A symmetric derivative of the trimetallic nitride endohedral metallofullerene, Sc3N @ C80

Erick B. Iezzi, James C. Duchamp, Kim Harich, Tom E. Glass, Hon Man Lee, Marilyn M. Olmstead, Alan L. Balch, Harry C. Dorn

Research output: Contribution to journalArticle

143 Citations (Scopus)

Abstract

The reaction of Sc3N@C80 with 6,7-dimethoxyisochroman-3-one (13C labeled) provides the first functionalized derivative of the trimetallic nitride template (TNT) endohedral metallofullerene family. The reaction mixture is dominated by a single 13C labeled monoadduct product that was purified by HPLC. The 13C labeled monoadduct was characterized by 1H NMR, 13C NMR, and MALDI-TOF mass spectrometry. The proposed structure for this novel symmetric monoadduct is consistent with derivatization at the [5,6] ring juncture on the Sc3N@C80 cage.

Original languageEnglish
Pages (from-to)524-525
Number of pages2
JournalJournal of the American Chemical Society
Volume124
Issue number4
DOIs
Publication statusPublished - 2002 Jan 30

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Matrix-Assisted Laser Desorption-Ionization Mass Spectrometry
Nitrides
Mass Spectrometry
High Pressure Liquid Chromatography
Nuclear magnetic resonance
Derivatives
Mass spectrometry
Proton Magnetic Resonance Spectroscopy
Carbon-13 Magnetic Resonance Spectroscopy

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

Cite this

Iezzi, E. B., Duchamp, J. C., Harich, K., Glass, T. E., Lee, H. M., Olmstead, M. M., ... Dorn, H. C. (2002). A symmetric derivative of the trimetallic nitride endohedral metallofullerene, Sc3N @ C80. Journal of the American Chemical Society, 124(4), 524-525. https://doi.org/10.1021/ja0171005
Iezzi, Erick B. ; Duchamp, James C. ; Harich, Kim ; Glass, Tom E. ; Lee, Hon Man ; Olmstead, Marilyn M. ; Balch, Alan L. ; Dorn, Harry C. / A symmetric derivative of the trimetallic nitride endohedral metallofullerene, Sc3N @ C80. In: Journal of the American Chemical Society. 2002 ; Vol. 124, No. 4. pp. 524-525.
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abstract = "The reaction of Sc3N@C80 with 6,7-dimethoxyisochroman-3-one (13C labeled) provides the first functionalized derivative of the trimetallic nitride template (TNT) endohedral metallofullerene family. The reaction mixture is dominated by a single 13C labeled monoadduct product that was purified by HPLC. The 13C labeled monoadduct was characterized by 1H NMR, 13C NMR, and MALDI-TOF mass spectrometry. The proposed structure for this novel symmetric monoadduct is consistent with derivatization at the [5,6] ring juncture on the Sc3N@C80 cage.",
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Iezzi, EB, Duchamp, JC, Harich, K, Glass, TE, Lee, HM, Olmstead, MM, Balch, AL & Dorn, HC 2002, 'A symmetric derivative of the trimetallic nitride endohedral metallofullerene, Sc3N @ C80', Journal of the American Chemical Society, vol. 124, no. 4, pp. 524-525. https://doi.org/10.1021/ja0171005

A symmetric derivative of the trimetallic nitride endohedral metallofullerene, Sc3N @ C80. / Iezzi, Erick B.; Duchamp, James C.; Harich, Kim; Glass, Tom E.; Lee, Hon Man; Olmstead, Marilyn M.; Balch, Alan L.; Dorn, Harry C.

In: Journal of the American Chemical Society, Vol. 124, No. 4, 30.01.2002, p. 524-525.

Research output: Contribution to journalArticle

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AU - Iezzi, Erick B.

AU - Duchamp, James C.

AU - Harich, Kim

AU - Glass, Tom E.

AU - Lee, Hon Man

AU - Olmstead, Marilyn M.

AU - Balch, Alan L.

AU - Dorn, Harry C.

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AB - The reaction of Sc3N@C80 with 6,7-dimethoxyisochroman-3-one (13C labeled) provides the first functionalized derivative of the trimetallic nitride template (TNT) endohedral metallofullerene family. The reaction mixture is dominated by a single 13C labeled monoadduct product that was purified by HPLC. The 13C labeled monoadduct was characterized by 1H NMR, 13C NMR, and MALDI-TOF mass spectrometry. The proposed structure for this novel symmetric monoadduct is consistent with derivatization at the [5,6] ring juncture on the Sc3N@C80 cage.

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