distance in other crystal structures.",
author = "Lin, {Chieh Shen} and Len, {Chia Her} and Huang, {Jui Hsien} and Ko, {Bao Tsan}",
year = "2008",
month = "11",
day = "14",
doi = "10.1107/S1600536808033114",
language = "English",
volume = "64",
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journal = "Acta Crystallographica Section E: Structure Reports Online",
issn = "1600-5368",
publisher = "International Union of Crystallography",
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}

(Acetato-κO)(2-{[2-(dimethyl-amino)-ethyl-imino](phen-yl)meth-yl} -5-methoxy-phenolatoκ-κ3 N,N′,O 1)copper(II). / Lin, Chieh Shen; Len, Chia Her; Huang, Jui Hsien; Ko, Bao Tsan.

In: Acta Crystallographica Section E: Structure Reports Online, Vol. 64, No. 11, 14.11.2008, p. m1434.

Research output: Contribution to journalArticle

TY - JOUR

T1 - (Acetato-κO)(2-{[2-(dimethyl-amino)-ethyl-imino](phen-yl)meth-yl} -5-methoxy-phenolatoκ-κ3 N,N′,O 1)copper(II)

AU - Lin, Chieh Shen

AU - Len, Chia Her

AU - Huang, Jui Hsien

AU - Ko, Bao Tsan

PY - 2008/11/14

Y1 - 2008/11/14

N2 - The CuII atom in the title complex, [Cu(C18H21N2O2)(C2H3O2)], is tetra-coordinated by two N atoms and two O atoms, of which one O atom is attributed to the acetate group and the other atoms are from the tridentate salicylideneiminate ligand, forming a slight distorted square-planar environment. The other acetate O atom exhibits a very weak intra-molecular inter-action toward the Cu atom, the Cu - O distance of 2.771 (2) Å being shorter than the van der Waals radii for Cu and O atoms (2.92 Å). Furthermore, there are weak inter-molecular inter-actions, in which the bonding O atom of the acetate group can bridge to the Cu atom of another complex, and the distance of 2.523 (2) Å is about 0.4 Å shorter than the van der Waals Cu - O distance in other crystal structures.

AB - The CuII atom in the title complex, [Cu(C18H21N2O2)(C2H3O2)], is tetra-coordinated by two N atoms and two O atoms, of which one O atom is attributed to the acetate group and the other atoms are from the tridentate salicylideneiminate ligand, forming a slight distorted square-planar environment. The other acetate O atom exhibits a very weak intra-molecular inter-action toward the Cu atom, the Cu - O distance of 2.771 (2) Å being shorter than the van der Waals radii for Cu and O atoms (2.92 Å). Furthermore, there are weak inter-molecular inter-actions, in which the bonding O atom of the acetate group can bridge to the Cu atom of another complex, and the distance of 2.523 (2) Å is about 0.4 Å shorter than the van der Waals Cu - O distance in other crystal structures.

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