A new monoclinic polymorph of trans-dichloridodipyridine-palladium(II)

Hon Man Lee, Chuang Yi Liao

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

In the structure of the title compound, [PdCl2(C5H5N)2], the Pd II atom is located on an inversion centre and the pyridine rings are coplanar. There is inter-molecular π-π stacking between the pyridyl rings, with a centroid-to-centroid separation of 3.916 (1) Å. The structure is a new polymorph of two previously determined structures [Viossat, Dung & Robert (1993). Acta Cryst. C49, 84-85; Liao & Lee (2006). Acta Cryst. E62, m680-m681].

Original languageEnglish
JournalActa Crystallographica Section E: Structure Reports Online
Volume64
Issue number11
DOIs
Publication statusPublished - 2008 Nov 14

Fingerprint

Palladium
Polymorphism
Pyridine
centroids
palladium
Atoms
rings
pyridines
inversions
atoms
palladium chloride
pyridine

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

Cite this

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abstract = "In the structure of the title compound, [PdCl2(C5H5N)2], the Pd II atom is located on an inversion centre and the pyridine rings are coplanar. There is inter-molecular π-π stacking between the pyridyl rings, with a centroid-to-centroid separation of 3.916 (1) {\AA}. The structure is a new polymorph of two previously determined structures [Viossat, Dung & Robert (1993). Acta Cryst. C49, 84-85; Liao & Lee (2006). Acta Cryst. E62, m680-m681].",
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A new monoclinic polymorph of trans-dichloridodipyridine-palladium(II). / Lee, Hon Man; Liao, Chuang Yi.

In: Acta Crystallographica Section E: Structure Reports Online, Vol. 64, No. 11, 14.11.2008.

Research output: Contribution to journalArticle

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N2 - In the structure of the title compound, [PdCl2(C5H5N)2], the Pd II atom is located on an inversion centre and the pyridine rings are coplanar. There is inter-molecular π-π stacking between the pyridyl rings, with a centroid-to-centroid separation of 3.916 (1) Å. The structure is a new polymorph of two previously determined structures [Viossat, Dung & Robert (1993). Acta Cryst. C49, 84-85; Liao & Lee (2006). Acta Cryst. E62, m680-m681].

AB - In the structure of the title compound, [PdCl2(C5H5N)2], the Pd II atom is located on an inversion centre and the pyridine rings are coplanar. There is inter-molecular π-π stacking between the pyridyl rings, with a centroid-to-centroid separation of 3.916 (1) Å. The structure is a new polymorph of two previously determined structures [Viossat, Dung & Robert (1993). Acta Cryst. C49, 84-85; Liao & Lee (2006). Acta Cryst. E62, m680-m681].

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