A simple and highly selective receptor for iodide in aqueous solution

Hsiu Jung Cheng, Hongbin Yan, Yao Lin Sun, Cheng Yi Lu, Tzu Yu Huang, Shau Jiun Chen, Ching-Han Hu, Ying Yann Wu, An-Tai Wu

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Abstract

We synthesized a simple fluorescent receptor 3 bearing two boronic acid groups as recognition sites. The recognition behaviour of receptor 3 towards various anions was evaluated in THF/H2O (1:1, v/v) solution. Receptor 3 showed high selectivity for iodide among a series of anions. Fluorescence spectroscopy and computational calculations revealed that the electrostatic interaction played a crucial role in its high selectivity for iodide.

Original languageEnglish
Pages (from-to)571-574
Number of pages4
JournalAnalyst
Volume137
Issue number3
DOIs
Publication statusPublished - 2012 Feb 7

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All Science Journal Classification (ASJC) codes

  • Analytical Chemistry
  • Biochemistry
  • Environmental Chemistry
  • Spectroscopy
  • Electrochemistry

Cite this

Cheng, H. J., Yan, H., Sun, Y. L., Lu, C. Y., Huang, T. Y., Chen, S. J., ... Wu, A-T. (2012). A simple and highly selective receptor for iodide in aqueous solution. Analyst, 137(3), 571-574. https://doi.org/10.1039/c1an15834a