A mixed valent heterometallic Cu II /Na I coordination polymer with sodium-phenyl bonds

Amitabha Datta, Kuheli Das, Chiara Massera, Jack K. Clegg, Chittaranjan Sinha, Jui-Hsien Huang, Eugenio Garribba

Research output: Contribution to journalArticle

10 Citations (Scopus)

Abstract

A mixed valent heterometallic Cu II /Na I coordination polymer (1) is generated by the reaction of a Schiff base ligand, (6,6′-(1E,1′E)-(2-hydroxypropane-1,3-diyl)bis(azan-1-yl-1-ylidene) bis(methan-1-yl-1-ylidene)bis(2-methoxyphenol)) with copper(ii) acetate and sodium perchlorate. In addition to the presence of alcohol oxygen-sodium coordination bonds, the single crystal X-ray structure reveals that the 1D coordination polymer is stabilised by the formation of phenyl-sodium η 2 -bonds, face-to-face π-π contacts and Cu-π interactions. This journal is

Original languageEnglish
Pages (from-to)5558-5563
Number of pages6
JournalDalton Transactions
Volume43
Issue number14
DOIs
Publication statusPublished - 2014 Apr 14

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Polymers
Sodium
Guaiacol
Schiff Bases
Copper
Alcohols
Single crystals
Oxygen
Ligands
X rays
sodium perchlorate

All Science Journal Classification (ASJC) codes

  • Inorganic Chemistry

Cite this

Datta, Amitabha ; Das, Kuheli ; Massera, Chiara ; Clegg, Jack K. ; Sinha, Chittaranjan ; Huang, Jui-Hsien ; Garribba, Eugenio. / A mixed valent heterometallic Cu II /Na I coordination polymer with sodium-phenyl bonds In: Dalton Transactions. 2014 ; Vol. 43, No. 14. pp. 5558-5563.
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Datta, A, Das, K, Massera, C, Clegg, JK, Sinha, C, Huang, J-H & Garribba, E 2014, ' A mixed valent heterometallic Cu II /Na I coordination polymer with sodium-phenyl bonds ', Dalton Transactions, vol. 43, no. 14, pp. 5558-5563. https://doi.org/10.1039/c4dt00189c

A mixed valent heterometallic Cu II /Na I coordination polymer with sodium-phenyl bonds . / Datta, Amitabha; Das, Kuheli; Massera, Chiara; Clegg, Jack K.; Sinha, Chittaranjan; Huang, Jui-Hsien; Garribba, Eugenio.

In: Dalton Transactions, Vol. 43, No. 14, 14.04.2014, p. 5558-5563.

Research output: Contribution to journalArticle

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AU - Huang, Jui-Hsien

AU - Garribba, Eugenio

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