A new type of asymmetric tridentate pyrrolyl-linked pincer ligand and lts aluminum dihydride complexes

Yu Ling Lien, Ya Chi Change, Nien Tsu Chuang, Amitabha Datta, Shau Jiun Chen, Ching-Han Hu, Wen Yen Huang, Chia Her Lin, Jui-Hsien Huang

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Abstract

The new pyrrolyl-linked pincer-type ligand, [C4H 2NH(2-CH2NHtBu)(5-CH2NMe 2)] (1), that has been employed conveniently in high yield by treatment of (2-t-butylaminomethyl)pyrrole with 1 equiv of formaldehyde and dimethylamine hydrochloride each in diethylether and its corresponding aluminum derivative, [C4H2N(2-CH2NHtBu)(5- CH2NMe2)]AlH2 (2), that has been generated from Me3N.AlH3 using diethylether as a solvent are described. Furthermore, reactions of 2 with 2 equiv of either 1,3-diphenylpropane-1,3-dione in diethylether or phenyl thioisocyanate in dichloromethane interestingly formed [C4H2N(2-CH2NHtBu)(5-CH 2NMe2)]Al(PhCOCHCOPh)2 (3) and [C 4H2N(2-CH2NHtBu)(5-CH 2NMe2)]Al(SCHNPh)2 (4), respectively, following deprotonation or hydroalumination reaction kinetics under a dry nitrogen environment. All of the compounds have been subjected to the X-ray diffraction technique in the solid state as well as characterized by NMR spectra.

Original languageEnglish
Pages (from-to)136-143
Number of pages8
JournalInorganic Chemistry
Volume49
Issue number1
DOIs
Publication statusPublished - 2010 Jan 4

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

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    Lien, Y. L., Change, Y. C., Chuang, N. T., Datta, A., Chen, S. J., Hu, C-H., Huang, W. Y., Lin, C. H., & Huang, J-H. (2010). A new type of asymmetric tridentate pyrrolyl-linked pincer ligand and lts aluminum dihydride complexes. Inorganic Chemistry, 49(1), 136-143. https://doi.org/10.1021/ic9016189