A symmetric derivative of the trimetallic nitride endohedral metallofullerene, Sc3N @ C80

Erick B. Iezzi, James C. Duchamp, Kim Harich, Tom E. Glass, Hon Man Lee, Marilyn M. Olmstead, Alan L. Balch, Harry C. Dorn

Research output: Contribution to journalArticle

146 Citations (Scopus)

Abstract

The reaction of Sc3N@C80 with 6,7-dimethoxyisochroman-3-one (13C labeled) provides the first functionalized derivative of the trimetallic nitride template (TNT) endohedral metallofullerene family. The reaction mixture is dominated by a single 13C labeled monoadduct product that was purified by HPLC. The 13C labeled monoadduct was characterized by 1H NMR, 13C NMR, and MALDI-TOF mass spectrometry. The proposed structure for this novel symmetric monoadduct is consistent with derivatization at the [5,6] ring juncture on the Sc3N@C80 cage.

Original languageEnglish
Pages (from-to)524-525
Number of pages2
JournalJournal of the American Chemical Society
Volume124
Issue number4
DOIs
Publication statusPublished - 2002 Jan 30

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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    Iezzi, E. B., Duchamp, J. C., Harich, K., Glass, T. E., Lee, H. M., Olmstead, M. M., Balch, A. L., & Dorn, H. C. (2002). A symmetric derivative of the trimetallic nitride endohedral metallofullerene, Sc3N @ C80. Journal of the American Chemical Society, 124(4), 524-525. https://doi.org/10.1021/ja0171005